Chemical Name CAS-Number |
ICSC Short-Term Exposure |
ICSC Long-Term Exposure |
ICSC Routes of Exposure and Symptoms |
US NIOSH Target Organs & Routes of Entry |
US NIOSH Symptoms |
BUTANE 106-97-8 |
Inhalation: drowsiness Skin: on contact with liquid: frostbite Eyes: on contact with liquid: frostbite |
CNS inh; con (liq) |
Drow, narco, asphy; liq: frostbite |
||
CYCLOHEXANE 110-82-7 |
eyes; skin; upper resp tract; lungs |
skin |
Inhalation: dizziness, headache, nausea Skin: redness Eyes: redness |
Eyes; resp sys; skin; CNS Inh; ing; con |
Irrit eyes, skin, resp sys; drow; derm; narco, coma |
CYCLOPENTANE 287-92-3 |
eyes; skin; upper resp tract; lungs; CNS |
skin |
Inhalation: dizziness, headache, nausea, unconsciousness, weakness Skin: redness Eyes: redness Ingestion: abdominal pain, diarrhoea, dizziness, nausea, sore throat |
Eyes; skin; resp sys; CNS Inh; ing; con |
Irrit eys, skin, nose, throat; li-head, dizz, euph, inco, nau, vomit, stupor; dry, cracking skin |
DECANE 124-18-5 |
lungs |
skin; kidneys; blood |
Inhalation: confusion, drowsiness Skin: dry skin, redness Eyes: redness, pain |
||
ETHANE 74-84-0 |
skin |
Inhalation: simple axphyxiant. Skin: on contact with liquid: frostbite Eyes: on contact with liquid: frosbite |
|||
HEPTANE 142-82-5 |
eyes; skin; resp tract; lungs; CNS |
skin |
Inhalation: dullness, headache Skin: dry skin, burning sensation Eyes: redness, pain Ingestion: abdominal cramps, nausea, vomiting |
Skin; resp sys; CNS Inh; ing; con |
Li-head, gidd, stupor, verti, inco; loss of appetite, nau; derm; chemical pneu (aspir liq); uncon |
HEXANE 110-54-3 |
eyes; skin; resp tract; lungs; CNS; liver |
skin; PNS; genes |
Inhalation: dizziness, drowsiness, dullness, headache, laboured breathing, nausea, unconsciousness, weakness Skin: dry skin, redness Eyes: redness, pain |
Skin; eyes; resp sys; CNS; PNS Inh; ing; con |
Irrit eyes, nose; li-head; nau, head; peri neur: numb extremities, musc weak; derm; gidd; chemical pneu (aspir liq) |
2-METHYLBUTANE 78-78-4 |
eyes; skin; resp tract; lungs; heart |
skin |
Inhalation: cough, dizziness, drowsiness, headache, shortness of breath, sore throat, irregular heartbeat Skin: dry skin, defats the skin redness Eyes: redness, pain Ingestion: abdominal pain, nausea, vomiting |
||
METHYLCYCLOHEXANE 108-87-2 |
lungs; CNS |
skin |
Inhalation: dizziness, drowsiness Skin: redness Eyes: redness Ingestion: nausea |
Resp sys; skin; eyes; CNS Inh; ing; con |
Irrit eyes, skin, nose, throat; li-head, drow; in animals: narco |
2-METHYLHEPTANE 592-27-8 |
skin |
Skin: redness |
|||
OCTANE 111-65-9 |
eyes; skin; resp tract; lungs |
skin |
Inhalation: confusion, dizziness, drowsiness, headache, laboured breathing, nausea, unconsciousness Skin: dry skin, redness Eyes: redness, painIngestion: vomiting |
Skin; eyes; resp sys; CNS Inh; ing; con |
Irrit eyes, nose; drow; derm; chemical pneu (aspir liq); in animals: narco |
PENTANE 109-66-0 |
lungs; CNS |
Inhalation: dizziness, drowsiness, headache, nausea, unconsciousness, vomiting Skin: dry skin |
Skin; eyes; resp sys; CNS Inh; ing; con |
Irrit eyes, skin, nose; derm; chemical pneu (aspir liq); drow; in animals: narco |
|
PROPANE 74-98-6 |
skin |
Inhalation: simple axphyxiant. Skin: on contact with liquid: frostbite Eyes: on contact with liquid: frosbite |
CNS Inh; con (liq) |
Dizz, conf, excitation, asphy; liq: frostbite |
|
2,2,4-TRIMETHYLPENTANE 540-84-1 |
eyes; skin; resp tract; kidneys; liver |
skin; kidneys; liver |
Inhalation: confusion, dizziness, headache, nausea, vomiting Skin: redness, pain Eyes: redness Ingestion: vomiting |
Chemical Formula |
Chemical |
Synonyms |
CAS-Number |
106978 |
BUTANE |
n-Butane; |
106-97-8 |
110827 |
CYCLOHEXANE |
Hexahydrobenzene; |
110-82-7 |
287923 |
CYCLOPENTANE |
Pentamethylene |
287-92-3 |
75194 |
CYCLOPROPANE |
Trimethylene |
75-19-4 |
124185 |
DECANE |
UN2247 |
124-18-5 |
75832 |
2,2-DIMETHYLBUTANE |
75-83-2 |
|
79298 |
2,3-DIMETHYLBUTANE |
2,3-Dimethylbutane |
79-29-8 |
463821 |
2,2-DIMETHYLPROPANE |
Neopentane |
463-82-1 |
74840 |
ETHANE |
Bimethyl; |
74-84-0 |
142825 |
HEPTANE |
Dipropyl methane; |
142-82-5 |
110543 |
HEXANE |
n-Hexane; |
110-54-3 |
75285 |
ISOBUTANE |
Propane, 2-methyl- |
75-28-5 |
107835 |
ISOHEXANE |
107-83-5 |
|
78784 |
2-METHYLBUTANE |
Ethyldimethylmethane; |
78-78-4 |
108872 |
METHYLCYCLOHEXANE |
Cyclohexylmethane; |
108-87-2 |
592278 |
2-METHYLHEPTANE |
592-27-8 |
|
96140 |
3-METHYLPENTANE |
96-14-0 |
|
111842 |
NONANE |
n-Nonane |
111-84-2 |
111659 |
OCTANE |
n-Octane |
111-65-9 |
109660 |
PENTANE |
UN1265 |
109-66-0 |
74986 |
PROPANE |
Dimethylmethane; |
74-98-6 |
540841 |
2,2,4-TRIMETHYLPENTANE |
Isobutyltrimethylmethane; |
540-84-1 |
Chemical Name |
Colour/Form |
Boiling Point ( °C) |
Melting Point ( °C) |
Molecular Weight |
Solubility in Water |
Relative Density (water=1) |
Relative Vapour Density (air=1) |
Vapour Pressure/ (Kpa) |
Inflam. |
Flash Point (°C) |
Auto Ignition Point ( °C) |
ACRIDINE |
rhombohedral needles or prisms from alcohol; monoclinic, orthorhombic; small colourless needles; orthorhombic plates, needles from diluted alcohol; small, colourless or faintly yellow crystals |
346 |
111 |
179.21 |
sl sol |
1.005 |
@ 129 °C |
||||
N-AMINOETHYLPIPERAZINE |
liquid |
220 |
-17.6 |
129.2 |
sol |
0.9837 |
4.4 |
93 oc |
|||
2-AMINOPYRIDINE |
white leaflets or large colourless crystals; white powder or crystals |
211 |
58 |
94.11 |
misc |
3.25 |
0.13 |
68 cc |
|||
BENZOGUANAMINE |
crystals |
227 |
187.20 |
0.6% |
@ 25 °C/4 °C |
||||||
1,2,3-BENZOTRIAZOLE |
needles from benzene; white to light tan, crystalline powder |
@ 15 mm Hg |
98.5 |
119.12 |
sl sol |
||||||
COUMARIN |
rhomboid, pyramidal crystals from ether; orthorhombic, rectangular plates; white, crystalline solid |
301.72 |
71 |
146.14 |
1 g/ 400 ml (cold) |
0.935 at 20/4 °C |
1 mm Hg at 106.0 °C |
||||
3,4,5,6-DIBENZOCARBAZOLE |
needles from ethanol |
158 |
267.34 |
||||||||
3,6-DICHLOROPICOLINIC ACID |
white crystalline solid; colourless crystals |
151-152 |
192.0 |
@ 25 °C |
0.8 |
0.003 Pa |
|||||
N-ETHYLMORPHOLINE |
colourless liquid |
138.5 |
-62.78 |
115.2 |
misc |
0.8996 |
4.0 |
@ 20 °C |
|||
2-MERCAPTOBENZOTHIAZOLE |
pale, yellow monoclinic needles or leaflets; yellowish powder; needles from alc or dilute methanol; yellowish to tan crystalline powder |
181 |
167.2 |
insol |
1.42 |
||||||
2-MERCAPTOBENZOTHIAZOLE DISULPHIDE |
pale yellow needles from benzene; free-flowing powder |
180 |
332.46 |
insol |
1.50 |
||||||
1-METHYL-2-PYRROLIDONE |
colourless liquid |
202 |
24 |
99.13 |
v sol |
@ 25 °C/ 25 °C |
3.4 |
@ 25 °C |
0.99 ll |
91 |
270 |
N-METHYLMORPHOLINE |
115-116 |
101.14 |
sol |
0.9051 |
|||||||
2-METHYLPYRIDINE |
colourless liquid |
129 |
-70 |
93.12 |
v sol |
0.9443 |
3.2 |
1.2 |
1.4 ll |
39 |
535 |
3-METHYLPYRIDINE |
colourless liquid |
143-144 |
-18.3 |
93.12 |
misc |
@ 15 °C/4 °C |
3.2 |
@ 25 °C |
1.3 ll |
38 cc |
|
4-METHYLPYRIDINE |
colourless liquid |
145 |
3.6 |
93.12 |
misc |
0.9548 |
3.2 |
@ 25 °C |
1.3 ll |
57 oc |
|
MORPHOLINE |
colourless liquid; mobile liquid |
128.9 |
-4.9 |
87.12 |
misc |
1.0007 |
3 |
1.06 |
2.0 ll |
38 oc |
310 |
NICOTINE |
colourless to pale yellow, oily liquid; thick, water-white, oil turning brown |
@ 745 mm Hg |
-79 |
162.23 |
misc |
1.0097 |
5.61 |
@ 62 °C |
0.7 ll |
95 |
244 |
NICOTINE TARTRATE |
white plates |
90 |
462.46 |
sol |
|||||||
N-NITROSONORNICOTINE |
yellow oil |
@ 0.2 mm Hg |
47 |
177.23 |
@ 154 °C |
||||||
PHENAZOPYRIDINE |
brownish-yellow crystals |
139 |
213.25 |
@ 25 °C (est) |
@ 25 °C |
||||||
PHENOTHIAZINE |
yellow, rhombic leaflets or diamond-shaped plates from toluene or butanol; yellow prisms from alcohol; grayish-green to greenish yellow powder, granules or flakes |
371 |
185.1 |
186.26 |
insol |
||||||
PHENYLENEPYRENE |
yellow plates or needles from light petroleum |
530 |
162.5-164 |
insol |
1.0x10- 10 torr |
||||||
PIPERAZINE |
plates or leaflets from ethanol; white to slightly off-white lumps or flakes; colourless, transparent, needle-like crystals |
146 |
106 |
86.14 |
v sol |
1.1 |
3.0 |
81 oc |
|||
PIPERAZINE DIHYDROCHLORIDE |
cream coloured crystalline powder; white needles |
159.07 |
41% |
||||||||
PIPERIDINE |
clear, colourless liquid |
@ 760 mm Hg |
-7 |
85.15 |
v sol |
0.8622 |
3.0 |
@ 29.2 °C |
16 cc |
||
1,3-PROPANE SULTONE |
colourless liquid or white crystals |
@ 0.039 atm. |
31 |
122.1 |
100 g/l |
@ 40 °C/4 °C |
|||||
PROPYLENE IMINE |
colourless, oily liquid |
66 |
-65 |
57.1 |
sol |
@ 16 °C/4 °C |
2.0 |
14.9 |
-39 cc |
||
PYRIDINE |
colourless liquid; slightly yellow |
115.2 |
-42 |
79.10 |
misc |
0.9819 |
2.73 |
2.0 |
1.8 ll |
17 cc |
482 |
PYRIMIDINE |
123.8 |
22 |
80.09 |
misc |
|||||||
PYRROLIDINE |
colourless to pale yellow liquid |
88.5-89 |
-57.8 |
71.12 |
misc |
@ 22.5 °C/4 °C |
2.45 |
@ 39 °C |
@ -2°C |
||
2-PYRROLIDINONE |
liquid |
@742 mm Hg |
25 |
85.1 |
v sol |
1.120 |
2.93 |
110 cc |
|||
QUINOLINE |
colourless to brown liquid |
237.7 |
-15 |
129.16 |
insol |
1.0929 |
4.45 |
0.1 |
1.2 ll |
99 |
480 |
SULPHOLANE |
white or creamy white, crystalline powder |
285 |
27.4-27.8 |
120.16 |
misc |
@ 30 °C/4 °C |
@ 27.6 °C |
177 oc |
|||
TETRAHYDROTHIOPHENE |
water-white liquid |
121.0 |
-96.1 |
88.2 |
insol |
0.9987 |
3.05 |
@ 25 °C |
1.1 ll |
12 |
200 |
THIOPHENE |
colourless liquid |
84.16 |
-38.25 |
84.14 |
insol |
1.06494 |
2.9 |
@ 12.5 °C |
-1 |
||
2-VINYLPYRIDINE |
colourless liquid |
159-160 |
159-160 |
105.1 |
sl sol |
0.9983 |
@ 44.5 °C |
Chemical Name |
Physical |
Chemical |
UN Class or Division / Subsidiary Risks |
N-AMINOETHYLPIPERAZINE |
8 |
||
2-AMINOPYRIDINE |
Dust explosion possible if in powder or granular form, mixed with air |
The substance decomposes on burning producing toxic gases and vapours including nitrous oxides • Reacts with strong oxidants causing fire and explosion hazard • The substance is a strong base that is soluble in water |
6.1 |
BENZOGUANAMINE |
6.1 |
||
3,6-DICHLOROPICOLINIC ACID |
The substance decomposes on burning producing toxic and corrosive gases • Reacts with bases forming salts • Solutions of them are corrosive to aluminum, iron, and tin |
||
2-MERCAPTOBENZOTHIAZOLE |
On combustion, forms toxic gases (carbon monoxide and sulphur compounds) • The substance decomposes on heating and on burning producing toxic and irritating fumes (sulphur and nitrogen oxides) • Reacts with acids with the formation of highly toxic fumes of sulphur compounds • Reacts with acids or acid fumes producing toxic fumes (sulphur compounds) |
||
2-MERCAPTOBENZOTHIAZOLE DISULPHIDE |
On combustion, forms toxic gases: carbon, sulphur and nitrogen oxides • Reacts with strong oxidants and acids |
||
2-METHYLPYRIDINE |
The substance decomposes on heating producing toxic fumes (nitrogen oxides) • Reacts with oxidants and strong acids • Attacks copper and its alloys |
3 |
|
3-METHYLPYRIDINE |
The substance decomposes on heating producing toxic fumes (nitrogen oxides) • Reacts with oxidants and strong acids |
3 |
|
4-METHYLPYRIDINE |
The substance decomposes on heating producing toxic fumes (nitrogen oxides) • Reacts with oxidants and strong acids |
3 |
|
1-METHYL-2-PYRROLIDONE |
The substance decomposes on heating above 315 °C producing toxic fumes • Reacts with strong acids • Attacks aluminium |
||
MORPHOLINE |
The substance decomposes on heating producing toxic fumes (nitrogen oxides) • The substance is a weak base • Reacts with strong oxidants causing fire hazard • Attacks copper and its compounds |
3 |
|
NICOTINE |
The substance decomposes on heating producing toxic fumes • Reacts violently with strong oxidants • Attacks rubber and some plastics |
||
NICOTINE TARTRATE |
Shock-sensitive compounds are formed with this substance • The substance decomposes on heating producing toxic fumes • The substance is a strong reducing agent and reacts with oxidants |
6.1 |
|
PHENOTHIAZINE |
The substance decomposes on heating and on burning producing toxic and irritating fumes including nitrogen oxides and sulphur oxides |
||
PHENYLENEPYRENE |
Upon heating, toxic fumes are formed |
||
PIPERAZINE |
8 |
||
PIPERIDINE |
The vapour is heavier than air and may travel along the ground; distant ignition possible |
The substance decomposes on heating and on burning producing toxic gases such as nitrogen oxides • The substance is a medium strong base • Reacts violently with oxidants |
3/ 8 |
PROPYLENE IMINE |
3 |
||
PYRIDINE |
The vapour is heavier than air and may travel along the ground; distant ignition possible |
On combustion, forms toxic fumes (amines) • The substance decomposes on heating or on burning producing toxic fumes (nitrogen oxides and hydrogen cyanide) • Reacts violently with strong oxidants and strong acids |
3 |
PYRROLIDINE |
3/ 8 |
||
2-PYRROLIDINONE |
The substance decomposes on heating producing toxic fumes • Reacts with strong acids cf • methylpyrrolidone • Attacks aluminium |
||
QUINOLINE |
The substance decomposes on heating and on burning producing toxic fumes of nitrogen oxides • Reacts with strong oxidants and maleine anhydride |
6.1 |
|
TETRAHYDROTHIOPHENE |
The vapour is heavier than air and may travel along the ground; distant ignition possible |
On combustion, forms toxic fumes • Reacts violently with strong oxidants and nitric acid • Attacks rubber |
3 |
THIOPHENE |
The vapour is heavier than air and may travel along the ground; distant ignition possible • As a result of flow, agitation, etc, electrostatic charges can be generated |
The substance decomposes on heating and on burning producing toxic and irritating fumes (sulphur oxides) • Reacts violently with oxidizing materials, including fuming nitric acid |
3 |
2-VINYLPYRIDINE |
6.1/ 3 |
For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance
Chemical Name CAS-Number |
ICSC Short-Term Exposure |
ICSC Long-Term Exposure |
ICSC Routes of Exposure and Symptoms |
US NIOSH Target Organs & Routes of Entry |
US NIOSH Symptoms |
2-AMINOPYRIDINE 504-29-0 |
Inhalation: convulsions, dizziness, headache, nausea, shortness of breath, weakness, increased blood pressure, collapse |
CNS; resp sys Inh; abs; ing; con |
Irrit eyes, nose, throat; head, dizz, excitement; nau; high BP; resp distress; weak; convuls; stupor |
||
3,6-DICHLOROPICOLINIC ACID 1702-17-6 |
eyes; resp tract |
liver; kidneys |
Inhalation: cough, dullness |
||
2-MERCAPTOBENZOTHIAZOLE 149-30-4 |
eyes |
skin |
Inhalation: cough Skin: redness Eyes: redness, pain |
||
2-MERCAPTOBENZOTHIAZOLE DISULPHIDE 120-78-5 |
eyes; skin; resp tract |
skin |
Inhalation: cough, sore throat Skin: may be absorbed, redness Eyes: redness |
||
2-METHYLPYRIDINE 109-06-8 |
eyes; skin; resp tract |
skin; CNS |
Inhalation: burning sensation, cough, dizziness, drowsiness, headache, laboured breathing, nausea, sore throat, unconsciousness, weakness Skin: may be absorbed, dry skin, redness, burning sensation, pain, blisters Eyes: pain, blurred vision, severe deep burns Ingestion: abdominal pain, burning sensation, diarrhoea, vomiting |
||
3-METHYLPYRIDINE 108-99-6 |
eyes; skin; resp tract |
skin; CNS |
Inhalation: burning sensation, cough, dizziness, drowsiness, headache, laboured breathing, nausea, sore throat, unconsciousness, weakness Skin: may be absorbed, dry skin, redness, burning sensation, pain, blisters Eyes: pain, blurred vision, severe deep burns Ingestion: abdominal pain, burning sensation, diarrhoea, vomiting |
||
4-METHYLPYRIDINE 108-89-4 |
eyes; skin; resp tract |
skin; CNS |
Inhalation: burning sensation, cough, dizziness, drowsiness, headache, laboured breathing, nausea, sore throat, unconsciousness, weakness Skin: may be absorbed, dry skin, redness, burning sensation, pain, blisters Eyes: pain, blurred vision, severe deep burns Ingestion: abdominal pain, burning sensation, diarrhoea, vomiting |
||
1-METHYL-2-PYRROLIDONE 872-50-4 |
resp tract; eyes |
lungs; bone marrow; lymphatic system |
Inhalation: cough, laboured breathing Skin: may be absorbed Eyes: redness, pain, blurred vision, loss of vision; abdominal cramps, diarrhoea, laboured breathing |
||
MORPHOLINE 110-91-8 |
eyes; skin; resp tract; lungs |
liver; kidneys |
Inhalation: Ingestion: burning sensation, cough, laboured breathing, shortness of breath, sore throat Skin: may be absorbed, redness, skin burns, pain Eyes: redness, pain, blurred vision Ingestion: abdominal pain, cough, diarrhoea, vomiting |
Resp sys; eyes; skin; liver; kidneys Inh; abs; ing; con |
Irrit eyes, skin, nose, resp sys; vis dist; cough; in animals: liver, kidney damage |
NICOTINE 54-11-5 |
Inhalation: abdominal pain, headache, nausea, vomiting, tremors, convulsions, |
CNS; CVS; lungs; GI tract; repro sys Inh; abs; ing; con |
Nau, salv, abdom pain, vomit, diarr; head, dizz, hearing, vis dist; conf, weak, inco; paroxysmal atrial fibrl; convuls, dysp; in animals: terato effects |
||
NICOTINE TARTRATE 65-31-6 |
eyes; skin; CNS |
Inhalation: abdominal pain, headache, nausea, vomiting, tremors, convulsions Skin: may be absorbed Eyes: redness, pain |
|||
PHENOTHIAZINE 92-84-2 |
eyes; skin; resp tract; blood; liver |
skin |
Inhalation: cough, sore throat Skin: may be absorbed, redness, pain, itching, coloured yellow-brown skin Eyes: redness, pain, blurred vision |
Skin; CVS; liver; kidneys Inh; abs; ing; con |
Itching, irrit, reddening skin; hepatitis, hemolytic anemia, abdom cramps, tacar; kidney damage; skin photo sens |
PHENYLENEPYRENE 193-39-5 |
Skin: may be absorbed |
||||
PIPERIDINE 110-89-4 |
Inhalation: burning sensation, cough, laboured breathing |
||||
PROPYLENE IMINE 75-55-8 |
eyes; skin; resp tract; lungs ; CNS |
skin |
Inhalation: cough, dizziness, headache, laboured breathing, shortness of breath, unconsciousness Skin: may be absorbed, redness, skin burns, itching, blisters Eyes: redness, pain, blurred vision Ingestion: burning sensation of the digestive tract, dizziness, headache, nausea, vomiting |
Eyes; skin (in animals: nasal tumors) Inh; abs; ing; con |
Eye, skin burns; (carc) |
PYRIDINE 110-86-1 |
eyes; skin; resp tract; GI tract; CNS; CVS |
skin; liver; kidneys |
Inhalation: cough, dizziness, headache, nausea, shortness of breath, unconsciousness Skin: may be absorbed, redness Eyes: redness, pain Ingestion: abdominal pain, diarrhoea, vomiting, weakness |
Eyes; skin; CNS; liver; kidneys; GI tract Inh; abs; ing; con |
Irrit eyes; head, ner, dizz, insom; nau, anor, derm; liver, kidney damage |
2-PYRROLIDINONE 616-45-5 |
eyes |
||||
QUINOLINE 91-22-5 |
eyes; resp tract; CNS |
liver; kidneys; retina |
Inhalation: cough, laboured breathing, nausea, shortness of breath, vomiting, weakness Skin: may be absorbed, redness, skin burns Eyes: redness, pain, blurred vision |
||
TETRAHYDROTHIOPHENE 110-01-0 |
eyes; skin; resp tract; CNS |
skin |
Inhalation: Burning sensation, cough, headache, sore throat Skin: may be absorbed, dry skin, redness, burning sensation Eyes: redness, pain, eyes Ingestion: abdominal pain |
||
THIOPHENE 110-02-1 |
eyes; skin; resp tract |
Inhalation: cough, sore throat Skin: may be absorbed Eyes: redness, pain |
Chemical Formula |
Chemical |
Synonyms |
CAS-Number |
1888911 |
N-ACETYLCAPROLACTAM |
Acetylcaprolactam; |
1888-91-1 |
260946 |
ACRIDINE |
Benzo(b)quinoline; |
260-94-6 |
140318 |
N-AMINOETHYLPIPERAZINE |
N-(2-Aminoethyl)piperazine; |
140-31-8 |
504290 |
2-AMINOPYRIDINE |
o-Aminopyridine; |
504-29-0 |
91769 |
BENZOGUANAMINE |
4,6-Diamino-2-phenyl-s-triazine; |
91-76-9 |
95147 |
1,2,3-BENZOTRIAZOLE |
1,2,-Aminozophenylene; |
95-14-7 |
91645 |
COUMARIN |
91-64-5 |
|
194592 |
3,4,5,6-DIBENZOCARBAZOLE |
3,4,5,6-Dibenzcarbazol; |
194-59-2 |
1702176 |
3,6-DICHLOROPICOLINIC ACID |
3,6-Dichloro-2-pyridinecarboxylic acid; |
1702-17-6 |
100743 |
N-ETHYLMORPHOLINE |
4-Ethylmorpholine |
100-74-3 |
149304 |
2-MERCAPTOBENZOTHIAZOLE |
Benzothiazole-2-thione; |
149-30-4 |
120785 |
2-MERCAPTOBENZOTHIAZOLE DISULPHIDE |
2-Benzothiazolyl disulphide; |
120-78-5 |
109024 |
N-METHYLMORPHOLINE |
Methylmorpholine; |
109-02-4 |
872504 |
1-METHYL-2-PYRROLIDINONE |
N-Methylpyrrolidinone; |
872-50-4 |
109068 |
2-METHYLPYRIDINE |
a-Methylpyridine; |
109-06-8 |
108996 |
3-METHYLPYRIDINE |
3-Picoline |
108-99-6 |
108894 |
4-METHYLPYRIDINE |
g-Picoline; |
108-89-4 |
110918 |
MORPHOLINE |
Diethyleneimide oxide; |
110-91-8 |
54115 |
NICOTINE |
1-Methyl-2-(3-pyridyl)pyrrolidine; |
54-11-5 |
65316 |
NICOTINE TARTRATE |
Nicotine acid tartrate; |
65-31-6 |
16543558 |
N-NITROSONORNICOTINE |
1'-Nitroso-1'-demethylnicotine; |
16543-55-8 |
94780 |
PHENAZOPYRIDINE |
2,6-Diamino-3-phenylazopyridine; |
94-78-0 |
92842 |
PHENOTHIAZINE |
Dibenzoparathiazine; |
92-84-2 |
193395 |
PHENYLENEPYRENE |
Indeno(1,2,3-CD)pyrene; |
193-39-5 |
110850 |
PIPERAZINE |
1,4-Diethylenediamine; |
110-85-0 |
142643 |
PIPERAZINE DIHYDROCHLORIDE |
Dihydrochloride salt of diethylenediamine; |
142-64-3 |
110894 |
PIPERIDINE |
Azacyclohexane; |
110-89-4 |
1120714 |
1,3-PROPANE SULTONE |
3-Hydroxy-1-propanesulphonic acid sulphone; |
1120-71-4 |
75558 |
PROPYLENE IMINE |
2-Methylazacyclopropane; |
75-55-8 |
110861 |
PYRIDINE |
UN1282 |
110-86-1 |
289952 |
PYRIMIDINE |
1,3-Diazabenzene; |
289-95-2 |
123751 |
PYRROLIDINE |
Azacyclopentane; |
123-75-1 |
616455 |
2-PYRROLIDINONE |
4-Aminobutyric acid lactam; |
616-45-5 |
91225 |
QUINOLINE |
1-Azanaphthalene; |
91-22-5 |
126330 |
SULPHOLANE |
Cyclic tetramethylene sulphone; |
126-33-0 |
110010 |
TETRAHYDROTHIOPHENE |
Tetrahydrothiophene; |
110-01-0 |
110021 |
THIOPHENE |
Divinylene sulphide; |
110-02-1 |
100696 |
2-VINYLPYRIDINE |
100-69-6 |
Chemical Name |
Colour/Form |
Boiling Point (°C) |
Melting Point (°C) |
Molecular Weight |
Solubility in Water |
Relative Density (water=1) |
Relative Vapour Density (air=1) |
Vapour Pressure/ (Kpa) |
Inflam. |
Flash Point (°C) |
Auto Ignition Point (°C) |
BROMINE |
dark reddish-brown liquid; reddish-brown vapor; rhombic crystals |
58.78 |
-7.25 |
159.808 |
3.58 g/ 100 ml |
@ 25 °C/4 °C |
@ 15 °C |
23.3 |
|||
BROMINE PENTAFLUORIDE |
colourless liquid; colourless gas above 40.3 °C |
40.76 |
-60.5 |
174.90 |
reacts |
@ 25 °C |
6.05 |
@ 25.5 °C |
|||
CARBONYL FLUORIDE |
colourless gas |
-83 |
-114 |
66.01 |
reacts |
@ 25 °C |
2.3 |
||||
CHLORINE |
greenish-yellow, diatomic gas |
-34.6 |
-100.98 |
70.906 |
@ 30 °C |
1.4085;6.864 atm |
2.5 |
638 |
|||
CHLORINE OXIDE |
yellow to reddish-yellow gas at room temp; solid chlorine dioxide is a yellowish-red crystalline mass; liquid is reddish-brown |
11 |
-59 |
67.46 |
@ 25 °C and 34.5 mm Hg |
@ 0 °C |
2.3 |
10 |
>10 |
||
CHLORINE TRIFLUORIDE |
colourless gas; liquid is yellow-green in colour; solid is white |
11.75 |
-76.34 |
92.46 |
reacts |
@ 13 °C |
3.18 |
@ -4.9 °C; 740 mm Hg |
|||
FLUORINE |
pale yellow; greenish yellow gas |
-188.13 |
-219.61 |
37.99 |
reacts |
@ -188.2 °C |
1.3 |
@ -223.0 °C; 10 mm Hg |
|||
HYDROGEN FLUORIDE |
colourless liquid |
20 |
-83 |
20.0 |
misc |
@ 19.54 °C |
@ 0 °C |
@ 2.5 °C |
|||
IODINE |
bluish-black scales or plates; diatomic; rhombic, violet-black crystals with metallic luster |
184.35 |
113.50 |
253.81 |
@ 25 °C (solid) |
6.75 g/l (gas) |
@ 38.7 °C (solid) |
||||
NITROGEN CHLORIDE |
yellow oil ot rhombic crystals |
<71 |
<-40 |
120.37 |
insol cold water, decomposes hot water |
1.653 |
|||||
NITROGEN TRIFLUORIDE |
colourless gas |
-129 |
-208.5 |
71.01 |
sl sol |
@ -129 °C (liquid) |
|||||
OXYGEN DIFLUORIDE |
colourless gas; yellowish-brown when liquid |
-144.8 |
-223.8 |
54.00 |
insol hot water; sl sol and decomposes cold water |
@ -233.8 °C (liquid) |
1.8 |
@ -144.6 °C |
|||
PERCHLORYL FLUORIDE |
colourless gas |
-46.8 |
-146 |
102.45 |
misc |
0.637 (gas); 1.434 (liquid) |
3.5 |
1.06 |
|||
PHOSGENE |
colourless gas |
8 |
-118 |
98.92 |
sl sol |
1.381 |
3.4 |
161.6 |
|||
PHOSPHORUS PENTABROMIDE |
yellow crystalline mass |
106 decomp |
430.49 |
decomposes |
|||||||
PHOSPHOROUS TRIBROMIDE |
colourless liquid; pale yellow liquid |
173.2 |
-41.5 |
270.73 |
@ 15 °C |
@ 47.8 °C |
|||||
SODIUM HEXAFLUOROSILICATE |
white granular powder |
188.05 |
sol |
2.68 |
|||||||
SULPHUR CHLORIDE |
light amber to yellowish red oily liquid |
135.6 |
-77 |
135.03 |
reacts |
@ 15.5 °C/15.5 °C |
4.66 |
0.906 |
118 cc |
234 |
|
SULPHUR DICHLORIDE |
dark red liquid; *reddish brown liquid |
59 (decomp) |
-78 |
102.96 |
@ 15 °C/15 °C |
3.55 |
@ -23 °C |
||||
SULPHUR HEXAFLUORIDE |
colourless gas; liquid at -50.5 °C |
-63.8 sublimes |
-50.8 |
146.06 |
sl sol |
@ -50 °C (liquid) |
5.1 |
2140 |
|||
SULPHURYL FLUORIDE |
colourless gas |
-55.38 |
-135.82 |
102.07 |
4-5 ml gas/ 100 ml |
3.72 g/l (gas), 1.7 g/l (liquid) |
3.5 |
@ 25 °C |
Chemical Name |
Physical |
Chemical |
UN Class or Division / Subsidiary Risks |
BROMINE |
The vapour is heavier than air |
Upon heating, toxic fumes are formed • The substance is a strong oxidant and reacts violently with combustible and reducing materials • Reacts violently with aqueous ammonia, oxidants, metals, organic compounds and phosphorus causing fire and explosion hazard • Attacks some forms of plastic, rubber and coatings |
3/ 6.1 |
BROMINE PENTAFLUORIDE |
The vapour is heavier than air |
The substance decomposes on heating above 460 °C and on contact with acid or acid fumes producing very toxic fumes of fluorine and bromine • Reacts violently with fuels and organic compounds, hydrogen containing material (such as ammonia, acetic acid, grease, paper) causing fire and explosion hazard • Reacts explosively with water or steam to produce toxic and corrosive fumes • Reacts with all known elements, except nitrogen, oxygen and rare gases |
5.1/ 6.1/ 8 |
CARBONYL FLUORIDE |
The gas is heavier than air |
The substance decomposes on heating at 450-490 °C producing toxic gases • Hydrolyzed rapidly by water to form carbon dioxide and hydrogen fluoride |
2.3/ 8 |
CHLORINE |
The gas is heavier than air |
Reacts violently with many organic compounds, ammonia and finely divided metals causing fire and explosion hazard • Attacks many metals in presence of water • Attacks plastic, rubber and coatings |
2.3/ 5.1/ 8 |
CHLORINE OXIDE |
The gas is heavier than air |
May explosively decompose on shock, friction, or concussion • May explode on heating • The substance is a strong oxidant and reacts violently with combustible and reducing materials • Reacts violently with mercury, phosphorus, sulphur and many compounds, causing fire and explosion hazard • Reacts with water producing hydrochloric acid and chloric acid |
|
CHLORINE TRIFLUORIDE |
The gas is heavier than air and corrosive |
The substance decomposes above 220 °C producing toxic gases (chlorine and fluorine compounds) • Reacts violently with water, sand, silicon-containing compounds, glass, and asbestos • Reacts with all forms of plastics, rubber, and resins, except the highly fluorinated polymers • Most combustible materials ignite spontaneously on contact with this substance • Reacts violently with oxidizable materials, metals and metal oxides • Explodes in contact with organic materials • Emits highly toxic fumes on contact with acids |
2.3/ 5.1/ 8 |
FLUORINE |
The gas is heavier than air |
The substance is a strong oxidant and reacts violently with combustible and reducing materials • Reacts violently with water producing toxic and corrosive vapours: ozone and hydrogen fluoride • Reacts violently with ammonia, metals, oxidants, and many other materials, causing fire and explosion hazard |
2.3/ 5.1/ 8 |
HYDROGEN BROMIDE |
The gas is heavier than air |
The solution in water is a strong acid, it reacts violently with bases and is corrosive • Reacts violently with strong oxidants and many organic compounds causing fire and explosion hazard • Attacks many metals forming flammable hydrogen gas |
8 |
HYDROGEN FLUORIDE |
The solution in water is a strong acid, it reacts violently with bases and is corrosive • Reacts violently with many compounds causing fire and explosion hazard • On contact with air it emits corrosive fumes which are heavier than air and will spread along the ground • Attacks glass and other silicon-containing compounds |
3/ 6.1 |
|
NITROGEN TRIFLUORIDE |
2.3/ 5.1 |
||
OXYGEN DIFLUORIDE |
The gas is heavier than air |
The substance decomposes on heating above 250 °C producing toxic fumes (fluorine) • The substance is a strong oxidant and reacts violently with combustible and reducing materials • Reacts explosively with hydrogen sulfide at ambient temperature, with chlorine, bromine or iodine on warming • Attacks mercury • Explodes on contact with steam • Reaction of oxygen difluoride with non-metals such as red phosphorous and boron powder and silica, alumina or similar surface-active solids is exothermic and may be explosive |
2.3/ 5.1/ 8 |
PERCHLORYL FLUORIDE |
The substance decomposes on heating producing toxic fumes (fluorine, fluorine oxides, chlorine, chlorine oxides) • The substance is a strong oxidant and reacts violently with combustible and reducing materials, causing fire and explosion hazard • Attacks some forms of plastics, rubber and coatings |
2.3/ 5.1 |
|
PHOSGENE |
The vapour is heavier than air and may travel along the ground |
The substance decomposes on heating above 300 °C, producing toxic and corrosive gases: hydrogen chloride and carbon monoxide, chlorine fumes • Reacts violently with strong oxidants • Reacts slowly with water producing corrosive, pungent and toxic gases • Reacts violently with amines, with aluminium • Attacks many metals in presence of water • Attacks metal, plastic, rubber |
2.3/ 8 |
PHOSPHORUS PENTABROMIDE |
8 |
||
PHOSPHOROUS TRIBROMIDE |
8 |
||
SULPHUR CHLORIDE |
On combustion, forms toxic gases and vapours (such as hydrogen chloride, sulphur dioxide, hydrogen sulfide) • The substance decomposes to toxic chlorine gas and solid sulphur on heating above 300 °C • Reacts with peroxides, oxides of phosphorous and some organic compounds, causing fire and explosion hazard • Reacts with moist air to form corrosive vapours (hydrochloric acid) • Contact with water causes a violent reaction, forming hydrogen chloride gas (or hydrochloric acid), sulphur dioxide, sulphur, sulfite, thiosulfate and hydrogen sulfide, which may corrode metal containers and form flammable hydrogen gas |
8 |
|
SULPHUR DICHLORIDE |
8 |
||
SULPHUR HEXAFLUORIDE |
The gas is heavier than air and may accumulate in low ceiling spaces causing deficiency of oxygen |
The substance decomposes in a fire producing toxic fumes of sulphur oxides and hydrogen fluoride • on contact with hot surfaces producing S02 • Upon heating, toxic fumes are formed • Reacts with strong oxidants and alkali and earth alkali |
2.2 |
SULFURYL FLUORIDE |
2.3 |
For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance
Chemical Name CAS-Number |
ICSC Short-Term Exposure |
ICSC Long-Term Exposure |
ICSC Routes of Exposure and Symptoms |
US NIOSH Target Organs & Routes of Entry |
US NIOSH Symptoms |
BROMINE 7726-95-6 |
eyes; skin; resp tract; lungs |
skin; lungs |
Inhalation: corrosive, burning sensation, cough, dizziness, headache, laboured breathing, sore throat Skin: corrosive, redness, skin burns, pain Eyes: corrosive, redness, pain, severe deep burns Ingestion: corrosive, abdominal cramps, burning sensation, sore throat, collapse |
Resp sys; eyes; CNS; skin Inh; ing; con |
Dizz, head; lac, epis; cough, feeling of oppression, pulm edema, pneu; abdom pain, diarr; measle-like eruptions; eye, skin burns |
BROMINE PENTAFLUORIDE 7789-30-2 |
eyes; skin; resp tract; lungs |
liver; kidneys; resp tract |
Inhalation: burning sensation, cough, shortness of breath, sore throat Skin: skin burns, pain, blisters Eyes: pain, blurred vision, severe deep burns Ingestion: abdominal pain, burning sensation |
Eyes; skin; resp sys; liver; kidneys Inh; ing; con |
Irrit eyes, skin, resp sys; corn nec; skin burns; cough; dysp, pulm edema; liver, kidney inj |
CARBONYL FLUORIDE 353-50-4 |
eyes; skin; resp tract; lungs; skin |
blood |
Inhalation: cough, laboured breathing, sore throat, symptoms may be delayed Skin: redness, on contact with liquid: frostbite Eyes: redness |
Eyes; skin; resp sys; bone Inh; con |
Irrit eyes, skin, muc memb, resp sys; eye, skin burns; lac; cough; pulm edema, dysp; chronic exposure: GI pain, musc fib, skeletal fluorosis; liq: frostbite |
CHLORINE 7782-50-5 |
eyes; skin; resp tract; lungs; skin |
lungs |
Inhalation: corrosive, burning sensation, cough, headache, laboured breathing, nausea, shortness of breath, sore throat, symptoms may be delayed Skin: corrosive, skin burns, pain Eyes: corrosive, pain, blurred vision, severe deep burns |
Resp sys, eyes, skin Inh; con |
Burning of eyes, nose, mouth; lac, rhin; cough, choking, subs pain; nau, vomit; head, dizz; syncope; pulm edema; pneu; hypox; derm; liq: frostbite |
CHLORINE OXIDE 10049-04-4 |
eyes; skin; resp tract; lungs; skin |
lungs |
Inhalation: corrosive, cough, headache, laboured breathing, nausea, shortness of breath, sore throat, symptoms may be delayed Skin: corrosive, redness, serious skin burns, pain |
Resp sys; eyes Inh; ing (liq); con |
Irrit eyes, nose, throat; cough, wheez, bron, pulm edema; chronic bron |
CHLORINE TRIFLUORIDE 7790-91-2 |
eyes; skin; resp tract; lungs |
Inhalation: cough, laboured breathing, sore throat Skin: corrosive, redness, serious skin burns, pain Eyes: permanent loss of vision, severe deep burns, blindness |
Skin; eyes; resp sys Inh; ing (liq); con |
Eye, skin burns (liq or high vap conc); resp irrit; in animals: lac; corn ulcer; pulm edema |
|
FLUORINE 7782-41-4 |
eyes; skin; resp tract; lungs |
skin |
Inhalation: corrosive, cough, shortness of breath, sore throat, choking Skin: corrosive, redness, serious skin burns, on contact with liquid: frostbite Eyes: redness, severe deep burns |
Resp sys; eyes; liver; kidneys Inh; con |
Irrit eyes, nose, resp sys; lar spasm, bron spasm; pulm edema; eye, skin burns; in animals: liver, kidney damage |
HYDROGEN FLUORIDE 7664-39-3 |
eyes; skin; resp tract; lungs |
Inhalation: cough, laboured breathing, sore throat, symptoms may have delayed effects Skin: may be adsorbed, serious skin burns Eyes: redness, pain, blurred vision Ingestion: abdominal pain, diarrhoea, sore throat, vomiting, symptoms may have delayed effects |
Eyes; resp sys; skin; bone Inh; abs (liq); ing (soln); con |
Irrit eyes, skin, nose, throat; pulm edema; eye, skin burns; rhinitis; bron; bone changes |
|
OXYGEN DIFLUORIDE 7783-41-7 |
eyes; skin; resp tract; lungs |
Inhalation: cough, laboured breathing, sore throat Skin: on contact with liquid: frostbite |
Resp sys; eyes; skin Inh; con |
Irrit eyes, skin, resp sys; head; pulm edema; eye, skin burns (from contact with the gas under pressure) |
|
PERCHLORYL FLUORIDE 7616-94-6 |
resp tract; skin |
blood |
Inhalation: headache Skin: on contact with liquid: frostbite Eyes: severe deep burns |
Resp sys; skin; blood Inh; con (liq) |
Irrit resp sys; liq: frostbite; in animals: methemo; cyan; weak; dizz, head; pulm edema; pneuitis; anoxia |
PHOSGENE 75-44-5 |
eyes; skin; resp tract; lungs |
lungs |
Inhalation: corrosive, burning sensation, cough, laboured breathing, shortness of breath, sore throat |
Resp sys; skin; eyes Inh; con (liq) |
Irrit eyes; dry, burning throat; vomit; cough, foamy sputum, dysp, chest pain, cyan; liq: frostbite |
SULPHUR CHLORIDE 10025-67-9 |
eyes; skin; resp tract; lungs; corrosive on ingestion |
skin |
Inhalation: burning sensation, cough, headache, laboured breathing, nausea, vomiting Skin: redness, skin burns, burning sensation, pain, blisters Eyes: redness, pain, severe deep burns |
Resp sys; skin; eyes Inh; ing; con |
Irrit eyes, skin, muc memb; lac; cough; eye, skin burns; pulm edema |
SULPHUR HEXAFLUORIDE 2551-62-4 |
skin |
Skin: on contact with liquid: frostbite Eyes: corneal damage |
Resp sys Inh |
Asphy: incr breath rate, pulse rate; slight musc inco, emotional upset; ftg, nau, vomit, convuls |
|
SULPHUR PENTAFLUORIDE 5714-22-7 |
Resp sys; CNS; eyes; skin Inh; ing; con |
Irrit eys, skin, resp sys; in animals: pulm edema, hemorr |
Chemical Formula |
Chemical |
Synonyms |
CAS-Number |
7726956 |
BROMINE |
Bromine |
7726-95-6 |
7789302 |
BROMINE PENTAFLUORIDE |
Bromine pentafluoride |
7789-30-2 |
7789755 |
CALCIUM FLUORIDE |
7789-75-5 |
|
353504 |
CARBONYL FLUORIDE |
Carbon difluoride oxide; |
353-50-4 |
7782505 |
CHLORINE |
Molecular chlorine |
7782-50-5 |
10049044 |
CHLORINE OXIDE |
Chlorine dioxide; |
10049-04-4 |
7790912 |
CHLORINE TRIFLUORIDE |
Chlorine fluoride; |
7790-91-2 |
7782414 |
FLUORINE |
Fluorine |
7782-41-4 |
10035106 |
HYDROGEN BROMIDE |
Anhydrous hydrobromic acid; |
10035-10-6 |
7664393 |
HYDROGEN FLUORIDE |
Hydrofluoric acid; |
7664-39-3 |
7553562 |
IODINE |
7553-56-2 |
|
10025851 |
NITROGEN CHLORIDE |
Chlorine nitride; |
10025-85-1 |
7783542 |
NITROGEN TRIFLUORIDE |
Nitrogen fluoride |
7783-54-2 |
7783417 |
OXYGEN DIFLUORIDE |
Fluorine monoxide; |
7783-41-7 |
7616946 |
PERCHLORYL FLUORIDE |
Chlorine fluoride oxide; |
7616-94-6 |
75445 |
PHOSGENE |
Carbonyl chloride; |
75-44-5 |
7789697 |
PHOSPHOROUS PENTABROMIDE |
7789-69-7 |
|
7789608 |
PHOSPHOROUS TRIBROMIDE |
Phosphorous bromide; |
7789-60-8 |
16893859 |
SODIUM HEXAFLUOROSILICATE |
16893-85-9 |
|
10025679 |
SULPHUR CHLORIDE |
Disulphurdichloride; |
10025-67-9 |
10545990 |
SULPHUR DICHLORIDE |
10545-99-0 |
|
2551624 |
SULPHUR HEXAFLUORIDE |
Sulphurfluoride |
2551-62-4 |
5714227 |
SULPHUR PENTAFLUORIDE |
Disulphurdecafluoride; |
5714-22-7 |
2699798 |
SULPHURYL FLUORIDE |
Sulphuric oxyfluoride |
2699-79-8 |