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Sunday, 07 August 2011 06:26

Halogens & Their Compounds: Health Hazards

Chemical Name CAS-Number	ICSC Short-Term Exposure	ICSC Long-Term Exposure	ICSC Routes of Exposure and Symptoms	US NIOSH Target Organs & Routes of Entry	US NIOSH Symptoms
BROMINE 7726-95-6	eyes; skin; resp tract; lungs	skin; lungs	Inhalation: corrosive, burning sensation, cough, dizziness, headache, laboured breathing, sore throat Skin: corrosive, redness, skin burns, pain Eyes: corrosive, redness, pain, severe deep burns Ingestion: corrosive, abdominal cramps, burning sensation, sore throat, collapse	Resp sys; eyes; CNS; skin Inh; ing; con	Dizz, head; lac, epis; cough, feeling of oppression, pulm edema, pneu; abdom pain, diarr; measle-like eruptions; eye, skin burns
BROMINE PENTAFLUORIDE 7789-30-2	eyes; skin; resp tract; lungs	liver; kidneys; resp tract	Inhalation: burning sensation, cough, shortness of breath, sore throat Skin: skin burns, pain, blisters Eyes: pain, blurred vision, severe deep burns Ingestion: abdominal pain, burning sensation	Eyes; skin; resp sys; liver; kidneys Inh; ing; con	Irrit eyes, skin, resp sys; corn nec; skin burns; cough; dysp, pulm edema; liver, kidney inj
CARBONYL FLUORIDE 353-50-4	eyes; skin; resp tract; lungs; skin	blood	Inhalation: cough, laboured breathing, sore throat, symptoms may be delayed Skin: redness, on contact with liquid: frostbite Eyes: redness	Eyes; skin; resp sys; bone Inh; con	Irrit eyes, skin, muc memb, resp sys; eye, skin burns; lac; cough; pulm edema, dysp; chronic exposure: GI pain, musc fib, skeletal fluorosis; liq: frostbite
CHLORINE 7782-50-5	eyes; skin; resp tract; lungs; skin	lungs	Inhalation: corrosive, burning sensation, cough, headache, laboured breathing, nausea, shortness of breath, sore throat, symptoms may be delayed Skin: corrosive, skin burns, pain Eyes: corrosive, pain, blurred vision, severe deep burns	Resp sys, eyes, skin Inh; con	Burning of eyes, nose, mouth; lac, rhin; cough, choking, subs pain; nau, vomit; head, dizz; syncope; pulm edema; pneu; hypox; derm; liq: frostbite
CHLORINE OXIDE 10049-04-4	eyes; skin; resp tract; lungs; skin	lungs	Inhalation: corrosive, cough, headache, laboured breathing, nausea, shortness of breath, sore throat, symptoms may be delayed Skin: corrosive, redness, serious skin burns, pain	Resp sys; eyes Inh; ing (liq); con	Irrit eyes, nose, throat; cough, wheez, bron, pulm edema; chronic bron
CHLORINE TRIFLUORIDE 7790-91-2	eyes; skin; resp tract; lungs		Inhalation: cough, laboured breathing, sore throat Skin: corrosive, redness, serious skin burns, pain Eyes: permanent loss of vision, severe deep burns, blindness	Skin; eyes; resp sys Inh; ing (liq); con	Eye, skin burns (liq or high vap conc); resp irrit; in animals: lac; corn ulcer; pulm edema
FLUORINE 7782-41-4	eyes; skin; resp tract; lungs	skin	Inhalation: corrosive, cough, shortness of breath, sore throat, choking Skin: corrosive, redness, serious skin burns, on contact with liquid: frostbite Eyes: redness, severe deep burns	Resp sys; eyes; liver; kidneys Inh; con	Irrit eyes, nose, resp sys; lar spasm, bron spasm; pulm edema; eye, skin burns; in animals: liver, kidney damage
HYDROGEN FLUORIDE 7664-39-3	eyes; skin; resp tract; lungs		Inhalation: cough, laboured breathing, sore throat, symptoms may have delayed effects Skin: may be adsorbed, serious skin burns Eyes: redness, pain, blurred vision Ingestion: abdominal pain, diarrhoea, sore throat, vomiting, symptoms may have delayed effects	Eyes; resp sys; skin; bone Inh; abs (liq); ing (soln); con	Irrit eyes, skin, nose, throat; pulm edema; eye, skin burns; rhinitis; bron; bone changes
OXYGEN DIFLUORIDE 7783-41-7	eyes; skin; resp tract; lungs		Inhalation: cough, laboured breathing, sore throat Skin: on contact with liquid: frostbite	Resp sys; eyes; skin Inh; con	Irrit eyes, skin, resp sys; head; pulm edema; eye, skin burns (from contact with the gas under pressure)
PERCHLORYL FLUORIDE 7616-94-6	resp tract; skin	blood	Inhalation: headache Skin: on contact with liquid: frostbite Eyes: severe deep burns	Resp sys; skin; blood Inh; con (liq)	Irrit resp sys; liq: frostbite; in animals: methemo; cyan; weak; dizz, head; pulm edema; pneuitis; anoxia
PHOSGENE 75-44-5	eyes; skin; resp tract; lungs	lungs	Inhalation: corrosive, burning sensation, cough, laboured breathing, shortness of breath, sore throat	Resp sys; skin; eyes Inh; con (liq)	Irrit eyes; dry, burning throat; vomit; cough, foamy sputum, dysp, chest pain, cyan; liq: frostbite
SULPHUR CHLORIDE 10025-67-9	eyes; skin; resp tract; lungs; corrosive on ingestion	skin	Inhalation: burning sensation, cough, headache, laboured breathing, nausea, vomiting Skin: redness, skin burns, burning sensation, pain, blisters Eyes: redness, pain, severe deep burns	Resp sys; skin; eyes Inh; ing; con	Irrit eyes, skin, muc memb; lac; cough; eye, skin burns; pulm edema
SULPHUR HEXAFLUORIDE 2551-62-4	skin		Skin: on contact with liquid: frostbite Eyes: corneal damage	Resp sys Inh	Asphy: incr breath rate, pulse rate; slight musc inco, emotional upset; ftg, nau, vomit, convuls
SULPHUR PENTAFLUORIDE 5714-22-7				Resp sys; CNS; eyes; skin Inh; ing; con	Irrit eys, skin, resp sys; in animals: pulm edema, hemorr

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 06:25

Halogens & Their Compounds: Chemical Identification

Chemical Formula	Chemical	Synonyms UN Code	CAS-Number
7726956	BROMINE	Bromine UN1744	7726-95-6
7789302	BROMINE PENTAFLUORIDE	Bromine pentafluoride UN1745	7789-30-2
7789755	CALCIUM FLUORIDE		7789-75-5
353504	CARBONYL FLUORIDE	Carbon difluoride oxide; Carbon fluoride oxide; Carbon oxyfluoride; Carbonyl difluoride; Difluoroformaldehyde; Fluophosgene; Fluoroformyl fluoride; Fluorophosgene UN2417	353-50-4
7782505	CHLORINE	Molecular chlorine UN1017	7782-50-5
10049044	CHLORINE OXIDE	Chlorine dioxide; Chlorine(IV) oxide; Chlorine peroxide; Chloroperoxyl	10049-04-4
7790912	CHLORINE TRIFLUORIDE	Chlorine fluoride; Chlorotrifluoride UN1749	7790-91-2
7782414	FLUORINE	Fluorine UN1045	7782-41-4
10035106	HYDROGEN BROMIDE	Anhydrous hydrobromic acid; Hydrobromic acid solution UN1788	10035-10-6
7664393	HYDROGEN FLUORIDE	Hydrofluoric acid; Hydrofluoride UN1052 UN1790	7664-39-3
7553562	IODINE		7553-56-2
10025851	NITROGEN CHLORIDE	Chlorine nitride; Nitrogen trichloride; Trichloramine; Trichlorine nitride	10025-85-1
7783542	NITROGEN TRIFLUORIDE	Nitrogen fluoride UN2451	7783-54-2
7783417	OXYGEN DIFLUORIDE	Fluorine monoxide; Fluorine oxide; Oxygen fluoride UN2190	7783-41-7
7616946	PERCHLORYL FLUORIDE	Chlorine fluoride oxide; Chlorine oxyfluoride UN3083	7616-94-6
75445	PHOSGENE	Carbonyl chloride; Carbonyl dichloride; Chloroformyl chloride UN1076	75-44-5
7789697	PHOSPHOROUS PENTABROMIDE		7789-69-7
7789608	PHOSPHOROUS TRIBROMIDE	Phosphorous bromide; Tribromophosphine UN1808	7789-60-8
16893859	SODIUM HEXAFLUOROSILICATE		16893-85-9
10025679	SULPHUR CHLORIDE	Disulphurdichloride; Sulphurmonochloride; Sulphurisubchloride; Thiosulphurous dichloride	10025-67-9
10545990	SULPHUR DICHLORIDE		10545-99-0
2551624	SULPHUR HEXAFLUORIDE	Sulphurfluoride UN1080	2551-62-4
5714227	SULPHUR PENTAFLUORIDE	Disulphurdecafluoride; Sulphurdecafluoride	5714-22-7
2699798	SULPHURYL FLUORIDE	Sulphuric oxyfluoride UN2191	2699-79-8

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 06:18

Glycerols & Glycols: Physical & Chemical Properties

Chemical Name CAS-Number	Colour/Form	Boiling Point (°C)	Melting Point (°C)	Molecular Weight	Solubility in Water	Relative Density (water=1)	Relative Vapour Density (air=1)	Vapour Pressure/ (Kpa)	Inflam. Limits	Flash Point (°C)	Auto Ignition Point (°C)
1,3-BUTANEDIOL 107-88-0	viscous liquid; pure compound is colourless	207.5	<50	90.12	sol	1.002	3.2	8 Pa		121	394
1,4-BUTANEDIOL 110-63-4	colourless, viscid liquid	230	20.1	90.12	misc	1.0171	3.1	@ 37.7 °C		121 oc	350
DIMETHYLENE GLYCOL 513-85-9	nearly colourless liquid or solid			90.12			3.1				402
DIETHYLENE GLYCOL 111-46-6	colourless liquid; syrupy liquid	245.8	-10.4	106.1	sol	1.18	3.66	5 Pa	1.6 ll 10.8 ul	143	400
DIPROPYLENE GLYCOL 110-98-5	colourless, slightly viscous liquid	233		134.17	misc	1.0252	4.63	@ 25 °C		137
2-ETHYL-1,3-HEXANEDIOL 94-96-2	slightly oily liquid; colourless liquid	244.	-40	146.22	sl sol	@ 22 °C/4 °C	5.03	< 0.01 mm Hg		110 oc	335
ETHYLENE GLYCOL 107-21-1	slightly viscous liquid; clear, colourless syrupy liquid	197.6	-13	62.07	misc	1.1135	2.14	7 Pa	3.2 ll 15.3 ul	111 cc	398
GLYCEROL 56-81-5	clear colourless syrupy liquid	290	18	92.09	sol	1.2613				320	392
1,6-HEXANEDIOL 629-11-8	crystals	208	42.8	118.17	sol	@ 0 °C/4 °C	4.07	@ 25 °C (est)		101	320
2,5-HEXANEDIOL 2935-44-6		216-218	43	118.17	sol	0.9610
HEXYLENE GLYCOL 107-41-5	colourless liquid	198	-50	118.2	sol	@ 17 °C	4.1	6.7 Pa	1.3 ll 7.4 ul	93	260
NEOPENTYL GLYCOL 126-30-7		208	130	104.14	sol
PENTAERYTHRITOL 115-77-5	ditetragonal crystals from diluted hydrochloric acid; white, crystalline powder	sublimes	260	136.1	sol	@ 25 °C/4 °C
PROPYLENE GLYCOL 57-55-6	colourless viscous liquid	187.6	-59	76.1	misc	1.0361	2.6	106.6 Pa	2.6 ll 12.5 ul	99 cc	371

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 06:15

Glycerols & Glycols: Physical & Chemical Hazards

Chemical Name CAS-Number	Physical	Chemical	UN Class or Division / Subsidiary Risks
1,4-BUTANEDIOL 110-63-4		On combustion, forms toxic fumes (CO) • Reacts with strong oxidants
1,6-HEXANEDIOL 629-11-8	Dust explosion possible if in powder or granular form, mixed with air	On combustion, forms toxic gases
DIETHYLENE GLYCOL 111-46-6		Reacts violently with strong oxidants • Attacks many plastics
ETHYLENE GLYCOL 107-21-1		On combustion, forms toxic gases • Reacts with strong oxidants and strong bases
HEXYLENE GLYCOL 107-41-5		The substance polymerizes • Reacts with strong oxidants
PROPYLENE GLYCOL 57-55-6	The vapour is heavier than air	Reacts with strong oxidants, eg, potassium perchlorate, causing fire and explosion hazard

For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 06:14

Glycerols & Glycols: Health Hazards

Chemical Name CAS-Number	ICSC Short-Term Exposure	ICSC Long-Term Exposure	ICSC Routes of Exposure and Symptoms	US NIOSH Target Organs & Routes of Entry	US NIOSH Symptoms
1,3-BUTANEDIOL 107-88-0	eyes; skin; resp tract		Inhalation: cough Skin: redness Eyes: stinging sensation
1,4-BUTANEDIOL 110-63-4	eyes; resp tract; CNS; kidneys		Inhalation: cough, dizziness, headache, unconsciousness Eyes: redness, irritant Ingestion: unconsciousness
DIETHYLENE GLYCOL 111-46-6	eyes; skin; resp tract; CNS; liver; kidneys	liver; kidneys	Skin: redness Eyes: redness Ingestion: confusion, diarrhoea, dizziness, drowsiness, nausea, unconsciousness, vomiting
DIPROPYLENE GLYCOL 110-98-5	eyes; skin; resp tract	skin	Inhalation: cough Skin: redness Eyes: redness
ETHYLENE GLYCOL 107-21-1	eyes; skin; resp tract; kidneys; CNS	CNS; eyes	Inhalation: cough, dizziness, headache Skin: dry skin, redness Eyes: redness Ingestion: abdominal pain, dullness, nausea, unconsciousness, vomiting	Eyes; skin; resp sys; CNS Inh; ing; con	Irrit eyes, skin, nose, throat; nau, vomit, abdom pain; weak; dizz, stupor, convuls, CNS depres; skin sens
1,6-HEXANEDIOL 629-11-8	eyes; resp tract		Inhalation: cough Eyes: Irritation, redness
2,5-HEXANEDIOL 2935-44-6	eyes; skin; resp tract	skin; CNS
HEXYLENE GLYCOL 107-41-5	eyes; skin	skin; kidneys	Inhalation: cough Skin: dry skin, redness Eyes: redness Ingestion: abdominal cramps, diarrhoea, nausea, vomiting	Eyes; skin; resp sys Inh; ing; con	Irrit eyes, skin, resp sys; head, dizz, nau, inco, CNS depres; derm, skin sens
NEOPENTYL GLYCOL 126-30-7	eyes; skin; resp tract; lungs	lungs; kidneys
PROPYLENE GLYCOL 57-55-6	eyes		Eyes: pain

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 06:11

Glycerols & Glycols: Chemical Identification

Chemical Formula	Chemical	Synonyms UN Code	CAS-Number
584032	1,2-BUTANEDIOL	1,2-Butylene glycol	584-03-2
107880	1,3-BUTANEDIOL	Butane-1,3-diol; b-Butylene glycol; 1,3-Butylene glycol; 1,3-Dihydroxybutane; Methyltrimethylene glycol	107-88-0
110634	1,4-BUTANEDIOL	Butanediol; Butane-1,4-diol; 1,4-Butylene glycol; 1,4-Dihydroxybutane; Tetramethylene 1,4-diol; 1,4-Tetramethylene glycol	110-63-4
96242	3-CHLORO-1,2-PROPANEDIOL	Chlorhydrin; Chlorodeoxyglycerol; 1-Chloro-2,3-dihydroxypropane; 3-Chloro-1,2-dihydroxypropane UN2689	96-24-2
111466	DIETHYLENE GLYCOL	Bis(2-hydroxyethyl) ether; Dihydroxydiethyl ether; 2,2'-Dihydroxyethyl ether; Ethylene diglycol; Glycol ether; Glycol ethyl ether; 3-Oxapentane-1,5-diol; 3-Oxa-1,5-pentanediol; 2,2'-Oxybisethanol; 2,2'-Oxydiethanol	111-46-6
513859	DIMETHYLENE GLYCOL	2,3-Butanediol; 2,3-Butylene glycol; 2,3-Dihydroxybutane;	513-85-9
110985	DIPROPYLENE GLYCOL	2,2'-Dihydroxydipropyl ether; 2,2'-Dihydroxyisopropyl ether; 1,1'-Oxydi-2-propanol; 2-Propanol, 1,1'-Oxydi	110-98-5
94962	2-ETHYL-1,3-HEXANEDIOL	Ethyl hexanediol; 2-Ethylhexane-1,3-diol; 2-Ethylhexanediol-1,3; Ethyl hexylene glycol; 2-Ethyl-3-propyl-1,3-propanediol; 3-Hydroxymethyl-n-heptane-4-ol; Octylene glycol	94-96-2
107211	ETHYLENE GLYCOL	1,2-Dihydroxyethane; 1,2-Ethandiol; 1,2-Ethanediol; Ethane-1,2-diol; Ethylene alcohol; Ethylene dihydrate; Glycol; Glycol alcohol; Monoethylene glycol	107-21-1
56815	GLYCEROL	Glycerin; Glycerine; Glycyl alcohol; 1,2,3-Propanetriol; Star; Superol; Synthetic glycerin; Trihydroxypropane; 1,2,3-Trihydroxypropane	56-81-5
629118	1,6-HEXANEDIOL	Hexamethylene glycol	629-11-8
2935446	2,5-HEXANEDIOL		2935-44-6
107415	HEXYLENE GLYCOL	2,4-Dihydroxy-2-methylpentane; 2-Methyl pentane-2,4-diol; 2-Methyl-2,4-pentanediol	107-41-5
126307	NEOPENTYL GLYCOL	Dimethylolpropane; 2,2-Dimethyl-1,3-propanediol; Dimethyltrimethylene glycol	126-30-7
115775	PENTAERYTHRITOL	2,2-Bis(hydroxymethyl)-1,3-propanediol; Methane tetramethylol; Pentaerythrite; 1,3-Propanediol, 2,2-Bis(hydroxymethyl)-; Tetrahydroxymethylmetane; Tetramethylolmethane	115-77-5
57556	PROPYLENE GLYCOL	1,2-Dihydroxypropane; Methylethylene glycol; Methyl glycol; Monopropylene glycol; 1,2-Propanediol	57-55-6

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 06:05

Glycol Ethers: Physical & Chemical Properties

Chemical Name CAS-Number	Colour/Form	Boiling Point (°C)	Melting Point (°C)	Molecular Weight	Solubility in Water	Relative Density (water=1)	Relative Vapour Density (air=1)	Vapour Pressure/ (Kpa)	Inflam. Limits	Flash Point (°C)	Auto Ignition Point (°C)
1,4-BUTANEDIOL DIGLYCIDYL ETHER 2425-79-8		266		-202.28		@ 25 °C
DIETHYLENE GLYCOL DIETHYL ETHER 112-36-7	colourless liquid	189	-44.3	162.22	v sol	0.907	5.6	79 Pa		71 cc	174
DIETHYLENE GLYCOL MONOBUTYL ETHER 112-34-5	colourless liquid	230.4	-68.1	162.2	misc	0.9553	5.58	2.99 Pa		78	225
DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE 124-17-4	clear liquid	245	-32	204.30	sol	0.985		< 0.01 mm Hg
DIETHYLENE GLYCOL MONOETHYL ETHER 111-90-0	colourless liquid	196		134.17	misc	0.9881	4.62	@ 25 °C	@ 135 °C ll	96 oc	204
DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3	colourless liquid	193	< -84	120.1	misc	1.0270	4.14	30 Pa	1.6 ll 18.1 ul	93 oc	215
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8	colourless liquid	190	-80	148.2	misc	@ 25 °C	5.11	@ 26 °C	1.3 ll 10.4 ul	85 cc	270
2-ETHOXYETHANOL 110-80-5	colourless liquid	135	-70	90.12	v sol	0.9297	3.1	0.5	@ 93 °C ll	44 cc	235
ETHYLENE GLYCOL DIETHYL ETHER 629-14-1	colourless liquid	123.5	-74	118.2	2 %	0.8484	4.07	9.4 mm Hg
ETHYLENE GLYCOL ETHYL ETHER ACETATE 111-15-9	colourless liquid	156	-61.7	132.2	v sol	0.9740	4.72	0.16	1.7 ll 13.0 ul	52 cc	379
ETHYLENE GLYCOL METHYL ETHER 109-86-4	colourless liquid	125	-85.1	76.09	misc	0.9647	2.62	0.83	2.3 ll 24.5 ul	42 cc	285
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2	colourless liquid	171-172	-75	118.2	misc	0.9015	4.1	0.10	@ 93 °C ll	61 cc	238
ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE 112-07-2	colourless liquid	192.3	-64.5	160.24	1.1 g/100 g	0.9422	5.5	30-40 Pa	@ 93 °C ll	71 cc	340
ETHYLENE GLYCOL, MONOMETHYL ETHER ACETATE 110-49-6	colourless liquid	143	-65.1	118.13	v sol	@ 19 °C/19 °C	4.1	0.44	1.7 ll 8.2 ul	45 cc	394
ETHYLENE GLYCOL MONOPROPYL ETHER 2807-30-9	volatile liquid	149.8	<-70	104.1	sol	0.9112	3.6	200 Pa	5.5 ll 23 ul	49	230
ETHYLENE GLYCOL PHENYL ETHER 122-99-6	oily liquid; colourless liquid	245	14	138.16	insol	1.1094	4.8	5.2	1.4 ll 9.0 ul	121
PROPYLENE GLYCOL MONOMETHYL ETHER 107-98-2	colourless liquid	@ 740 mm Hg	-96.7	90.1	v sol	0.9620	3.11	1.6	1.6 ll 13.8 ul	38 oc

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 05:59

Glycol Ethers: Physical & Chemical Hazards

Chemical Name CAS-Number	Physical	Chemical	UN Class or Division / Subsidiary Risks
DIETHYLENE GLYCOL DIETHYL ETHER 112-36-7		The substance can form explosive peroxides. •On heating or on burning producing acrid smoke and irritating fumes. •Reacts with strong oxidants
DIETHYLENE GLYCOL MONOBUTYL ETHER 112-34-5		Reacts with strong oxidants, causing fire and explosion hazard
DIETHYLENE GLYCOL METHYL ETHER 111-77-3		The substance can presumably form explosive peroxides. •Reacts with strong oxidants
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8		The substance can presumably form explosive peroxides in contact with air. •Reacts violently with strong oxidants
2-ETHOXYETHANOL 110-80-5		The substance can form explosive peroxides. •The substance decomposes on burning producing toxic gas. •Reacts with strong oxidants causing fire and explosion hazard. •Attacks many plastics and rubber	3
ETHYLENE GLYCOL DIETHYL ETHER 629-14-1			3
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2		The substance can form explosive peroxides. •The substance decomposes, producing toxic fumes. •Reacts with strong oxidants, causing fire and explosion hazard	6.1
ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE 112-07-2	The vapour mixes well with air	Reacts with strong oxidants causing fire and explosion hazard
ETHYLENE GLYCOL, ETHYL ETHER ACETATE 111-15-9	The vapour is heavier than air	Reacts with strong oxidants causing fire and explosion hazard	3
ETHYLENE GLYCOL, MONOMETHYL ETHER ACETATE 110-49-6			3
ETHYLENE GLYCOL METHYL ETHER 109-86-4		The substance can form explosive peroxides. •The substance decomposes on burning and on contact with strong caustics, producing toxic gas. •Reacts with strong oxidants causing fire and explosion hazard	3
ETHYLENE GLYCOL PHENYL ETHER 122-99-6	The vapour is heavier than air	Reacts with oxidants
ETHYLENE GLYCOL MONOPROPYL ETHER 2807-30-9	The vapour is heavier than air and may travel along the ground; distant ignition possible
PROPYLENE GLYCOL MONOMETHYL ETHER 107-98-2		The substance can presumably form explosive peroxides. •Reacts with strong oxidants

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 05:57

Glycol Ethers: Health Hazards

Chemical Name CAS-Number	ICSC Short-Term Exposure	ICSC Long-Term Exposure	ICSC Routes of Exposure and Symptoms	US NIOSH Target Organs & Routes of Entry	US NIOSH Symptoms
1,4-BUTANEDIOL DIGLYCIDYL ETHER 2425-79-8	eyes; skin; resp tract; lungs	skin
DIETHYLENE GLYCOL DIETHYL ETHER 112-36-7	eyes; skin; resp tract		Inhalation: cough Skin: redness Eyes: redness Ingestion: diarrhoea, headache, nausea, vomiting
DIETHYLENE GLYCOL DIGLYCIDYL ETHER 4206-61-5	lungs	skin; CNS; blood; kidneys
DIETHYLENE GLYCOL MONOBUTYL ETHER 112-34-5	eyes; skin; CNS	skin	Skin: may be absorbed, redness Eyes: redness, pain Ingestion: headache, unconsciousness, vomiting
DIETHYLENE GLYCOL MONOETHYL ETHER 111-90-0	lungs	skin
DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3	eyes; skin; resp tract	skin; lungs; may impair male fertility	Skin: redness, roughness Eyes: redness
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8			Skin: dry skin	Resp sys; eyes; CNS Inh; abs; ing; con	Irrit eyes, nose, throat; weak, li-head, head
2-ETHOXYETHANOL 110-80-5	eyes; skin; resp tract; CNS; liver; kidneys	skin; male fertility; birth defects	Inhalation: cough, drowsiness, headache, shortness of breath, sore throat, weakness Skin: may be absorbed Eyes: Blurred vision Ingestion: abdominal pain, nausea, vomiting	Resp sys; eyes; blood; kidneys; liver; repro sys; hemato sys Inh; abs; ing; con	In animals: irrit eyes, resp sys; blood changes; liver, kidney, lung damage; repro, terato effects
ETHYLENE GLYCOL ETHYL ETHER ACETATE 111-15-9	CNS; blood	liver; kidneys	Inhalation: cough, drowsiness, headache, nausea, shortness of breath, sore throat, vomiting Skin: may be absorbed, dizziness, headache, nausea and vomiting Eyes: blurred vision Ingestion: abdominal pain, drowsiness, headache, nausea, vomiting	Resp sys; eyes; GI tract; repro sys; hemato sys Inh; abs; ing; con	Irrit eyes, nose; vomit; kidney damage; para; in animals: repro, terato effects
ETHYLENE GLYCOL METHYL ETHER 109-86-4	eyes; resp tract; CNS; liver; kidneys		Inhalation: confusion, dizziness, headache, nausea, unconsciousness, vomiting, weakness Skin: may be absorbed Eyes: blurred vision	Eyes; resp sys; CNS; blood; kidneys; repro sys; hemato sys Inh; abs; ing; con	Irrit eyes, nose, throat; head, drow, weak; ataxia, tremor, som; anemic pallor, in animals: repro, terato effects
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2	eyes; skin; resp tract; CNS; liver; kidneys	skin	Inhalation: cough, drowsiness, headache, nausea Skin: may be absorbed, dry skin Eyes: redness, pain, blurred vision Ingestion: abdominal pain, diarrhoea, nausea, vomiting	Liver; kidneys; lymphoid sys; skin; blood; eyes; resp sys; hemato sys; CNS Inh; abs; ing; con	Irrit eyes, skin, nose, throat; hemolysis, hemog; CNS depres, head, vomit
ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE 112-07-2	eyes; skin; resp tract; kidneys; blood	skin; liver; bone marrow	Inhalation: cough, headache, nausea Skin: redness Eyes: redness	Eyes; skin; resp sys; CNS; hemato sys; blood; kidneys; liver; lymphoid sys imh	Irrit eyes, skin, nose, throat; hemolysis, hemog; CNS depres, head, vomit
ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE 110-49-6	CNS	skin; liver; kidneys;blood	Inhalation: Confusion, dizziness, headache, nausea, unconsciousness, vomiting, weakness. Skin: Dizziness, headache, nausea, vomiting Eyes: Blurred vision. Ingestion: Abdominal pain, burning sensation, confusion, dizziness, headache, nausea, unconsciousness.	Eyes; resp sys; kidneys; brain; CNS; PNS; repro sys; hemato sys Inh; abs; ing; con	Irrit eyes, nose, throat; kidney, brain damage; in animals: narco; repro, terato effects
ETHYLENE GLYCOL MONOPROPYL ETHER 2807-30-9	eyes; skin; resp tract; lungs	blood; spleen; kidneys	Inhalation: confusion, cough, headache, nausea, sore throat, symptoms may be delayed Skin: redness, burning sensation Eyes: redness, pain Ingestion: confusion, diarrhoea, headache, nausea, vomiting
ETHYLENE GLYCOL PHENYL ETHER 122-99-6	eyes; skin		Inhalation: sore throat Skin: redness Eyes: redness, pain Ingestion: abdominal pain, sore throat
PROPYLENE GLYCOL MONOMETHYL ETHER 107-98-2	eyes; skin; resp tract; nose; throat; CNS		Inhalation: dizziness, drowsiness, headache, nausea Skin: dry skin, redness Eyes: lacrimation, redness Ingestion: diarrhoea, drowsiness, headache, nausea, vomiting, incoordination or possible unconsciousness	Eyes; skin; resp sys; CNS Inh; ing; con	Irrit eyes, skin, nose, throat; head, nau, li-head, drow, inco; vomit, diarr

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 05:54

Glycol Ethers: Chemical Identification

Chemical Formula	Chemical	Synonyms UN Code	CAS-Number
2425798	1,4-BUTANEDIOL DIGLYCIDYL ETHER	1,4-Bis(2,3-epoxypropoxy)butane; 1,4-Bis(glycidyloxy)butane; 1,4-Butane diglycidyl ether; Butanediol diglycidyl ether; Butane-1:4-diol diglycidyl ether; 2,2'-(1,4-Butanediylbis(oxymethylene))bisoxirane; 1,4-Diglycidloxybutane	2425-79-8
112367	DIETHYLENE GLYCOL DIETHYL ETHER	Bis(2-ethoxyethyl) ether; Diethyl carbitol; 3,6,9-Trioxaundecane	112-36-7
4206615	DIETHYLENE GLYCOL DIGLYCIDYL ETHER	Ether, bis(2-(2,3-epoxypropoxy)ethyl); Oxirane, 2,2'-(oxybis(2,1-ethanediyloxymethylene))bis-; 2,2'-(Oxybis(2,1-ethanediyloxymethylene))bisoxirane	4206-61-5
112345	DIETHYLENE GLYCOL MONOBUTYL ETHER	Butoxydiethylene glycol; Butoxydiglycol; 2-(2-Butoxyethoxy)ethanol; Butyl carbitol; Glycol-n-butyl ether; Diglycol monobutyl ether	112-34-5
124174	DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE	Acetic acid 2-(2-butoxyethoxy)ethyl ester; 2-(2-Butoxyethoxy)ethyl acetate; Butyl carbitol acetate; Diethylene glycol butyl ether acetate	124-17-4
111900	DIETHYLENE GLYCOL MONOETHYL ETHER	Carbitol cellosolve; Ethyl diethylene glycol; Ethanol, 2-(2-ethoxyethoxy)	111-90-0
111773	DIETHYLENE GLYCOL MONOMETHYL ETHER	Diethylene glycol monomethyl ether; Dowanol DM; Ethylene diglycol monomethyl ether; Methoxydiglycol	111-77-3
110714	1,2-DIMETHOXYETHANE	Dimethoxyethane; Dimethylcellosolve; 2,5-Dioxahexane; Ethylene dimethyl ether; Ethylene glycol dimethyl ether UN2252	110-71-4
34590948	DIPROPYLENE GLYCOL METHYL ETHER	Arcosolv; Dipropylene Dowanol DPM; Dowanol-50B; 1-(2-Methoxyisopropoxy)-2-propanol	34590-94-8
1002671	2-ETHOXYETHYL 2-METHOXYETHYL ETHER	Diethylene glycol ethyl methyl ether	1002-67-1
110805	ETHYLENE GLYCOL ETHYL ETHER ACETATE	Cellosolve; Dowanol EE; 2-Ethoxyethanol; Ethyl cellosolve; Glycol monoethyl ether; Hydroxy ether UN1171	110-80-5
629141	ETHYLENE GLYCOL DIETHYL ETHER	1,2-Diethoxyethane; Diethyl cellosolve; Ethylene glycol diethyl ether UN1153	629-14-1
109864	ETHYLENE GLYCOL METHYL ETHER	Glycol monomethyl ether; 2-Methoxyethanol; Methoxyhydroxyethane; Methyl cellosolve UN1188	109-86-4
111762	ETHYLENE GLYCOL MONOBUTYL ETHER	Butoxyethanol; Butyl cellosolve; 2-Butoxyethanol; Glycol butyl ether; Glycol monobutyl ether; Monobutyl glycol ether UN2369	111-76-2
112072	ETHYLENE GLYCOL MONOBUTYL ETHYL ETHER ACETATE		112-07-2
111159	ETHYLENE GLYCOL MONOETHYL ETHER ACETATE	Cellosolve acetate; Ethoxy acetate; Ethoxyethyl acetate UN1172	111-15-9
110496	ETHYLENE GLYCOL, MONOMETHYL ETHER ACETATE	Acetic acid 2-methoxyethyl ester; Ethylene glycol methyl ether acetate; Ethylene glycol monomethyl ether acetate; Glycol ether EM acetate; Glycol monomethyl ether acetate; Mecsac; 2-Methoxyethanol, acetate; 2-Methoxyethyl acetate; Methyl cellosolve acetate; Methyl glycol acetate; Methyl glycol monoacetate UN1189	110-49-6
2807309	ETHYLENE GLYCOL MONOPROPYL ETHER	Ektasolve EP; 2-Propoxyethanol; Propyl cellosolve	2807-30-9
122996	ETHYLENE GLYCOL PHENYL ETHER	Arosol; Dowanol EP; Dowanol EPH; 2-Phenoxyethanol; Glycol monophenyl ether; Phenyl cellosolve	122-99-6
107982	PROPYLENE GLYCOL MONOMETHYL ETHER	Glycol ether PM; Methoxy ether of propylene glycol; 1-Methoxy-2-propanol; Propasol solvent M; Propylene glycol methyl ether; Propylene glycol monomethyl ether UN3092	107-98-2

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Published in 104. Guide to Chemicals

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Sunday, 07 August 2011 02:16

Fluorocarbons: Physical & Chemical Properties

Chemical Name CAS-Number	Colour/Form	Boiling Point (°C)	Melting Point (°C)	Molecular Weight	Solubility in Water	Relative Density (water=1)	Relative Vapour Density (air=1)	Vapour Pressure/ (Kpa)	Inflam. Limits	Flash Point (°C)	Auto Ignition Point (°C)
BENZOTRIFLUORIDE 98-08-8	water white liquid	103.46	-29.05	146.11		1.1886	5.04	@ 0 °C		12 cc
BROMOTRIFLUOROMETHANE 75-63-8	colourless gas	-57.86	-166	148.92	insol	1.5800	3.8
CHLORODIFLUOROBROMOMETHANE 353-59-3	colourless gas	-4	-161	165.37	insol	@ 15 °C (liquid)	5.7
1,1,1-CHLORODIFLUOROETHANE 75-68-3	colourless gas	-9.2	-130.8		@ 25 °C	@ -9 °C		@ 25 °C	6.2 ll 17.9 ul
CHLORODIFLUOROMETHANE 75-45-6	colourless gas	-40.8	-146	86.47	v sol	@ 21 °C	2.98	908
CHLOROFLUOROMETHANE 593-70-4		-9.1	-133	68.48
CHLOROPENTAFLUOROETHANE 76-15-3	colourless gas	-38	-106	154.47	insol	@ -20 °C	5.54	711.7
CHLOROTRIFLUOROETHANE 1330-45-6		6.93	-105.5	118.49		@ 0 °C/4 °C
CHLOROTRIFLUOROETHYLENE 79-38-9	colourless gas	-27.9	-157.5	116.47		1.305			8.4 ll 38.7 ul
CHLOROTRIFLUOROMETHANE 75-72-9	colourless gas	-81.1	-181	104.46	insol	1.3	3.65	@ 15 °C
DICHLORODIFLUOROMETHANE 75-71-8	colourless gas; liquified compressed gas	-29.8	-158	120.91	sol	@ -29.8 °C	4.1	568
DICHLOROFLUOROMETHANE 75-43-4	colourless heavy gas	9	-135	102.92	insol	@ 9 °C	3.82	160			522
DICHLOROTETRAFLUOROETHANE 1320-37-2	colourless gas	3.6	-94	170.92	insol	@ 25 °C
DIFLUORODIBROMOMETHANE 75-61-6	colourless heavy liquid; colourless gas	25	-146 MEGALON -110.1	209.83 MEGALON 207.81	sol	@ 15 °C/4 °C	7.2
1,1-DIFLUOROETHANE 75-37-6	colourless gas	-24.7	-117	66.05	insol	0.95	2.3	@ 25 °C	3.7 ll 18 ul
ENFLURANE 13838-16-9	liquid	56.5			sl sol	1.52
HALOTHANE 151-67-7	colourless, volatile liquid	50.2		197.39	3900 mg/l	@ 20 ° C/4 ° C		@ 20 ° C
HEXAFLUOROACETONE 684-16-2	colourless gas	-27	-122	166.03		@ 25 °C (liquid)
HEXAFLUOROPROPYLENE 116-15-4	gas	-29.4	-156.2	150.02		1.583 at -40 ° C/4 ° C
PERFLUOROISOBUTYLENE 382-21-8	gas	7		200.03		@ 0 °C
TEFLON 9002-84-0	grayish white transparent thin sheets; soft, waxy, milk-white solid; white powder					2.25
1,1,2,2-TETRACHLORO-1,2-DIFLUOROETHANE 76-12-0	colourless liquid or solid	93	25	203.83	insol	@ 25 °C/4 °C	7.03	40 torr
1,1,1,2-TETRACHLORO-2,2-DIFLUOROETHANE 76-11-9	colourless liquid or solid	91.5	40.6	203.82	insol	1.65	7.0	40 mm Hg
TETRAFLUOROETHYLENE 116-14-3	colourless gas	-76.3	-142.5	100.02	insol	@ -76.3 °C	3.87		10.0 ll 50.0 ul		180
TETRAFLUOROMETHANE 75-73-0	colourless gas	-127.8	-183.6	88.01	sl sol	@ 25 °C	3.04				>1100
1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE 76-13-1	colourless gas; volatile liquid	47.7	-36.4	187.38	0.017 g/100 g	@ 25 °C/4 °C	6.5	36		350
TRICHLOROFLUOROMETHANE 75-69-4	colourless liquid	23.7	-111	137.4	@ 25 °C	@ 17.2 °C/4 °C (liquid)	4.7	89	non flammable
TRIFLUOROMETHANE 75-46-7	colourless gas	-84.4	-160	70.02	sol	@ -100 °C (liquid)		30,000 mm Hg
VINYL FLUORIDE 75-02-5	colourless gas	-72.2	-160.5	46.05	insol	1.58			2.6 vol% ll 21.7 vol% ul		725 deg F
VINYLIDENE FLUORIDE 75-38-7	colourless gas	-83	-144	64.04	insol	0.617	2.2	3600	5.5 ll 21.3 ul	flammable gas

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 02:15

Fluorocarbons: Physical & Chemical Hazards

Chemical Name CAS-Number	Physical	Chemical	UN Class or Division / Subsidiary Risks
BENZOTRIFLUORIDE 98-08-8			3
BROMOTRIFLUOROMETHANE 75-63-8	The vapour is heavier than air and may accumulate in low ceiling spaces causing deficiency of oxygen	The substance decomposes on heating producing hydrogen bromide, hydrogen fluoride • The substance is a strong reducing agent and reacts with oxidants • Reacts with strong oxidants, aluminium	2.2
CHLORODIFLUOROBROMOMETHANE 353-59-3	The gas is heavier than air and may accumulate in low ceiling spaces causing deficiency of oxygen	The substance decomposes on contact with open flames or very hot surfaces, producing toxic gases	2.2
1,1,1-CHLORODIFLUOROETHANE 75-68-3			2.1
CHLORODIFLUOROMETHANE 75-45-6	The gas is heavier than air and may accumulate in low ceiling spaces causing deficiency of oxygen	On contact with hot surfaces or flames this substance decomposes forming corrosive and very toxic fumes (hydrogen chloride, phosgene, chlorine, hydrogen fluoride) • Reacts violently with powdered metals such as aluminium and zinc, causing fire and explosion hazard • Attacks magnesium and its alloys	2.2
CHLOROPENTAFLUOROETHANE 76-15-3	The vapour is heavier than air and may accumulate in low ceiling spaces causing deficiency of oxygen	The substance decomposes on heating producing hydrogen chloride, hydrogen fluoride • Reacts with strong oxidants	2.2
CHLOROTRIFLUOROMETHANE 75-72-9		On contact with hot surfaces or flames this substance decomposes forming HCl, HF, Carbonyl halides • The substance decomposes in a fire or on contact with certain metals producing toxic products	2.2
DICHLORODIFLUOROMETHANE 75-71-8	The gas is heavier than air and may accumulate in low ceiling spaces causing deficiency of oxygen	On contact with hot surfaces or flames this substance decomposes forming corrosive and very toxic fumes (hydrogen chloride, phosgene, chlorine, hydrogen fluoride) • Reacts violently with metals such as calcium, magnesium, potassium, sodium, zinc and powdered aluminium • Attacks magnesium and its alloys	2.2
DICHLOROFLUOROMETHANE 75-43-4	The gas is heavier than air	The substance decomposes on heating producing corrosive and highly toxic fumes (hydrogen chloride, hydrogen fluoride, and phosgene) • Reacts violently with chemically active metals • Reacts with acids or acid fumes producing highly toxic fumes (chlorine, fluorine) • Attacks some forms of plastics, rubber and coatings	2.2
DICHLOROTETRAFLUOROETHANE 1320-37-2			2.2
DIFLUORODIBROMOMETHANE 75-61-6			9
1,1-DIFLUOROETHANE 75-37-6			2.1
ENFLURANE 13838-16-9		The substance decomposes on heating or on burning producing toxic and corrosive fumes (hydrogen chloride, hydrogen fluoride, phosgene)
HEXAFLUOROACETONE 684-16-2			2.3/ 8
1,1,2,2-TETRACHLORO-1,2-DIFLUOROETHANE 76-12-0			2.2
1,1,1,2-TETRACHLORO-2,2-DIFLUOROETHANE 76-11-9			2.2
TETRAFLUOROMETHANE 75-73-0	The gas is heavier than air and may accumulate in low ceiling spaces causing deficiency of oxygen	On contact with hot surfaces or flames this substance decomposes forming hydrofluoric acid	2.2
1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE 76-13-1	The vapour is heavier than air and may accumulate in low ceiling spaces causing deficiency of oxygen	On contact with hot surfaces or flames this substance decomposes forming corrosive and very toxic fumes (carbonylfluoride, hydrogen chloride, phosgene, chlorine, hydrogen fluoride) • Reacts violently with calcium, potassium, sodium and powdered metals such as aluminium, beryllium, magnesium and zinc, causing fire and explosion hazard • Attacks alloys containing more than 2% magnesium
TRICHLOROFLUOROMETHANE 75-69-4	The gas is heavier than air • The vapour is heavier than air and may accumulate in low ceiling spaces causing deficiency of oxygen	On contact with hot surfaces or flames this substance decomposes forming corrosive and very toxic fumes (hydrogen chloride, phosgene, chlorine, hydrogen fluoride) • Reacts violently with metals and various powdered metals, such as aluminium, barium, calcium, magnesium and sodium
TRIFLUOROMETHANE 75-46-7			2.2
VINYL FLUORIDE 75-02-5			2.1
VINYLIDENE FLUORIDE 75-38-7	The gas is heavier than air and may travel along the ground; distant ignition possible, and may accumulate in low ceiling spaces causing deficiency of oxygen • As a result of flow, agitation, etc, electrostatic charges can be generated	The substance can form explosive peroxides • The substance can polymerize with fire or explosion hazard • Heating may cause violent combustion or explosion • The substance decomposes on burning producing hydrogen fluoride • Reacts violently with oxidants and hydrogen chloride

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 02:14

Fluorocarbons: Health Hazards

Chemical Name CAS-Number	ICSC Short-Term Exposure	ICSC Long-Term Exposure	ICSC Routes of Exposure and Symptoms	US NIOSH Target Organs & Routes of Entry	US NIOSH Symptoms
BROMOTRIFLUOROMETHANE 75-63-8			Inhalation: dizziness Skin: redness, on contact with liquid: frostbite Eyes: severe deep burns	Heart; CNS Inh; con (liq)	Li-head; card arrhy; liq: frostbite
CHLORODIFLUOROBROMOMETHANE 353-59-3	skin		Inhalation: drowsiness, unconsciousness Skin: On contact with liquid: frostbite Eyes: severe deep burns
CHLORODIFLUOROMETHANE 75-45-6	resp tract; skin; CNS; CVS		Inhalation: confusion, drowsiness, unconsciousness Skin: on contact with liquid: frostbite Eyes: redness, pain	Resp sys; CVS; CNS; liver; spleen; kidneys Inh; con (liq)	Irrit resp sys; conf, drow, ringing in ears; heart palp, card arrhy; asphy; liver, kidney, spleen inj; liq: frostbite
CHLOROPENTAFLUOROETHANE 76-15-3	skin		Inhalation: dizziness, unconsciousness Skin: on contact with liquid: frostbite Eyes: severe deep burns	Skin; CNS; CVS Inh; con (liq)	Dysp; dizz, inco, narco; nau, vomit; heart palp, card arrhy, asphy; liq: frostbite, derm
CHLOROTRIFLUOROMETHANE 75-72-9			Inhalation: confusion, headache Skin: on contact with liquid: frostbite
DICHLORODIFLUOROMETHANE 75-71-8	resp tract; skin; CNS; CVS; lungs	skin	Inhalation: confusion, drowsiness, unconsciousness Skin: on contact with liquid: frostbite Eyes: redness, pain	CVS; PNS Inh; con (liq)	Dizz, tremor, asphy, uncon, card arrhy, card arrest; liq: frostbite
DICHLOROFLUOROMETHANE 75-43-4	skin; CNS; CVS		Inhalation: drowsiness, unconsciousness Skin: on contact with liquid: frostbite	Resp sys; CVS Inh; con (liq)	Asphy, card arrhy, card arrest; liq: frostbite
DIFLUORODIBROMOMETHANE 75-61-6				Resp sys; CNS; liver Inh; ing; con	In animals: irrit resp sys; CNS symptoms; liver damage
ENFLURANE 13838-16-9	CNS	liver	Inhalation: drowsiness, weakness	Eyes; CNS Inh; ing; con	Irrit eyes; CNS depres, analgesia, anes, sez, resp depres
HALOTHANE 151-67-7	cardiovascular system; CNS	liver; kidneys; reproductive toxicity in humans	Inhalation: Confusion, dizziness, drowsiness, nausea. Skin: Dry skin, roughness. Eyes: Redness.	Eyes; skin; resp sys; CVS; CNS; liver; kidneys; repro sys Inh; ing; con	In animals: irrit eyes, skin, muc memb; liver damage
OCTAFLUOROISOBUTYLENE 382-21-8	resp tract		Inhalation: Cough, irritant, shortness of breath, pulmonary oedema, sore throat, irritant. symptoms may be delayed Skin: Redness, pain. Eyes: Redness, pain.
PERFLUOROISOBUTYLENE 382-21-8			Inhalation: cough, irritantshortness of breath, pulmonary oedema, sore throat, irritant, symptoms may be delayed Skin: redness, pain Eyes: redness, pain
1,1,1,2-TETRACHLORO-2,2-DIFLUOROETHANE 76-11-9				Resp sys; skin; eyes; CNS Inh; ing; con	Irrit eyes, skin; CNS depres; pulm edema; drow; dysp
1,1,2,2-TETRACHLORO-1,2-DIFLUOROETHANE 76-12-0				Resp sys; skin; eyes; CNS Inh; ing; con	In animals: irrit eyes, skin; conj; pulm edema; narco
TETRAFLUOROMETHANE 75-73-0	CNS		Inhalation: confusion, headache Skin: on contact with liquid: frostbite
1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE 76-13-1	resp tract;skin; CNS; CVS		Inhalation: confusion, cough, drowsiness, unconsciousness Skin: redness, pain Eyes: redness, pain	Skin; heart; CNS; CVS Inh; ing; con	Irrit skin, throat; drow; derm; CNS depres; in animals: card arrhy, narco
TRICHLOROFLUOROMETHANE 75-69-4	eyes; skin; resp tract		Inhalation: confusion, drowsiness, shortness of breath, unconsciousness Skin: on contact with liquid: frostbite Eyes: redness, pain	CVS; skin; resp sys Inh; ing; con	Inco, tremor; derm; card arrhy, card arrest; asphy; liq: frostbite
VINYL FLUORIDE 75-02-5	eyes; resptract;nervous system		Inhalation: Dizziness, shortness of breath. Skin: On contact with liquid: frostbite. Eyes: On contact with liquid: frostbite.	CNS Inh; con (liq)	Head, dizz, conf, inco, narco, nau, vomit; liq: frostbite
VINYLIDINE FLUORIDE 75-38-7			Inhalation: dizziness, drowsiness, shortness of breath Skin: on contact with liquid: frostbite Eyes: severe deep burns	CNS Inh; con (liq)	Dizz, head, nau; liq: frostbite

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Published in 104. Guide to Chemicals

Sunday, 07 August 2011 02:12

Fluorocarbons: Chemical Identification

Chemical Formula	Chemical	Synonyms UN Code	CAS-Number
75638	BROMOTRIFLUOROMETHANE	Bromofluoroform; Bromotrifluoromethane; F-13B1; Freon 13B1; Halon 1301; R13b1; Trifluorobromomethane; Trifluoromonobromomethane UN1009	75-63-8
75683	1-CHLORO-1,1-DIFLUOROETHANE	CFC 142b; Chloroethylidene fluoride; 1,1-Difluoro-1-chloroethane; Freon 142; Freon 142B; Hydrochlorofluorocarbon 142B; R142B UN2517	75-68-3
353593	CHLORODIFLUOROBROMOMETHANE	Bromochlorodifluoromethane; Flugex 12B1; Fluorocarbon 1211; Freon 12B1; Halon 1211; R12B1 UN1974	353-59-3
75456	CHLORODIFLUOROMETHANE	CFC 22; Difluorochloromethane; Difluoromonochloromethane; Eskimon 22; F 22; FC 22 UN1018	75-45-6
593704	CHLOROFLUOROMETHANE	CFC 31; FC 31; freon 31; Monochloromonofluoromethane; R 31; R 31 (refrigerant)	593-70-4
76153	CHLOROPENTAFLUOROETHANE	Chloropentafluoroethane; Fluorocarbon-115; Freon 115; Genetron 115; Halocarbon 115; Monochloropentafluoroethane; R115 UN1020	76-15-3
79389	CHLOROTRIFLUOROETHYLENE	1-Chloro-1,2,2-trifluoroethylene; 2-Chloro-1,1,2-trifluoroethylene; Ctfe; R1113; Trifluorochloroethylene; 1,1,2-Trifluoro-2-chloroethylene UN1082	79-38-9
75729	CHLOROTRIFLUOROMETHANE	Arcton 3; F 13; Freon 13; Genetron 13; Monochlorotrifluoromethane; R 13; Trifluorochloromethane; Trifluoromethyl chloride; Ttrifluoromonochlorocarbon UN1022	75-72-9
76142	1,2-DICHLORO-1,1,2,2-TETRAFLUOROETHANE	Cryofluoran; Dichlorotetrafluoroethane; F 114; FC 114; Fluorane 114; Fluorocarbon 114; R 114; 1,1,2,2-tetrafluoro-1,2-dichloroethane	76-14-2
75718	DICHLORODIFLUOROMETHANE	Arcton 6; Arcton 12; Difluorodichloromethane; Electro-cf 12; F 12; FC 12; Fluorocarbon-12; Freon 12; Eskimon 12; Freon f-12 UN1028	75-71-8
75434	DICHLOROFLUOROMETHANE	Algofrene type 5; Arcton 7; Fluorodichloromethane; Freon 21; Genetron 21; FC-21; R21 UN1029	75-43-4
75616	DIFLUORODIBROMOMETHANE	Dibromodifluoromethane; Freon 12-b2; Halon 1202; R12b2 UN1941	75-61-6
75376	DIFLUOROETHANE	Algofrene type 67; Eethylene fluoride; Ethylidene difluoride; Ethylidene fluoride; FC 152a; Freon 152; Genetron 100; Genetron 152a; Halocarbon 152a	75-37-6
13838169	ENFLURANE	2-Chloro-1-(difluoromethoxy)-1,1,2-trifluoroethane; 2-Chloro-1,1,2-trifluoroethyl difluoromethyl ether; Ethrane; Methylflurether	13838-16-9
151677	HALOTHANE	Bromochlorotrifluoroethane	151-67-7
684162	HEXAFLUOROACETONE	Acetone, hexafluoro-; 6FK; NCI-C56440; 2-Propanone, 1,1,1,3,3,3-hexafluoro UN2420	684-16-2
382218	OCTAFLUOROISOBUTYLENE		382-21-8
382218	PERFLUOROISOBUTYLENE	Iisobutene, octafluoro-; Octafluoroisobutylene; Octafluoro-sec-butene; 1-Propene, 1,1,3,3,3-pentafluoro-2-trifluoromethyl PFIB	382-21-8
9002840	TEFLON	Poly(ethylene tetrafluoride); Polytetrafluoroethene; Polytetrafluoroethylene; PTFE	9002-84-0
76119	1,1,1,2-TETRACHLORO-2,2-DIFLUOROETHANE	Halocarbon 112a; Refrigerant 112a	76-11-9
76120	1,1,2,2-TETRACHLORO-1,2-DIFLUOROETHANE	1,2-Difluoro-1,1,2,2-tetrachloroethane; F-112; FC 112; Freon 112; Freon r 112; Halocarbon 112; Refrigerant 112; 1,1,2,2-Tetrachloro-1,2-difluoroethane	76-12-0
116143	TETRAFLUOROETHYLENE	Fluoroplast 4; perfluoroethene; Perfluoroethylene; Tetrafluorethylene UN1081	116-14-3
75730	TETRAFLUOROMETHANE	Arcton 0; Carbon fluoride; Carbon-tetrafluoride; F 14; FC 14; Freon 14; Halocarbon 14; Halon 14; Perfluoromethane; Tetrafluorocarbon; UN1982	75-73-0
98088	TOLUENE, a,a,a-TRIFLUORO	Bbenzenyl fluoride; Benzotrifluoride; Benzylidyne fluoride; Phenylfluoroform; (trifluoromethyl)benzene UN2338	98-08-8
76131	1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE	F 113; FC 113; Freon 113; Halocarbon 113; Isceon 113; Trichlorotrifluoroethane; 1,1,2-Trichlorotrifluoroethane; 1,2,2-Trichlorotrifluoroethan	76-13-1
75694	TRICHLOROFLUOROMETHANE	Eskimon 11; FC 11; Freon 11; Freon 11a; Freon 11b; Freon he; Freon mf	75-69-4
406906	2,2,2-TRIFLUOROETHYL VINYL ETHER	Ethene, (2,2,2-trifluoroethoxy)-; Fluoroxenefluoroxene; Fluorxene	406-90-6
75467	TRIFLUOROMETHANE	Arcton; Carbon trifluoride; Fluoroform; Fluoryl; Freon 23; Freon f-23; Genetron-23; Halocarbon 23; Methyl trifluoride; R 23 UN1984 UN3136	75-46-7
75025	VINYL FLUORIDE	Fluoroethylene	75-02-5
75387	VINYLIDENE FLUORIDE		75-38-7

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