Chemical Name CAS-Number |
ICSC Short-Term Exposure |
ICSC Long-Term Exposure |
ICSC Routes of Exposure and Symptoms |
US NIOSH Target Organs & Routes of Entry |
US NIOSH Symptoms |
n-BUTYLMERCAPTAN 109-79-5 |
eyes; skin; resp tract; CNS; thyroid |
Inhalation: weakness, confusion, cough, dizziness, headache, nausea, vomiting, shortness of breath Skin: redness, pain Eyes: redness, pain Ingestion: see inhalation |
Resp sys; CNS; liver; kidneys; eyes; skin Inh; ing; con |
Irrit eyes, skin; musc weak, mal, sweat, nau, vomit, head, conf; in animals: narco, inco, weak; cyan, pulm irrit; liver, kidney damage |
|
tert-BUTYLMERCAPTAN 75-66-1 |
eyes; skin; resp tract; CNS |
skin |
Inhalation: cough, dizziness, headache, nausea, vomiting Skin: redness Eyes: redness |
||
CYCLOHEXYLMERCAPTAN 1569-69-3 |
eyes; skin; resp tract; CNS |
skin |
Inhalation: cough, dizziness, headache, nausea, unconsciousness, vomiting, weakness Skin: redness Eyes: redness |
Eyes; skin; resp sys; CNS Inh; abs; ing; con |
Irrit eyes, skin, resp sys; head, dizz, weak, nau, vomit, convuls; cough, wheez, laryngitis, dysp |
DECYLMERCAPTAN 143-10-2 |
eyes; skin; resp tract; CNS |
skin |
Inhalation: confusion, dizziness, headache, nausea, unconsciousness, weakness Skin: redness Eyes: redness |
Eyes; skin; resp sys Inh; abs; ing; con |
Irrit eyes, skin, resp sys; conf, dizz, head, drow, nau, vomit, weak, convuls |
DODECYLMERCAPTAN 112-55-0 |
eyes; skin; resp tract; CNS |
skin |
Inhalation: confusion, cough, dizziness, headache, nausea, shortness of breath, sore throat, unconsciousness, weakness Skin: redness Eyes: redness, pain Ingestion: abdominal pain, dullness, headache, nausea, unconsciousness |
Eyes; skin; resp sys; CNS; blood; Inh; con |
Irrit eyes, skin, resp sys; cough; dysp, weak, conf, cyan; abdom pain, nau; skin sens |
ETHYLMERCAPTAN 75-08-1 |
Inhalation: drowsiness, nausea, unconsciousness, weakness, tremors Skin: redness Eyes: redness, pain |
Resp sys; liver; kidneys; eyes; blood Inh; con |
Irrit muc memb; head, nau; in animals: inco, weak; liver, kidney damage; cyan; narco |
||
HEXANETHIOL 2917-26-2 |
eyes; skin; resp tract; CNS |
skin |
Inhalation: dizziness, headache, nausea, sore throat, unconsciousness, weakness Skin: redness Eyes: redness |
Eyes; skin; resp sys; CNS; blood Inh; abs; ing; con |
Irrit eys, skin, resp sys; head, dizz, weak, cyan, nau, convuls |
METHYLMERCAPTAN 74-93-1 |
eyes; skin; resp tract; lungs; CNS; blood; skin |
Inhalation: cough, irritant, headache, nausea, shortness of breath, sore throat, unconsciousness Skin: redness, irritant, pain, on contact with liquid: frostbite Eyes: redness, irritant, pain |
Resp sys; CNS; eyes; skin; blood Inh; con (liq) |
Irrit eyes, skin, resp sys; narco; cyan; convuls; liq: frostbite |
|
1-OCTADECANETHIOL 2885-00-9 |
Eyes; skin; resp sys; CNS; bloodInh; abs; ing; con |
Irrit eyes, skin, resp sys; head; dizz; weak; cyan; nau; convuls |
|||
1-OCTANETHIOL 111-88-6 |
Eyes; skin; resp sys; blood; CNSInh; ing; con |
Irrit eyes, skin, nose, throat; weak; cyan; incr respiration; nau; drow; head; vomit |
|||
PERCHLOROMETHYLMERCAPTAN 594-42-3 |
eyes; skin; resp tract; lungs |
skin; lungs |
Eyes; resp sys; liver; kidneys; skin Inh; abs; ing; con |
Irrit eyes, skin, nose, throat; lac; cough, dysp, deep breath pain, coarse rales; vomit; pallor, tacar; acidosis; anuria; liver, kidney damage |
|
PHENYLMERCAPTAN 108-98-5 |
eyes; skin; resp tract; CNS |
skin |
Inhalation: cough, headache, laboured breathing Skin: redness, pain Eyes: redness, pain Ingestion: nausea, sore throat |
Eyes; skin; resp sys; CNS; kidneys; liver; spleen Inh; abs; ing; con |
Irrit eyes, skin, resp sys; derm; cyan; cough, wheez, dysp, pulm edema, pneuitis; head, dizz, CNS depres; nau, vomit; kidney, liver, spleen damage |
PROPANETHIOL 107-03-9 |
Eyes; skin; resp sys; CNS; blood; liver; kidneysInh; ing; con |
Irrit eyes, skin, nose, throat, resp sys; head, nau, dizz, cyan; in animals: liver, kidney damage |
|||
SODIUM DODECYLBENZENESULFONATE 25155-30-0 |
eyes; skin; resp tract |
skin |
Inhalation: cough, laboured breathing Skin: redness Eyes: redness, pain Ingestion: diarrhoea, vomiting |
||
THIOACETAMIDE 62-55-5 |
eyes; skin; resp tract |
Inhalation: cough, laboured breathing, sore throat Skin: redness Eyes: redness, pain, blurred vision Ingestion: burning sensation, sore throat |
|||
THIOACETIC ACID 507-09-5 |
eyes; skin; resp tract; lungs |
kidneys |
Inhalation: cough, laboured breathing, nausea, sore throat, symptoms may be delayed Skin: burning sensation, pain Eyes: redness, pain, severe deep burns Ingestion: abdominal cramps, burning sensation |
Chemical Formula |
Chemical |
Synonyms |
CAS-Number |
86884 |
ANTU |
a-Naphthyl thiourea; |
86-88-4 |
98099 |
BENZENESULPHONYL CHLORIDE |
Benzenesulphonic chloride |
98-09-9 |
531862 |
BENZIDINE SULPHATE |
(1,1'-Biphenyl)-4,4'-diamine, sulphate (1:1) |
531-86-2 |
109795 |
n-BUTYLMERCAPTAN |
n-Butanethiol; |
109-79-5 |
75661 |
tert-BUTYLMERCAPTAN |
tert-Butanethiol; |
75-66-1 |
463581 |
CARBONYL SULPHIDE |
463-58-1 |
|
1569693 |
CYCLOHEXYL-1-MERCAPTAN |
Cyclohexanethiol |
1569-69-3 |
143102 |
DECYLMERCAPTAN |
1-Decanethiol; |
143-10-2 |
64675 |
DIETHYLSULPHATE |
Diethyl sulphate; |
64-67-5 |
77781 |
DIMETHYLSULPHATE |
Dimethyl monosulphate |
77-78-1 |
112550 |
DODECYLMERCAPTAN |
1-Dodecanethiol; |
112-55-0 |
75081 |
ETHYLMERCAPTAN |
Ethanethiol; |
75-08-1 |
1639094 |
n-HEPTYLMERCAPTAN |
1-Heptanethiol |
1639-09-4 |
2917262 |
HEXANETHIOL |
Cetylmercaptan; |
2917-26-2 |
111319 |
n-HEXYLMERCAPTAN |
1-Hexanethiol |
111-31-9 |
151213 |
LAURYL SODIUM SULPHATE |
Monododecyl sodium sulphate; |
151-21-3 |
60242 |
2-MERCAPTOETHANOL |
1-Ethanol-2-thiol; |
60-24-2 |
59518 |
D,L-METHIONINE |
Acimetion; |
59-51-8 |
74931 |
METHYLMERCAPTAN |
Methylmercaptan; |
74-93-1 |
67685 |
METHYL-SULFOXIDE |
Dimethyl sulfoxide; |
67-68-5 |
75183 |
METHYL-SULPHIDE |
Dimethyl sulphide; |
75-18-3 |
2885009 |
1-OCTADECANEDIOL |
1-Mercaptooctadene; |
2885-00-9 |
111886 |
1-OCTANETHIOL |
1-Mercaptooctane; |
111-88-6 |
110667 |
1-PENTANETHIOL |
Amyl hydrosulphide; |
110-66-7 |
594423 |
PERCHLOROMETHYLMERCAPTAN |
PCM; |
594-42-3 |
108985 |
PHENYLMERCAPTAN |
Benzenethiol; |
108-98-5 |
107039 |
PROPANETHIOL |
107-03-9 |
|
25155300 |
SODIUM DODECYLBENZENESULFONATE |
25155-30-0 |
|
540727 |
SODIUM ISOTHIOCYANATE |
Sodium rhodanate; |
540-72-7 |
62555 |
THIOACETAMIDE |
Acetothioamide; |
62-55-5 |
507095 |
THIOACETIC ACID |
Acetylmercaptan; |
507-09-5 |
68111 |
THIOGLYCOLIC ACID |
Glycolic acid, 2-thio-; |
68-11-1 |
111488 |
2,2'-THIODIETHANOL |
Bis(b-hydroxyethyl)sulfide; |
111-48-8 |
62566 |
THIOUREA |
Isothiourea; |
62-56-6 |
137268 |
THIRAM |
Bis((dimethylamino)carbonothioyl) disulphide; |
137-26-8 |
Chemical Name CAS-Number |
Colour/Form |
Boiling Point (°C) |
Melting Point (°C) |
Molecular Weight |
Solubility in Water |
Relative Density (water=1) |
Relative Vapour Density (air=1) |
Vapour Pressure/ (Kpa) |
Inflam. |
Flash Point (°C) |
Auto Ignition Point (°C) |
AMMONIUM PERSULPHATE |
white crystals |
120 decomp |
228.19 |
v sol |
1.98 |
||||||
AMMONIUM SULPHAMATE |
crystals (large plates); colourless, white crystalline substance; brownish-gray; bright yellow-orange crystalline solid |
131 |
114.13 |
@ 10 °C; 2.16 kg/ kg |
>1 (solid) |
||||||
AMMONIUM SULPHATE |
colourless rhombic crystals; orthorhombic crystals or white granules; brownish gray to white crystals according to degree of purity |
132.14 |
sol |
@ 50 °C |
|||||||
AMMONIUM SULPHIDE |
yellow crystals |
decomp |
68.14 |
v sol |
|||||||
CALCIUM SULPHATE |
natural anhydrite crystals are colourless, rhombic or monoclinic; natural anhydrite crystals are orthorhombic, colour varies (white with blue, gray or reddish tinge, or brick red); insol anhydrite has same crystal structure as mineral anhydrite |
1193 |
1450 |
136.14 |
sl sol |
2.960 |
|||||
CALCIUM SULPHIDE |
deep orange malodorous liquid |
@ 15.6 °C |
|||||||||
CARBON DISULPHIDE |
mobil liquid; clear, colourless or faintly yellow liquid |
46.5 |
-111.5 |
76.14 |
0.2 g/100 ml |
1.2632 |
2.67 |
@ 25 °C |
1.3 ll |
-30 cc |
90 |
CARBONYL SULPHIDE |
colourless gas |
-30 |
-138 |
60.08 |
1220 mg/l at 25 °C |
@ 17 °C/4 °C |
2.1 |
9412 mm Hg at 25 °C |
12% ll |
||
HYDROGEN SULPHIDE |
colourless gas |
-60.33 |
-85.49 |
34.08 |
1 g /242 ml |
@ 0 °C;1.19 (gas) |
1.189 |
@ -60.4 °C |
4.3 ll |
260 |
|
POTASSIUM PERSULPHATE |
colourless, triclinic crystal; white crystal |
270.3 |
@ 0 °C; 5.2 g/100 cc |
2.47 |
|||||||
POTASSIUM PYROSULPHITE |
white crystals or crystalline powder; colourless, monoclinic plates |
190 decomp |
222.32 |
v sol |
2.34 |
||||||
POTASSIUM SULPHIDE |
white cubic crystals or fused plates; red or yellow-red crystalline mass or fused solid |
912 |
110.26 |
v sol |
@ 14 °C |
||||||
SODIUM BISULPHITE |
white crystal or crystalline powder; granular powder; white, monoclinic |
104.07 |
3.5 parts in cold, 2 parts in boiling |
1.48 |
|||||||
SODIUM HYDROSULPHITE |
white or grayish-white crystalline powder |
176.10 |
|||||||||
SODIUM METABISULPHITE |
white crystals or white to yellowish crystalline powder |
150 decomp |
190.13 |
@ 100 °C |
1.4 |
||||||
SODIUM SULPHATE |
white powder or orthorhombic bipyramidal crystals; monoclinic crystals from 160-185 °C |
888 |
142.06 |
sol in about 3.6 parts |
2.671 |
||||||
SODIUM SULPHIDE |
clear crystals; yellow or brick-red lumps or flakes; cubic crystals or granules; amorphous, yellow-pink or white crystals |
1180 |
78.05 |
18.6 g/100 g |
@ 14 °C/4 °C |
||||||
SODIUM SULPHITE |
small crystals or powder; white powder or hexagonal prism |
128.06 |
sol in 3.2 parts |
@ 15.4 °C |
|||||||
SODIUM THIOSULPHATE |
powder; colourless monoclinic crystals |
158.13 |
50 g/100 ml |
1.667 |
|||||||
SULPHUR BROMIDE |
yellow liquid |
54 |
- 40 |
223.93 |
decomposes |
2.63 |
|||||
SULPHUR DIOXIDE |
colourless liquid or gas |
-10 |
-72.7 |
64.07 |
@ 25 °C |
2.927 g/l (gas); 1.434 (liquid) |
2.2 |
330 |
|||
SULPHUR TETRAFLUORIDE |
gas |
- 40 |
- 124 |
108.05 |
decomposes |
||||||
SULPHUR TRIOXIDE |
alpha-form, asbestos-like needles; beta-form, asbestos-like neeedles; gamma-form, ice-like mass or liquid |
80.07 |
sol in 100 parts |
@ 25 °C |
|||||||
SULPHUR |
orthorhombic, cycloocta or alpha-sulphur, amber coloured crystals; monoclinic, cycloocta or beta-sulphur, light-yellow, opaque, brittle, needle-like crystals; sublimed & washed sulphur are in form of fine, yellow crystalline powder |
444.6 |
112-120 |
32.06 |
insol |
2.1 |
@ 32 ºC |
@ 30.4 °C |
35 mg/l ll |
207 |
232 |
SULPHURYL CHLORIDE |
colourless, mobile liquid |
69.3 |
-54.1 |
134.98 |
1.6674 |
4.7 |
@17.8 °C |
||||
THIONYL CHLORIDE |
colourless to pale yellow or reddish liquid; colourless to pale yellow, fuming, refractive liquid |
76 |
-104.5 |
118.98 |
1.638 |
4.1 |
@ 26 °C |
Chemical Name |
Physical |
Chemical |
UN Class or Division / Subsidiary Risks |
AMMONIUM PERSULPHATE |
5.1 |
||
AMMONIUM SULPHATE |
8 |
||
CARBON DISULPHIDE |
The vapour is heavier than air and may travel along the ground; distant ignition possible • As a result of flow, agitation, etc, electrostatic charges can be generated |
May explosively decompose on shock, friction, or concussion • May explode on heating • The substance may spontaneously ignite on contact with air and on contact with hot surfaces producing toxic fumes of sulphur dioxide • Reacts violently with oxidants causing fire and explosion hazard • Attacks some forms of plastic, rubber and coating |
3/ 6.1 |
CARBONYL SULPHIDE |
2.3/2.1 |
||
HYDROGEN SULPHIDE |
2.3/ 2.1 |
||
POTASSIUM PERSULPHATE |
5.1 |
||
POTASSIUM SULPHIDE |
Dust explosion possible if in powder or granular form, mixed with air |
Heating may cause violent combustion or explosion • May explosively decompose on shock, friction, or concussion • The substance may spontaneously ignite on contact with air forming hydrogen sulphide • The solution in water is a strong base, it reacts violently with acid and is corrosive forming sulphur dioxide |
4.2 |
SODIUM HYDROSULPHITE |
4.2 |
||
SODIUM PERSULPHATE |
5.1 |
||
SODIUM SULPHIDE |
4.2 |
||
SULPHUR DIOXIDE |
2.3/ 8 |
||
SULPHUR TETRAFLUORIDE |
2.3/ 8 |
||
SULPHUR TRIOXIDE |
8 |
||
SULPHUR |
Dust explosion possible if in powder or granular form, mixed with air • If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc. |
On combustion, forms sulphur oxides including sulphur dioxide • Reacts violently with strong oxidants causing fire and explosion hazard |
4.1 |
SULPHURYL CHLORIDE |
8 |
||
THIONYL CHLORIDE |
8 |
For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance
Chemical Name CAS-Number |
ICSC Short-Term Exposure |
ICSC Long-Term Exposure |
ICSC Routes of Exposure and Symptoms |
US NIOSH Target Organs & Routes of Entry |
US NIOSH Symptoms |
AMMONIUM SULPHAMATE 7773-06-0 |
Resp sys; eyes Inh; con |
Irrit eyes, nose, throat; cough, dysp |
|||
CARBON DISULPHIDE 75-15-0 |
eyes; skin; resp tract; lungs; CNS |
Inhalation: confusion, dizziness, drowsiness, headache, nausea, shortness of breath, vomiting, weakness, irritability, hallucination Skin: may be absorbed, dry skin, redness Eyes: redness, pain |
CNS; PNS; CVS; eyes; kidneys; liver; skin; repro sys Inh; abs; ing; con |
Dizz, head, poor sleep, ftg, ner, anor, low-wtg; psychosis; polyneur; Parkinson-like syndrome; ocular changes; coronary heart disease; gastritis; kidney, liver inj; eye, skin burns; derm; repro effects |
|
HYDROGEN SULPHIDE 7783-06-4 |
Resp sys; eyes; CNS Inh; con |
Irrit eyes, resp sys; apnea, coma, convuls; conj, eye pain, lac, photo, corn vesic; dizz, head, ftg, irrity, insom; GI dist |
|||
POTASSIUM SULPHIDE 1312-73-8 |
eyes; skin; resp tract; lungs |
Inhalation: cough, dizziness, drowsiness, headache, nausea, shortness of breath, sore throat, weakness, symptoms may have delayed effects Skin: redness, skin burns, pain Eyes: redness, pain, severe deep burns |
|||
SULPHUR DIOXIDE 7446-09-5 |
eyes; resp tract; lungs; skin |
lungs |
Inhalation: irritation of respiratory tract, cough, choking, sneezing Skin: on contact with liquid: frostbite Eyes: irritation burns |
Resp sys; skin; eyes Inh; con |
Irrit eyes, nose, throat; rhin; choking, cough; reflex bronchoconstriction; liq: frostbite |
SULPHUR 7704-34-9 |
eyes; skin; resp tract; lungs |
skin; resp tract |
Ingestion: Inhalation: burning sensation, cough, sore throat Skin: redness Eyes: redness, pain, blurred visionburning sensation, diarrhoea |
Chemical Formula |
Chemical |
Synonyms |
CAS-Number |
7727540 |
AMMONIUM PERSULPHATE |
Ammonium peroxydisulphate; |
7727-54-0 |
7773060 |
AMMONIUM SULPHAMATE |
Amcide; |
7773-06-0 |
7783202 |
AMMONIUM SULPHATE |
Actamaster; |
7783-20-2 |
12124991 |
AMMONIUM SULPHIDE |
Ammonium bisulphide; |
12124-99-1 |
7778189 |
CALCIUM SULPHATE |
Crysalba; |
7778-18-9 |
1344816 |
CALCIUM SULPHIDE |
Calcium polysulphide; |
1344-81-6 |
75150 |
CARBON DISULPHIDE |
Carbon bisulphide; |
75-15-0 |
463581 |
CARBONYL SULPHIDE |
463-58-1 |
|
7783064 |
HYDROGEN SULPHIDE |
Hydrogen sulphuric acid; |
7783-06-4 |
7727211 |
POTASSIUM PERSULPHATE |
Anthion; |
7727-21-1 |
16731558 |
POTASSIUM PYROSULPHIDE |
Dipotassium disulphide; |
16731-55-8 |
1312738 |
POTASSIUM SULPHIDE |
Potassium monosulphide |
1312-73-8 |
7631905 |
SODIUM BISULPHITE |
Hydrogen sulphide sodium; |
7631-90-5 |
7775146 |
SODIUM HYDROSULPHITE |
Dithionous acid, disodium salt ; |
7775-14-6 |
7681574 |
SODIUM METABISULFITE |
Disodium disulphide; |
7681-57-4 |
7775271 |
SODIUM PERSULPHATE |
Sodium peroxydisulphate; |
7775-27-1 |
7757826 |
SODIUM SULPHATE |
Disodium sulphate; |
7757-82-6 |
1313822 |
SODIUM SULPHIDE |
Sodium monosulphide; |
1313-82-2 |
7757837 |
SODIUM SULPHITE |
Anhydrous sodium sulphide; |
7757-83-7 |
7772987 |
SODIUM THIOSULFATE |
Ametox; |
7772-98-7 |
7704349 |
SULPHUR |
Flour sulphur; |
7704-34-9 |
7446095 |
SULPHUR DIOXIDE |
Sulphur dioxide, sulphurous acid anhydride; |
7446-09-5 |
7783600 |
SULPHUR TETRAFLUORIDE |
Tetrafluorosulphurane |
7783-60-0 |
7446119 |
SULPHUR TRIOXIDE |
Sulphan; |
7446-11-9 |
7791255 |
SULPHURYL CHLORIDE |
Sulphonyl chloride; |
7791-25-5 |
7719097 |
THIONYL CHLORIDE |
Sulphinyl chloride; |
7719-09-7 |
Chemical Name |
Colour/Form |
Boiling Point (°C) |
Melting Point (°C) |
Molecular Weight |
Solubility in Water |
Relative Density (water=1) |
Relative Vapour Density (air=1) |
Vapour Pressure/ (Kpa) |
Inflam. |
Flash Point (°C) |
Auto Ignition Point ( °C) |
ACETONE |
colourless liquid |
56.2 |
-95.35 |
58.08 |
misc |
0.7899 |
2.0 |
2.15 ll |
-20 |
465 |
|
ACETOPHENONE |
monoclinic prisms or plates; slightly oily liquid; colourless liquid; liquid forms laminar crystals at low temperature |
202 |
20.5 |
120.16 |
insol |
@ 15(°C)/15 °C |
4.14 |
@ 25 °C |
82 oc |
570 |
|
ACETYL BROMIDE |
colourless liquid |
76 |
-96 |
122.96 |
sol |
@ 9 °C |
@ 21 |
||||
BENZOPHENONE |
white crystals |
305 |
49 |
182.2 |
insol |
1.1 |
|||||
p-BENZOQUINONE |
yellow monoclinic prisms from water or petroleum ether; greenish-yellowish solid |
115.7 |
108.09 |
sl sol |
@ 20 °C/4 °C |
3.7 |
@ 25 °C |
38-93 cc |
560 |
||
1-BROMO-2-PROPANONE |
colourless liquid; rapidly becomes violet even in absence of air |
137 |
-36.5 |
136.99 |
sl sol |
@ 23 °C |
4.75 |
1.20 |
|||
1-CHLORO-2-PROPANONE |
colourless liquid |
119.7 |
-44.5 |
92.53 |
sol |
@ 25 °C |
40 oc |
||||
CHLORACETYL CHLORIDE |
colourless to slightly yellow liquid |
106 |
21.77 |
112.95 |
1.4202 |
2.35 |
|||||
2-CHLOROACETOPHENONE |
colourless to grey crystals |
247 |
56.5 |
154.6 |
insol |
@ 15 °C |
5.3 |
< 10 Pa |
118 |
||
CYCLOHEXANONE |
oily liquid; water-white to pale yellow liquid |
155.6 |
16.4 |
98.14 |
sol |
@ 25 °C; 0.9478 |
3.4 |
@ 26.4 °C |
1.1 ll |
63 cc |
420 |
CYCLOHEXANONE OXIME |
hexagonal prisms from petroleum ether |
206-210 |
89-90 |
113.18 |
sol |
||||||
CYCLOPENTANONE |
water-white, mobile liquid |
130.6 |
-51.3 |
84.12 |
insol |
0.948 |
2.3 |
@ 25 °C |
31cc |
||
DIACETONE |
colourless liquid |
167.9 |
-44 |
116.16 |
misc |
@ 25 °C |
4.0 |
0.13 |
1.8 ll |
66 oc |
acetone-free 603 commercial 643 |
DICHLORACETYL CHLORIDE |
colourless to yellow fuming liquid |
107 - 108 |
147.4 |
decomposes |
1.53 |
5.09 |
3.06 |
11.9 ll |
66 |
585 |
|
DIETHYL KETONE |
colourless, mobile liquid |
101.7 |
-39.8 |
86.13 |
v sol |
0.814 |
3.0 |
@ 25 °C |
1.6. |
13 oc |
452 |
DIKETENE |
clear, colourless liquid when pure |
127.4 |
-6.5 |
84.08 |
sol |
1.0897 |
2.9 |
34 oc |
|||
2,6-DIMETHYL-4-HEPTANONE |
colourless liquid |
168 |
- 42 |
142.2 |
insol |
0.805 |
4.9 |
0.23 |
@ 93 °C ul |
49 cc |
396 |
DIPROPYL KETONE |
144 |
-33 |
114.18 |
insol |
1.407 |
||||||
ETHYL AMYL KETONE |
167.5 |
128.21 |
insol |
@ |
|||||||
ETHYL BUTYL KETONE |
clear liquid |
@ 765 mm Hg |
-39 |
114.21 |
insol |
0.8183 |
@ 25 °C |
46 oc |
|||
2,5-HEXANEDIONE |
194 |
-5.5 |
114.4 |
v sol |
0.737 |
||||||
ISOPHORONE |
water-clear liquid |
@ 754 mm Hg |
-8.1 |
138.2 |
sl sol |
0.9229 |
4.77 |
@ 25 °C |
0.8 ll |
84 cc |
460 |
KETENE |
colourless gas |
- 56 |
-150 |
42.0 |
reacts |
1.4 |
Flammable gas |
||||
MESITYL OXIDE |
The substance can presumably form explosive peroxides • Reacts violently with strong oxidants • Attacks many plastics |
3 |
|||||||||
4-METHOXY-4-METHYL-2-PENTANONE |
water-white liquid |
147-163 |
130.21 |
v sol |
@ 25 °C |
||||||
METHYL AMYL KETONE |
water-white liquid |
151.5 |
-35.5 |
114.18 |
v sol |
@ 15 °C; 0.8068 |
3.9 |
@ 25 °C |
@ 66 °C ll |
39 cc |
393 |
METHYL BUTYL KETONE |
colourless liquid |
128 |
-57 |
100.16 |
sl sol |
0.8113 |
3.5 |
@ 25 °C |
1.3 ll |
25 cc |
423 |
2-METHYLCYCLO HEXANONE |
112.19 |
||||||||||
METHYL ETHYL KETONE |
colourless liquid |
79.6 |
-86.3 |
72.10 |
v sol |
0.805 |
2.41 |
10.33 |
@ 93 °C ul |
-9 cc |
404 |
5-METHYL-3-HEPTANONE |
colourless liquid |
157-162 |
128.24 |
insol in water |
0.820-0.824 /20 °C |
@ 0.27 |
59 |
||||
5-METHYL-2-HEXANONE |
colourless liquid |
144 |
73.9 |
114.21 |
sl sol |
0.888 /20 °C |
3.9 |
0.60 |
@ 93 °C ul |
36 cc |
191 |
METHYL ISOBUTYL KETONE |
colourless liquid |
116.8 |
-84.7 |
100.16 |
sl sol |
0.7978 |
3.5 |
2.09 |
@ 93 °C ul |
24 oc |
460 |
METHYL ISOPROPYL KETONE |
colourless liquid |
94 |
- 92 |
86.1 |
sl sol |
0.8 |
3.46 |
@ 29.6 °C |
1.2 ll |
3 |
456 |
METHYL PROPYL KETONE |
colourless liquid |
101.7 |
-77.8 |
86.13 |
sl sol |
0.805 |
3.0 |
@ 25 °C |
1.5 ll |
70 cc |
505 |
METHYLVINYL KETONE |
colourless liquid |
81.4 |
-7 |
70.09 |
sol |
@ 25 °C |
2.41 |
@ 25 °C |
2.1 ll |
-7 cc |
491 |
2,4-PENTANEDIONE |
colourless or slightly yellow liquid |
@ 746 mm Hg |
-23 |
100.12 |
v sol |
@ 25 °C |
3.5 |
0.39 |
2.4 ll |
34 cc |
335 |
Chemical Name |
Physical |
Chemical |
Subsidiary Risks |
ACETONE |
The vapour is heavier than air and may travel along the ground; distant ignition possible |
The substance can form explosive peroxides on contact with strong oxidants • Attacks many plastics |
3 |
ACETYL BROMIDE |
The substance decomposes on heating producing toxic and corrosive fumes • Reacts violently with water and alcohols, causing fire and explosion hazard |
||
ACETYL-CHLORIDE |
3 |
||
BENZOPHENONE |
Reacts with strong oxidants |
||
p-BENZOQUINONE |
Dust explosion possible if in powder or granular form, mixed with air • If dry, it can be charged elecrostatically by swirling, pneumatic transport, pouring, etc |
Reacts with strong oxidants causing fire and explosion hazard • Reacts violently with strong bases • Above 60 ºC when moist, is self-heating and decomposes giving off toxic gases (carbon monoxide) |
6.1 |
2-CHLOROACETOPHENONE |
On combustion, forms toxic and corrosive vapours • The substance decomposes on heating producing corrosive gas (hydrogen chloride) |
||
1-CHLORO-2-PROPANONE |
The substance polymerizes slowly under the influence of light • On combustion, forms toxic and corrosive gases (carbon oxides, hydrogen chloride, phosgene) • Reacts with strong oxidants |
||
CYCLOHEXANONE |
The vapour is heavier than air and may travel along the ground; distant ignition possible |
On combustion, forms carbon monoxide • Reacts with oxidants and nitric acid causing fire and explosion hazard |
3 |
CYCLOPENTANONE |
The vapour is heavier than air |
The substance easily polymerizes under the influence of acids • On combustion, forms toxic gases (carbon oxides) • Reacts with acids |
3 |
DIACETONE |
3 |
||
DICHLORACETYL CHLORIDE |
The substance decomposes on heating, on contact with moisture, alkali metal, earth alkali metal, metal powder, producing hydrogen chloride, phosgene, causing fire and explosion hazard • Reacts with strong oxidants, alcohols, water • Attacks many metals forming combustible gas |
||
DIETHYL KETONE |
The vapour is heavier than air and may travel along the ground; distant ignition possible • The vapour mixes well with air; explosive mixtures are easily formed |
Reacts violently with oxidants causing fire and explosion hazard • Attacks many plastics |
3 |
DIKETENE |
3 |
||
2,6-DIMETHYL-4-HEPTANONE |
Reacts with oxidants • Attacks some forms of plastics |
3 |
|
DIPROPYL KETONE |
3 |
||
ETHYL AMYL KETONE |
3 |
||
KETENE |
The gas is heavier than air and may travel along the ground; distant ignition possible |
The substance may readily polymerize • Reacts violently with many organic compounds • Reacts with water to form acetic acid • Decomposes in alcohol and ammonia |
|
MESITYL OXIDE |
The substance can presumably form explosive peroxides • Reacts violently with strong oxidants • Attacks many plastics |
3 |
|
4-METHOXY-4-METHYL-2-PENTANONE |
3 |
||
METHYL AMYL KETONE |
Reacts with oxidizing materials • Attacks some forms of plastics |
3 |
|
METHYL BUTYL KETONE |
Reacts violently with oxidants and may form unstable peroxides • Attacks plastics |
||
METHYL ETHYL KETONE |
3 |
||
5-METHYL-2-HEXANONE |
3 |
||
METHYL ISOBUTYL KETONE |
The vapour is heavier than air and may travel along the ground; distant ignition possible |
The substance can presumably form explosive peroxides • On combustion, forms carbon monoxide |
3 |
METHYL ISOPROPYL KETONE |
The vapour is heavier than air and may travel along the ground; distant ignition possible |
The substance decomposes on heating producing acrid smoke and toxic fumes • Reacts violently with strong oxidants |
3 |
METHYL PROPYL KETONE |
The vapour mixes well with air; explosive mixtures are easily formed |
Can react vigorously with oxidizing agents |
3 |
2,4-PENTANEDIONE |
The vapour is heavier than air |
The substance may polymerize under the influence of the light • On combustion, forms toxic carbon oxides • Reacts with strong oxidants, bases and reducing agents |
For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance
Chemical Name CAS-Number |
ICSC Short-Term Exposure |
ICSC Long-Term Exposure |
ICSC Routes of Exposure and Symptoms |
US NIOSH Target Organs & Routes of Entry |
US NIOSH Symptoms |
ACETONE 67-64-1 |
eyes; resp tract; CNS; liver; kidneys; stomach |
skin; CNS; blood cells |
Inhalation: salivation, confusion, cough, dizziness, drowsiness, headache, red head, sore throat, unconsciousness Skin: redness Eyes: redness, pain, blurred vision, possible corneal damage Ingestion: nausea, vomiting. |
Resp sys; skin; eyes; CNS Inh; ing; con |
Irrit eyes, nose, throat; head, dizz, CNS depres; derm |
ACETYL BROMIDE 506-96-7 |
resp tract; skin |
Inhalation: cough, sore throat, shortness of breath, laboured breathing, symptoms of delayed effects Skin: redness, pain, skin burns Eyes: pain, redness, blurred vision, severe deep burns Ingestion: burning sensation, abdominal cramps, vomiting. |
|||
BENZOPHENONE 119-61-9 |
eyes; skin; resp tract; CNS |
Inhalation: sore throat Skin: redness Eyes: redness |
|||
p-BENZOQUINONE 106-51-4 |
eyes; skin; resp tract; CNS; liver; kidneys |
skin; resp tract; liver; kidneys |
Inhalation: burning sensation, cough, nose bleeds, laboured breathing, shortness of breath, sore throat Skin: may be absorbed; redness, pain, brown staining, blister Eyes: redness, pain, loss of vision, brown staining Ingestion: abdominal pain, burning sensation, diarrhoea, vomiting, death. |
Eyes; skin Inh; ing; con |
Eye irrit; conj; kera; skin irrit |
1-CHLORO-2-PROPANONE 78-95-5 |
eyes; skin; resp tract; lungs |
skin |
Inhalation: cough, burning sensation, laboured breathing, sore throat Skin: may be absorbed, redness, skin burns, burning sensation, pain, delayed effects: blisters Eyes: redness, pain, blurred vision. |
||
2-CHLOROACETOPHENONE 532-27-4 |
eyes; skin; resp tract; CNS |
skin |
Inhalation: burning sensation of chest, cough, headache, laboured breathing, shortness of breath, vomiting, wheezing Skin: redness, pain Eyes: redness, pain, blurred vision, permanent partial loss of vision Ingestion: unconsciousness, loss of reflexes. |
Resp sys; skin; eyes Inh; ing; con |
Irrit eyes, skin, resp sys; pulm edema |
CYCLOHEXANONE 108-94-1 |
eyes; resp tract; skin |
Inhalation: cough, dizziness, drowsiness, dullness, sore throat, unconsciousness Skin: may be absorbed, dry skin, redness Eyes: Lacrimation, redness, pain, opacity of the cornea Ingestion: abdominal pain, burning sensation, drowsiness, dullness, unconsciousness. |
Eyes; skin; resp sys; CNS; liver; kidneys |
Irrit eyes; skin; muc memb; head; narco; coma; derm; in animals: liver, kidney damage |
|
CYCLOPENTANONE 120-92-3 |
eyes; skin; resp tract |
skin |
Inhalation: cough, sore throat Skin: redness Eyes: redness, pain. |
||
DIACETONE 123-42-2 |
Eyes; skin; resp sys; CNS; liver Inh; ing; con |
Irrit eyes, skin, nose, throat; corn damage; in animals: narco, liver damage |
|||
DICHLORACETYL CHLORIDE 79-36-7 |
eyes; skin; upper resp tract |
Inhalation: burning sensation , cough, laboured breathing Skin: redness, pain, blisters Eyes: redness, pain, severe deep burns Ingestion: abdominal cramps, burning sensation, weakness. |
|||
DIETHYL KETONE 96-22-0 |
eyes; skin; resp tract; lungs |
lungs |
Inhalation: cough , shortness of breath Skin: redness Eyes: redness. |
Resp sys; eyes; skin Inh; ing; con |
Irrit eyes, skin, muc memb, resp sys; cough, sneez |
DIKETENE 674-82-8 |
Inhalation: cough, headache, shortness of breath, dizziness, dullness Skin: dry skin, redness, pain Eyes: redness, pain Ingestion: abdominal cramps, dizziness, dullness, headache. |
||||
2,6-DIMETHYL-4-HEPTANONE 108-83-8 |
eyes; resp tract; lungs |
skin; liver; kidneys |
Inhalation: headache, dizziness, nausea, vomiting, sore throat Skin: redness, numbness Eyes: redness |
Eyes; skin; resp sys; CNS; liver; kidneys Inh; ing; con |
Irrit eyes, skin, nose, throat; head, dizz; derm; liver, kidney damage |
ETHYL BUTYL KETONE 106-35-4 |
eyes; skin; resp tract |
skin; liver; kidneys |
Inhalation: headache, dizziness, sore throat, unconsciousness Skin: redness Eyes: redness, pain. |
Resp sys; eyes; skin; CNS Inh; ing; con |
Irrit eyes, skin, muc memb; head, narco, coma; derm |
ISOPHORONE 78-59-1 |
eyes; skin |
skin |
Eyes; skin; resp sys; CNS; liver; kidneys Inh; ing; con |
Irrit eyes, nose, throat; head, nau, dizz, ftg, mal, narco; derm; in animals: kidney, liver damage |
|
KETENE 463-51-4 |
Inhalation: cough, shortness of breath Skin: redness Eyes: redness. |
Eyes, skin, resp sys Inh; con |
Irrit eyes, skin, nose, throat, resp sys; pulm edema |
||
METHYL AMYL KETONE 110-43-0 |
Eyes: Inhalation: headache, dizziness, blurred vision, unconsciousnessredness. |
Eyes; skin; resp sys; CNS; PNS Inh; ing; con |
Irrit eyes, skin, muc memb; head, narco, coma; derm |
||
METHYL BUTYL KETONE 591-78-6 |
eyes; skin; resp tract |
Inhalation: cough, drowsiness, headache, unconsciousness Skin: may be absorbed, dry skin, redness Eyes: redness, pain, blurred vision Ingestion: abdominal pain, diarrhoea, nausea, sore throat. |
|||
2-METHYLCYCLOHEXANONE 583-60-8 |
eyes; skin; resp tract; CNS |
skin; CNS |
CNS; skin; resp sys; liver; kidneys Inh; abs; ing; con |
In animals: irrit eyes, muc memb; narco; derm |
|
METHYL ETHYL KETONE 78-93-3 |
Eyes; skin; resp sys; CNS Inh; ing; con |
Irrit eyes, skin, nose; head, dizz; vomit; derm |
|||
5-METHYL-3-HEPTANONE 541-85-5 |
eyes; skin; resp tract; lungs |
skin |
Eyes; skin; resp sys; CNS |
Irrit eyes, skin, muc memb; head, narco, coma; derm |
|
5-METHYL-2-HEXANONE 110-12-3 |
eyes; skin; resp tract |
skin; eyes |
Inhalation: headache, dizziness, drowsiness Skin: redness Eyes: redness Ingestion: nausea, vomiting. |
Eyes; skin; resp sys; CNS; liver; kidneys Inh; ing; con |
Irrit eyes, skin, muc memb; head, narco, coma; derm; in animals: liver, kidney damage |
METHYL ISOBUTYL KETONE 108-10-1 |
eyes; skin; resp tract; CNS |
skin; thymus; lungs; brain; nasal passage |
Inhalation: burning sensation, diarrhoea, headache, nausea, sore throat, unconsciousness, vomiting, weakness Skin: dry skin, burning sensation Eyes: redness, pain. |
Eyes; skin; resp sys; CNS; PNS Inh; abs; ing; con |
Irrit eyes, nose; peri neur; weak, pares; derm; head, drow |
METHYL ISOPROPYL KETONE 563-80-4 |
Inhalation: cough, headache, sore throat, weakness Skin: may be absorbed Eyes: redness Ingestion: nausea, vomiting . |
Eyes; skin; resp sys Inh; ing; con |
Irrit eyes, skin, muc memb, resp sys; cough |
||
METHYL PROPYL KETONE 107-87-9 |
eyes; skin; resp tract; CNS |
skin; liver; kidneys; blood |
Inhalation: dullness, drowsiness Skin: dry skin, redness Eyes: redness, pain Ingestion: nausea, vomiting. |
Eyes; skin; resp sys; CNS Inh; ing; con |
Irrit eyes, skin, muc memb; head; derm; narco, coma |
2,4-PENTANEDIONE 123-54-6 |
eyes; skin; resp tract |
skin |
Inhalation: dizziness, drowsiness, headache, laboured breathing, nausea, vomiting, ataxia and tremors Skin: may be absorbed, redness Eyes: Redness, pain Ingestion: diarrhoea, nausea, vomiting, weakness, ataxia. |
Resp sys eyes; skin; CNS |
Chemical Formula |
Chemical |
Synonyms |
CAS-Number |
67641 |
ACETONE |
Dimethylformaldehyde; |
67-64-1 |
98862 |
ACETOPHENONE |
Acetylbenzene; |
98-86-2 |
506967 |
ACETYL BROMIDE |
Acetic acid, bromide; |
506-96-7 |
75365 |
ACETYL CHLORIDE |
Acetic acid, chloride; |
75-36-5 |
119619 |
BENZOPHENONE |
Benzoylbenzene; |
119-61-9 |
106514 |
p-BENZOQUINONE |
1,4-Benzoquine; |
106-51-4 |
598312 |
1-BROMO-2-PROPANONE |
Acetonyl Bromide; |
598-31-2 |
532274 |
2-CHLOROACETOPHENONE |
a-Chloroacetophenone; |
532-27-4 |
79049 |
CHLORACETYL CHLORIDE |
Chloroacetic acid chloride; |
79-04-9 |
78955 |
1-CHLORO-2-PROPANONE |
Acetonyl chloride; |
78-95-5 |
108941 |
CYCLOHEXANONE |
Cyclohexyl ketone; |
108-94-1 |
120923 |
CYCLOPENTANONE |
Adipic ketone; |
120-92-3 |
123422 |
DIACETONE |
Diacetone alcohol; |
123-42-2 |
79367 |
DICHLORACETYL CHLORIDE |
a, a-Dichloroacetyl chloride; |
79-36-7 |
96220 |
DIETHYL KETONE |
DEK; |
96-22-0 |
674828 |
DIKETENE |
3-Buteno-beta-lactone; |
674-82-8 |
108838 |
2,6-DIMETHYL-4-HEPTANONE |
Diisobutyl ketone; |
108-83-8 |
123193 |
DIPROPYL KETONE |
Butyrone; |
123-19-3 |
106683 |
ETHYL AMYL KETONE |
3-Octanone; |
106-68-3 |
106354 |
ETHYL BUTYL KETONE |
n-Ethyl butyl ketone, 3-heptanone |
106-35-4 |
110134 |
2,5-HEXANEDIONE |
Acetone, acetonyl-; |
110-13-4 |
78591 |
ISOPHORONE |
Isoacetophorone; |
78-59-1 |
463514 |
KETENE |
Carbomethene; |
463-51-4 |
141797 |
MESITYL OXIDE |
Acetone, isopropylidene; |
141-79-7 |
107700 |
4-METHOXY-4-METHYL-2-PENTANONE |
UN2293 |
107-70-0 |
110430 |
METHYL AMYL KETONE |
Amyl methyl ketone; |
110-43-0 |
591786 |
METHYL BUTYL KETONE |
2-Hexanone; |
591-78-6 |
583608 |
2-METHYLCYCLOHEXANONE |
o-Methylcyclohexanone |
583-60-8 |
78933 |
METHYL ETHYL KETONE |
2-Butanone ; |
78-93-3 |
541855 |
5-METHYL-3-HEPTANONE |
Ethyl-sec-amyl ketone; |
541-85-5 |
110123 |
5-METHYL-2-HEXANONE |
Isoamyl methyl ketone; |
110-12-3 |
108101 |
METHYL ISOBUTYL KETONE |
Hexone; |
108-10-1 |
563804 |
METHYL ISOPROPYL KETONE |
2-Acetyl propane; |
563-80-4 |
107879 |
METHYL PROPYL KETONE |
Ethyl acetone; |
107-87-9 |
78944 |
METHYLVINYL KETONE |
Acetone, methylene; |
78-94-4 |
100641 |
OXIME CYCLOHEXANONE |
(Hydroxyimino)cyclohexane |
100-64-1 |
123546 |
2,4-PENTANEDIONE |
Acetoacetone; |
123-54-6 |