Chemical Name

CAS-Number

ICSC Short-Term Exposure

ICSC Long-Term Exposure

ICSC Routes of Exposure and Symptoms

US NIOSH Target Organs & Routes of Entry

US NIOSH Symptoms

BROMINE          7726-95-6

eyes; skin; resp tract; lungs

skin; lungs

Inhalation: corrosive, burning sensation, cough, dizziness, headache, laboured breathing, sore throat

Skin: corrosive, redness, skin burns, pain

Eyes: corrosive, redness, pain, severe deep burns

Ingestion: corrosive, abdominal cramps, burning sensation, sore throat, collapse

Resp sys; eyes; CNS; skin Inh; ing; con

Dizz, head; lac, epis; cough, feeling of oppression, pulm edema, pneu; abdom pain, diarr; measle-like eruptions; eye, skin burns

BROMINE PENTAFLUORIDE     7789-30-2

eyes; skin; resp tract; lungs

liver; kidneys; resp tract

Inhalation: burning sensation, cough, shortness of breath, sore throat

Skin: skin burns, pain, blisters

Eyes: pain, blurred vision, severe deep burns

Ingestion: abdominal pain, burning sensation

Eyes; skin; resp sys; liver; kidneys Inh; ing; con

Irrit eyes, skin, resp sys; corn nec; skin burns; cough; dysp, pulm edema; liver, kidney inj

CARBONYL FLUORIDE     353-50-4

eyes; skin; resp tract; lungs; skin

blood

Inhalation: cough, laboured breathing, sore throat, symptoms may be delayed

Skin: redness, on contact with liquid: frostbite

Eyes: redness

Eyes; skin; resp sys; bone Inh; con

Irrit eyes, skin, muc memb, resp sys; eye, skin burns; lac; cough; pulm edema, dysp; chronic exposure: GI pain, musc fib, skeletal fluorosis; liq: frostbite

CHLORINE         7782-50-5

eyes; skin; resp tract; lungs; skin

lungs

Inhalation: corrosive, burning sensation, cough, headache, laboured breathing, nausea, shortness of breath, sore throat, symptoms may be delayed

Skin: corrosive, skin burns, pain

Eyes: corrosive, pain, blurred vision, severe deep burns

Resp sys, eyes, skin Inh; con

Burning of eyes, nose, mouth; lac, rhin; cough, choking, subs pain; nau, vomit; head, dizz; syncope; pulm edema; pneu; hypox; derm; liq: frostbite

CHLORINE OXIDE     10049-04-4

eyes; skin; resp tract; lungs; skin

lungs

Inhalation: corrosive, cough, headache, laboured breathing, nausea, shortness of breath, sore throat, symptoms may be delayed

Skin: corrosive, redness, serious skin burns, pain

Resp sys; eyes Inh; ing (liq); con

Irrit eyes, nose, throat; cough, wheez, bron, pulm edema; chronic bron

CHLORINE TRIFLUORIDE     7790-91-2

eyes; skin; resp tract; lungs

Inhalation: cough, laboured breathing, sore throat

Skin: corrosive, redness, serious skin burns, pain

Eyes: permanent loss of vision, severe deep burns, blindness

Skin; eyes; resp sys Inh; ing (liq); con

Eye, skin burns (liq or high vap conc); resp irrit; in animals: lac; corn ulcer; pulm edema

FLUORINE         7782-41-4

eyes; skin; resp tract; lungs

skin

Inhalation: corrosive, cough, shortness of breath, sore throat, choking

Skin: corrosive, redness, serious skin burns, on contact with liquid: frostbite

Eyes: redness, severe deep burns

Resp sys; eyes; liver; kidneys Inh; con

Irrit eyes, nose, resp sys; lar spasm, bron spasm; pulm edema; eye, skin burns; in animals: liver, kidney damage

HYDROGEN FLUORIDE     7664-39-3

eyes; skin; resp tract; lungs

Inhalation: cough, laboured breathing, sore throat, symptoms may have delayed effects

Skin: may be adsorbed, serious skin burns

Eyes: redness, pain, blurred vision

Ingestion: abdominal pain, diarrhoea, sore throat, vomiting, symptoms may have delayed effects

Eyes; resp sys; skin; bone Inh; abs (liq); ing (soln); con

Irrit eyes, skin, nose, throat; pulm edema; eye, skin burns; rhinitis; bron; bone changes

OXYGEN DIFLUORIDE     7783-41-7

eyes; skin; resp tract; lungs

Inhalation: cough, laboured breathing, sore throat

Skin: on contact with liquid: frostbite

Resp sys; eyes; skin Inh; con

Irrit eyes, skin, resp sys; head; pulm edema; eye, skin burns (from contact with the gas under pressure)

PERCHLORYL FLUORIDE     7616-94-6

resp tract; skin

blood

Inhalation: headache

Skin: on contact with liquid: frostbite

Eyes: severe deep burns

Resp sys; skin; blood Inh; con (liq)

Irrit resp sys; liq: frostbite; in animals: methemo; cyan; weak; dizz, head; pulm edema; pneuitis; anoxia

PHOSGENE       75-44-5

eyes; skin; resp tract; lungs

lungs

Inhalation: corrosive, burning sensation, cough, laboured breathing, shortness of breath, sore throat

Resp sys; skin; eyes Inh; con (liq)

Irrit eyes; dry, burning throat; vomit; cough, foamy sputum, dysp, chest pain, cyan; liq: frostbite

SULPHUR CHLORIDE     10025-67-9

eyes; skin; resp tract; lungs; corrosive on ingestion

skin

Inhalation: burning sensation, cough, headache, laboured breathing, nausea, vomiting

Skin: redness, skin burns, burning sensation, pain, blisters

Eyes: redness, pain, severe deep burns

Resp sys; skin; eyes Inh; ing; con

Irrit eyes, skin, muc memb; lac; cough; eye, skin burns; pulm edema

SULPHUR HEXAFLUORIDE     2551-62-4

skin

Skin: on contact with liquid: frostbite

Eyes: corneal damage

Resp sys Inh

Asphy: incr breath rate, pulse rate; slight musc inco, emotional upset; ftg, nau, vomit, convuls

SULPHUR PENTAFLUORIDE     5714-22-7

Resp sys; CNS; eyes; skin Inh; ing; con

Irrit eys, skin, resp sys; in animals: pulm edema, hemorr

 

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Chemical Formula

Chemical

Synonyms
UN Code

CAS-Number

7726956

BROMINE

Bromine
UN1744

7726-95-6

7789302

BROMINE PENTAFLUORIDE

Bromine pentafluoride
UN1745

7789-30-2

7789755

CALCIUM FLUORIDE

7789-75-5

353504

CARBONYL FLUORIDE

Carbon difluoride oxide;
Carbon fluoride oxide;
Carbon oxyfluoride;
Carbonyl difluoride;
Difluoroformaldehyde;
Fluophosgene;
Fluoroformyl fluoride;
Fluorophosgene
UN2417

353-50-4

7782505

CHLORINE

Molecular chlorine
UN1017

7782-50-5

10049044

CHLORINE OXIDE

Chlorine dioxide;
Chlorine(IV) oxide;
Chlorine peroxide;
Chloroperoxyl

10049-04-4

7790912

CHLORINE TRIFLUORIDE

Chlorine fluoride;
Chlorotrifluoride
UN1749

7790-91-2

7782414

FLUORINE

Fluorine
UN1045

7782-41-4

10035106

HYDROGEN BROMIDE

Anhydrous hydrobromic acid;
Hydrobromic acid solution
UN1788

10035-10-6

7664393

HYDROGEN FLUORIDE

Hydrofluoric acid;
Hydrofluoride
UN1052
UN1790

7664-39-3

7553562

IODINE

7553-56-2

10025851

NITROGEN CHLORIDE

Chlorine nitride;
Nitrogen trichloride;
Trichloramine;
Trichlorine nitride

10025-85-1

7783542

NITROGEN TRIFLUORIDE

Nitrogen fluoride
UN2451

7783-54-2

7783417

OXYGEN DIFLUORIDE

Fluorine monoxide;
Fluorine oxide;
Oxygen fluoride
UN2190

7783-41-7

7616946

PERCHLORYL FLUORIDE

Chlorine fluoride oxide;
Chlorine oxyfluoride
UN3083

7616-94-6

75445

PHOSGENE

Carbonyl chloride;
Carbonyl dichloride;
Chloroformyl chloride
UN1076

75-44-5

7789697

PHOSPHOROUS PENTABROMIDE

7789-69-7

7789608

PHOSPHOROUS TRIBROMIDE

Phosphorous bromide;
Tribromophosphine
UN1808

7789-60-8

16893859

SODIUM HEXAFLUOROSILICATE

16893-85-9

10025679

SULPHUR CHLORIDE

Disulphurdichloride;
Sulphurmonochloride;
Sulphurisubchloride;
Thiosulphurous dichloride

10025-67-9

10545990

SULPHUR DICHLORIDE

10545-99-0

2551624

SULPHUR HEXAFLUORIDE

Sulphurfluoride
UN1080

2551-62-4

5714227

SULPHUR PENTAFLUORIDE

Disulphurdecafluoride;
Sulphurdecafluoride

5714-22-7

2699798

SULPHURYL FLUORIDE

Sulphuric oxyfluoride
UN2191

2699-79-8

 

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Chemical Name

CAS-Number

Colour/Form

Boiling Point (°C)

Melting Point (°C)

Molecular Weight

Solubility in Water

Relative Density (water=1)

Relative Vapour Density (air=1)

Vapour Pressure/ (Kpa)

Inflam.
Limits

Flash Point (°C)

Auto Ignition Point (°C)

1,3-BUTANEDIOL
107-88-0

viscous liquid; pure compound is colourless

207.5

<50

90.12

sol

1.002

3.2

8 Pa

121

394

1,4-BUTANEDIOL
110-63-4

colourless, viscid liquid

230

20.1

90.12

misc

1.0171

3.1

@ 37.7 °C

121 oc

350

DIMETHYLENE GLYCOL
513-85-9

nearly colourless liquid or solid

90.12

3.1

402

DIETHYLENE GLYCOL
111-46-6

colourless liquid; syrupy liquid

245.8

-10.4

106.1

sol

1.18

3.66

5 Pa

1.6 ll
10.8 ul

143

400

DIPROPYLENE GLYCOL
110-98-5

colourless, slightly viscous liquid

233

134.17

misc

1.0252

4.63

@ 25 °C

137

2-ETHYL-1,3-HEXANE­DIOL
94-96-2

slightly oily liquid; colourless liquid

244.

-40

146.22

sl sol

@ 22 °C/4 °C

5.03

< 0.01 mm Hg

110 oc

335

ETHYLENE GLYCOL
107-21-1

slightly viscous liquid; clear, colourless syrupy liquid

197.6

-13

62.07

misc

1.1135

2.14

7 Pa

3.2 ll
15.3 ul

111 cc

398

GLYCEROL
56-81-5

clear colourless syrupy liquid

290

18

92.09

sol

1.2613

320

392

1,6-HEXANEDIOL
629-11-8

crystals

208

42.8

118.17

sol

@ 0 °C/4 °C

4.07

@ 25 °C (est)

101

320

2,5-HEXANEDIOL
2935-44-6

216-218

43

118.17

sol

0.9610

HEXYLENE GLYCOL
107-41-5

colourless liquid

198

-50

118.2

sol

@ 17 °C

4.1

6.7 Pa

1.3 ll
7.4 ul

93

260

NEOPENTYL GLYCOL
126-30-7

208

130

104.14

sol

PENTAERYTHRITOL
115-77-5

ditetragonal crystals from diluted hydrochloric acid; white, crystalline powder

sublimes

260

136.1

sol

@ 25 °C/4 °C

PROPYLENE GLYCOL
57-55-6

colourless viscous liquid

187.6

-59

76.1

misc

1.0361

2.6

106.6 Pa

2.6 ll
12.5 ul

99 cc

371

 

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Chemical Name
CAS-Number

Physical

Chemical

UN Class or Division /  Subsidiary Risks

1,4-BUTANEDIOL
110-63-4

On combustion, forms toxic fumes (CO) • Reacts with strong oxidants

1,6-HEXANEDIOL
629-11-8

Dust explosion possible if in powder or granular form, mixed with air

On combustion, forms toxic gases

DIETHYLENE GLYCOL
111-46-6

Reacts violently with strong oxidants • Attacks many plastics

ETHYLENE GLYCOL
107-21-1

On combustion, forms toxic gases • Reacts with strong oxidants and strong bases

HEXYLENE GLYCOL
107-41-5

The substance polymerizes • Reacts with strong oxidants

PROPYLENE GLYCOL
57-55-6

The vapour is heavier than air

Reacts with strong oxidants, eg, potassium perchlorate, causing fire and explosion hazard

For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance

 

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Sunday, 07 August 2011 06:14

Glycerols & Glycols: Health Hazards

Chemical Name

CAS-Number

ICSC Short-Term Exposure

ICSC Long-Term Exposure

ICSC Routes of Exposure and Symptoms

US NIOSH Target Organs & Routes of Entry

US NIOSH Symptoms

1,3-BUTANEDIOL     107-88-0

eyes; skin; resp tract

Inhalation: cough

Skin: redness

Eyes: stinging sensation

1,4-BUTANEDIOL     110-63-4

eyes; resp tract; CNS; kidneys

Inhalation: cough, dizziness, headache, unconsciousness

Eyes: redness, irritant

Ingestion: unconsciousness

DIETHYLENE GLYCOL     111-46-6

eyes; skin; resp tract; CNS; liver; kidneys

liver; kidneys

Skin: redness

Eyes: redness

Ingestion: confusion, diarrhoea, dizziness, drowsiness, nausea, unconsciousness, vomiting

DIPROPYLENE GLYCOL     110-98-5

eyes; skin; resp tract

skin

Inhalation: cough

Skin: redness

Eyes: redness

ETHYLENE GLYCOL     107-21-1

eyes; skin; resp tract; kidneys; CNS

CNS; eyes

Inhalation: cough, dizziness, headache

Skin: dry skin, redness

Eyes: redness

Ingestion: abdominal pain, dullness, nausea, unconsciousness, vomiting

Eyes; skin; resp sys; CNS Inh; ing; con

Irrit eyes, skin, nose, throat; nau, vomit, abdom pain; weak; dizz, stupor, convuls, CNS depres; skin sens

1,6-HEXANEDIOL     629-11-8

eyes; resp tract

Inhalation: cough

Eyes: Irritation, redness

2,5-HEXANEDIOL     2935-44-6

eyes; skin; resp tract

skin; CNS

HEXYLENE GLYCOL     107-41-5

eyes; skin

skin; kidneys

Inhalation: cough

Skin: dry skin, redness

Eyes: redness

Ingestion: abdominal cramps, diarrhoea, nausea, vomiting

Eyes; skin; resp sys Inh; ing; con

Irrit eyes, skin, resp sys; head, dizz, nau, inco, CNS depres; derm, skin sens

NEOPENTYL GLYCOL     126-30-7

eyes; skin; resp tract; lungs

lungs; kidneys

PROPYLENE GLYCOL     57-55-6

eyes

Eyes: pain

 

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Chemical Formula

Chemical

Synonyms
UN Code

CAS-Number

584032

1,2-BUTANEDIOL

1,2-Butylene glycol

584-03-2

107880

1,3-BUTANEDIOL

Butane-1,3-diol;
b-Butylene glycol;
1,3-Butylene glycol;
1,3-Dihydroxybutane;
Methyltrimethylene glycol

107-88-0

110634

1,4-BUTANEDIOL

Butanediol;
Butane-1,4-diol;
1,4-Butylene glycol;
1,4-Dihydroxybutane;
Tetramethylene 1,4-diol;
1,4-Tetramethylene glycol

110-63-4

96242

3-CHLORO-1,2-PROPANEDIOL

Chlorhydrin;
Chlorodeoxyglycerol;
1-Chloro-2,3-dihydroxypropane;
3-Chloro-1,2-dihydroxypropane
UN2689

96-24-2

111466

DIETHYLENE GLYCOL

Bis(2-hydroxyethyl) ether;
Dihydroxydiethyl ether;
2,2'-Dihydroxyethyl ether;
Ethylene diglycol;
Glycol ether;
Glycol ethyl ether;
3-Oxapentane-1,5-diol;
3-Oxa-1,5-pentanediol;
2,2'-Oxybisethanol;
2,2'-Oxydiethanol

111-46-6

513859

DIMETHYLENE GLYCOL

2,3-Butanediol;
2,3-Butylene glycol;
2,3-Dihydroxybutane;

513-85-9

110985

DIPROPYLENE GLYCOL

2,2'-Dihydroxydipropyl ether;
2,2'-Dihydroxyisopropyl ether;
1,1'-Oxydi-2-propanol;
2-Propanol, 1,1'-Oxydi

110-98-5

94962

2-ETHYL-1,3-HEXANEDIOL

Ethyl hexanediol;
2-Ethylhexane-1,3-diol;
2-Ethylhexanediol-1,3;
Ethyl hexylene glycol;
2-Ethyl-3-propyl-1,3-propanediol;
3-Hydroxymethyl-n-heptane-4-ol;
Octylene glycol

94-96-2

107211

ETHYLENE GLYCOL

1,2-Dihydroxyethane;
1,2-Ethandiol;
1,2-Ethanediol;
Ethane-1,2-diol;
Ethylene alcohol;
Ethylene dihydrate;
Glycol;
Glycol alcohol;
Monoethylene glycol

107-21-1

56815

GLYCEROL

Glycerin;
Glycerine;
Glycyl alcohol;
1,2,3-Propanetriol;
Star;
Superol;
Synthetic glycerin;
Trihydroxypropane;
1,2,3-Trihydroxypropane

56-81-5

629118

1,6-HEXANEDIOL

Hexamethylene glycol

629-11-8

2935446

2,5-HEXANEDIOL

2935-44-6

107415

HEXYLENE GLYCOL

2,4-Dihydroxy-2-methylpentane;
2-Methyl pentane-2,4-diol;
2-Methyl-2,4-pentanediol

107-41-5

126307

NEOPENTYL GLYCOL

Dimethylolpropane;
2,2-Dimethyl-1,3-propanediol;
Dimethyltrimethylene glycol

126-30-7

115775

PENTAERYTHRITOL

2,2-Bis(hydroxymethyl)-1,3-propanediol;
Methane tetramethylol;
Pentaerythrite;
1,3-Propanediol, 2,2-Bis(hydroxymethyl)-;
Tetrahydroxymethylmetane;
Tetramethylolmethane

115-77-5

57556

PROPYLENE GLYCOL

1,2-Dihydroxypropane;
Methylethylene glycol;
Methyl glycol;
Monopropylene glycol;
1,2-Propanediol

57-55-6

 

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Chemical Name
CAS-Number

Colour/Form

Boiling Point (°C)

Melting Point (°C)

Molecular Weight

Solubility in Water

Relative Density (water=1)

Relative Vapour Density (air=1)

Vapour Pressure/ (Kpa)

Inflam.
Limits

Flash Point (°C)

Auto Ignition Point (°C)

1,4-BUTANEDIOL DIGLYCIDYL ETHER
2425-79-8

266

-202.28

@ 25 °C

DIETHYLENE GLYCOL DIETHYL ETHER
112-36-7

colourless liquid

189

-44.3

162.22

v sol

0.907

5.6

79 Pa

71 cc

174

DIETHYLENE GLYCOL MONOBUTYL ETHER
112-34-5

colourless liquid

230.4

-68.1

162.2

misc

0.9553

5.58

2.99 Pa

78

225

DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE
124-17-4

clear liquid

245

-32

204.30

sol

0.985

< 0.01 mm Hg

DIETHYLENE GLYCOL MONOETHYL ETHER
111-90-0

colourless liquid

196

134.17

misc

0.9881

4.62

@ 25 °C

@ 135 °C ll

96 oc

204

DIETHYLENE GLYCOL MONOMETHYL ETHER
111-77-3

colourless liquid

193

< -84

120.1

misc

1.0270

4.14

30 Pa

1.6 ll
18.1 ul

93 oc

215

DIPROPYLENE GLYCOL METHYL ETHER
34590-94-8

colourless liquid

190

-80

148.2

misc

@ 25 °C

5.11

@ 26 °C

1.3 ll
10.4 ul

85 cc

270

2-ETHOXYETHANOL
110-80-5

colourless liquid

135

-70

90.12

v sol

0.9297

3.1

0.5

@ 93 °C ll

44 cc

235

ETHYLENE GLYCOL DIETHYL ETHER
629-14-1

colourless liquid

123.5

-74

118.2

2 %

0.8484

4.07

9.4 mm Hg

ETHYLENE GLYCOL ETHYL ETHER ACETATE
111-15-9

colourless liquid

156

-61.7

132.2

v sol

0.9740

4.72

0.16

1.7 ll
13.0 ul

52 cc

379

ETHYLENE GLYCOL METHYL ETHER
109-86-4

colourless liquid

125

-85.1

76.09

misc

0.9647

2.62

0.83

2.3 ll
24.5 ul

42 cc

285

ETHYLENE GLYCOL MONOBUTYL ETHER
111-76-2

colourless liquid

171-172

-75

118.2

misc

0.9015

4.1

0.10

@ 93 °C ll

61 cc

238

ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE
112-07-2

colourless liquid

192.3

-64.5

160.24

1.1 g/100 g

0.9422

5.5

30-40 Pa

@ 93 °C ll

71 cc

340

ETHYLENE GLYCOL, MONOMETHYL ETHER ACETATE
110-49-6

colourless liquid

143

-65.1

118.13

v sol

@ 19 °C/19 °C

4.1

0.44

1.7 ll
8.2 ul

45 cc

394

ETHYLENE GLYCOL MONOPROPYL ETHER
2807-30-9

volatile liquid

149.8

<-70

104.1

sol

0.9112

3.6

200 Pa

5.5 ll
23 ul

49

230

ETHYLENE GLYCOL PHENYL ETHER
122-99-6

oily liquid; colourless liquid

245

14

138.16

insol

1.1094

4.8

5.2

1.4 ll
9.0 ul

121

PROPYLENE GLYCOL MONOMETHYL ETHER
107-98-2

colourless liquid

@ 740 mm Hg

-96.7

90.1

v sol

0.9620

3.11

1.6

1.6 ll
13.8 ul

38 oc

 

Back

Chemical Name

CAS-Number

Physical

Chemical

UN Class or Division / Subsidiary Risks

DIETHYLENE GLYCOL DIETHYL ETHER
112-36-7

The substance can form explosive peroxides. •On heating or on burning producing acrid smoke and irritating fumes. •Reacts with strong oxidants

DIETHYLENE GLYCOL MONOBUTYL ETHER
112-34-5

Reacts with strong oxidants, causing fire and explosion hazard

DIETHYLENE GLYCOL METHYL ETHER
111-77-3

The substance can presumably form explosive peroxides. •Reacts with strong oxidants

DIPROPYLENE GLYCOL METHYL ETHER
34590-94-8

The substance can presumably form explosive peroxides in contact with air. •Reacts violently with strong oxidants

2-ETHOXYETHANOL
110-80-5

The substance can form explosive peroxides. •The substance decomposes on burning producing toxic gas. •Reacts with strong oxidants causing fire and explosion hazard. •Attacks many plastics and rubber

3

ETHYLENE GLYCOL DIETHYL ETHER
629-14-1

3

ETHYLENE GLYCOL MONOBUTYL ETHER
111-76-2

The substance can form explosive peroxides. •The substance decomposes, producing toxic fumes. •Reacts with strong oxidants, causing fire and explosion hazard

6.1

ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE
112-07-2

The vapour mixes well with air

Reacts with strong oxidants causing fire and explosion hazard

ETHYLENE GLYCOL, ETHYL ETHER ACETATE
111-15-9

The vapour is heavier than air

Reacts with strong oxidants causing fire and explosion hazard

3

ETHYLENE GLYCOL, MONOMETHYL ETHER ACETATE
110-49-6

3

ETHYLENE GLYCOL METHYL ETHER
109-86-4

The substance can form explosive peroxides. •The substance decomposes on burning and on contact with strong caustics, producing toxic gas. •Reacts with strong oxidants causing fire and explosion hazard

3

ETHYLENE GLYCOL PHENYL ETHER
122-99-6

The vapour is heavier than air

Reacts with oxidants

ETHYLENE GLYCOL MONOPROPYL ETHER
2807-30-9

The vapour is heavier than air and may travel along the ground; distant ignition possible

PROPYLENE GLYCOL MONOMETHYL ETHER
107-98-2

The substance can presumably form explosive peroxides. •Reacts with strong oxidants

For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance

 

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Sunday, 07 August 2011 05:57

Glycol Ethers: Health Hazards

Chemical Name

CAS-Number

ICSC Short-Term Exposure

ICSC Long-Term Exposure

ICSC Routes of Exposure and Symptoms

US NIOSH Target Organs & Routes of Entry

US NIOSH Symptoms

1,4-BUTANEDIOL DIGLYCIDYL ETHER     2425-79-8

eyes; skin; resp tract; lungs

skin

DIETHYLENE GLYCOL DIETHYL ETHER 112-36-7

eyes; skin; resp tract

Inhalation: cough

Skin: redness

Eyes: redness

Ingestion: diarrhoea, headache, nausea, vomiting

DIETHYLENE GLYCOL DIGLYCIDYL ETHER     4206-61-5

lungs

skin; CNS; blood; kidneys

DIETHYLENE GLYCOL MONOBUTYL ETHER     112-34-5

eyes; skin; CNS

skin

Skin: may be absorbed, redness

Eyes: redness, pain

Ingestion: headache, unconsciousness, vomiting

DIETHYLENE GLYCOL MONOETHYL ETHER     111-90-0

lungs

skin

DIETHYLENE GLYCOL MONOMETHYL ETHER     111-77-3

eyes; skin; resp tract

skin; lungs; may impair male fertility

Skin: redness, roughness

Eyes: redness

DIPROPYLENE GLYCOL METHYL ETHER  34590-94-8

Skin: dry skin

Resp sys; eyes; CNS Inh; abs; ing; con

Irrit eyes, nose, throat; weak, li-head, head

2-ETHOXYETHANOL     110-80-5

eyes; skin; resp tract; CNS; liver; kidneys

skin; male fertility; birth defects

Inhalation: cough, drowsiness, headache, shortness of breath, sore throat, weakness

Skin: may be absorbed

Eyes: Blurred vision

Ingestion: abdominal pain, nausea, vomiting

Resp sys; eyes; blood; kidneys; liver; repro sys; hemato sys Inh; abs; ing; con

In animals: irrit eyes, resp sys; blood changes; liver, kidney, lung damage; repro, terato effects

ETHYLENE GLYCOL ETHYL ETHER ACETATE     111-15-9

CNS; blood

liver; kidneys

Inhalation: cough, drowsiness, headache, nausea, shortness of breath, sore throat, vomiting

Skin: may be absorbed, dizziness, headache, nausea and vomiting

Eyes: blurred vision

Ingestion: abdominal pain, drowsiness, headache, nausea, vomiting

Resp sys; eyes; GI tract; repro sys; hemato sys Inh; abs; ing; con

Irrit eyes, nose; vomit; kidney damage; para; in animals: repro, terato effects

ETHYLENE GLYCOL METHYL ETHER  109-86-4

eyes; resp tract; CNS; liver; kidneys

Inhalation: confusion, dizziness, headache, nausea, unconsciousness, vomiting, weakness

Skin: may be absorbed

Eyes: blurred vision

Eyes; resp sys; CNS; blood; kidneys; repro sys; hemato sys Inh; abs; ing; con

Irrit eyes, nose, throat; head, drow, weak; ataxia, tremor, som; anemic pallor, in animals: repro, terato effects

ETHYLENE GLYCOL MONOBUTYL ETHER     111-76-2

eyes; skin; resp tract; CNS; liver; kidneys

skin

Inhalation: cough, drowsiness, headache, nausea

Skin: may be absorbed, dry skin

Eyes: redness, pain, blurred vision

Ingestion: abdominal pain, diarrhoea, nausea, vomiting

Liver; kidneys; lymphoid sys; skin; blood; eyes; resp sys; hemato sys; CNS Inh; abs; ing; con

Irrit eyes, skin, nose, throat; hemolysis, hemog; CNS depres, head, vomit

ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE           112-07-2

eyes; skin; resp tract; kidneys; blood

skin; liver; bone marrow

Inhalation: cough, headache, nausea

Skin: redness

Eyes: redness

Eyes; skin; resp sys; CNS; hemato sys; blood; kidneys; liver; lymphoid sys imh

Irrit eyes, skin, nose, throat; hemolysis, hemog; CNS depres, head, vomit

ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE           110-49-6

CNS

skin; liver; kidneys;blood

Inhalation: Confusion, dizziness, headache, nausea, unconsciousness, vomiting, weakness.

Skin: Dizziness, headache, nausea, vomiting

Eyes: Blurred vision.

Ingestion: Abdominal pain, burning sensation, confusion, dizziness, headache, nausea, unconsciousness.

Eyes; resp sys; kidneys; brain; CNS; PNS; repro sys; hemato sys Inh; abs; ing; con

Irrit eyes, nose, throat; kidney, brain damage; in animals: narco; repro, terato effects

ETHYLENE GLYCOL MONOPROPYL ETHER     2807-30-9

eyes; skin; resp tract; lungs

blood; spleen; kidneys

Inhalation: confusion, cough, headache, nausea, sore throat, symptoms may be delayed

Skin: redness, burning sensation

Eyes: redness, pain

Ingestion: confusion, diarrhoea, headache, nausea, vomiting

ETHYLENE GLYCOL PHENYL ETHER  122-99-6

eyes; skin

Inhalation: sore throat

Skin: redness

Eyes: redness, pain

Ingestion: abdominal pain, sore throat

PROPYLENE GLYCOL MONOMETHYL ETHER     107-98-2

eyes; skin; resp tract; nose; throat; CNS

Inhalation: dizziness, drowsiness, headache, nausea

Skin: dry skin, redness

Eyes: lacrimation, redness

Ingestion: diarrhoea, drowsiness, headache, nausea, vomiting, incoordination or possible unconsciousness

Eyes; skin; resp sys; CNS Inh; ing; con

Irrit eyes, skin, nose, throat; head, nau, li-head, drow, inco; vomit, diarr

 

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Sunday, 07 August 2011 05:54

Glycol Ethers: Chemical Identification

Chemical Formula

Chemical

Synonyms
UN Code

CAS-Number

2425798

1,4-BUTANEDIOL DIGLYCIDYL ETHER

1,4-Bis(2,3-epoxypropoxy)butane;
1,4-Bis(glycidyloxy)butane;
1,4-Butane diglycidyl ether;
Butanediol diglycidyl ether;
Butane-1:4-diol diglycidyl ether;
2,2'-(1,4-Butanediylbis(oxymethylene))bisoxirane;
1,4-Diglycidloxybutane

2425-79-8

112367

DIETHYLENE GLYCOL DIETHYL ETHER

Bis(2-ethoxyethyl) ether;
Diethyl carbitol;
3,6,9-Trioxaundecane

112-36-7

4206615

DIETHYLENE GLYCOL DIGLYCIDYL ETHER

Ether, bis(2-(2,3-epoxypropoxy)ethyl);
Oxirane, 2,2'-(oxybis(2,1-ethanediyloxymethylene))bis-;
2,2'-(Oxybis(2,1-ethanediyloxymethylene))bisoxirane

4206-61-5

112345

DIETHYLENE GLYCOL MONOBUTYL ETHER

Butoxydiethylene glycol;
Butoxydiglycol;
2-(2-Butoxyethoxy)ethanol;
Butyl carbitol;
Glycol-n-butyl ether;
Diglycol monobutyl ether

112-34-5

124174

DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE

Acetic acid 2-(2-butoxyethoxy)ethyl ester;
2-(2-Butoxyethoxy)ethyl acetate;
Butyl carbitol acetate;
Diethylene glycol butyl ether acetate

124-17-4

111900

DIETHYLENE GLYCOL MONOETHYL ETHER

Carbitol cellosolve;
Ethyl diethylene glycol;
Ethanol, 2-(2-ethoxyethoxy)

111-90-0

111773

DIETHYLENE GLYCOL MONOMETHYL ETHER

Diethylene glycol monomethyl ether;
Dowanol DM;
Ethylene diglycol monomethyl ether;
Methoxydiglycol

111-77-3

110714

1,2-DIMETHOXYETHANE

Dimethoxyethane;
Dimethylcellosolve;
2,5-Dioxahexane;
Ethylene dimethyl ether;
Ethylene glycol dimethyl ether
UN2252

110-71-4

34590948

DIPROPYLENE GLYCOL METHYL ETHER

Arcosolv;
Dipropylene Dowanol DPM;
Dowanol-50B;
1-(2-Methoxyisopropoxy)-2-propanol

34590-94-8

1002671

2-ETHOXYETHYL 2-METHOXYETHYL ETHER

Diethylene glycol ethyl methyl ether

1002-67-1

110805

ETHYLENE GLYCOL ETHYL ETHER ACETATE

Cellosolve;
Dowanol EE;
2-Ethoxyethanol;
Ethyl cellosolve;
Glycol monoethyl ether;
Hydroxy ether
UN1171

110-80-5

629141

ETHYLENE GLYCOL DIETHYL ETHER

1,2-Diethoxyethane;
Diethyl cellosolve;
Ethylene glycol diethyl ether
UN1153

629-14-1

109864

ETHYLENE GLYCOL METHYL ETHER

Glycol monomethyl ether;
2-Methoxyethanol;
Methoxyhydroxyethane;
Methyl cellosolve
UN1188

109-86-4

111762

ETHYLENE GLYCOL MONOBUTYL ETHER

Butoxyethanol;
Butyl cellosolve;
2-Butoxyethanol;
Glycol butyl ether;
Glycol monobutyl ether;
Monobutyl glycol ether
UN2369

111-76-2

112072

ETHYLENE GLYCOL MONOBUTYL ETHYL ETHER ACETATE

112-07-2

111159

ETHYLENE GLYCOL MONOETHYL ETHER ACETATE

Cellosolve acetate;
Ethoxy acetate;
Ethoxyethyl acetate
UN1172

111-15-9

110496

ETHYLENE GLYCOL, MONOMETHYL ETHER ACETATE

Acetic acid 2-methoxyethyl ester;
Ethylene glycol methyl ether acetate;
Ethylene glycol monomethyl ether acetate;
Glycol ether EM acetate;
Glycol monomethyl ether acetate;
Mecsac;
2-Methoxyethanol, acetate;
2-Methoxyethyl acetate;
Methyl cellosolve acetate;
Methyl glycol acetate;
Methyl glycol monoacetate
UN1189

110-49-6

2807309

ETHYLENE GLYCOL MONOPROPYL ETHER

Ektasolve EP;
2-Propoxyethanol;
Propyl cellosolve

2807-30-9

122996

ETHYLENE GLYCOL PHENYL ETHER

Arosol;
Dowanol EP;
Dowanol EPH;
2-Phenoxyethanol;
Glycol monophenyl ether;
Phenyl cellosolve

122-99-6

107982

PROPYLENE GLYCOL MONOMETHYL ETHER

Glycol ether PM;
Methoxy ether of propylene glycol;
1-Methoxy-2-propanol;
Propasol solvent M;
Propylene glycol methyl ether;
Propylene glycol monomethyl ether
UN3092

107-98-2

 

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