WHO Headquarters:                                                 
150, cours Albert Thomas,                                        
F-69372 Lyon Cedex 08, France                                          
Tel.: +33-7 273 84 85                                                
Fax: +33-7 273 85 75                                                
Telex: 380023                                                           
Headquarters: 20 avenue Appia,                                           
1211 Geneva 27, Switzerland                                   
Tel.: +41-22-791 21 11                                                   
Fax: +41-22-791 07 46                                             
Telex: 845 415 416                                                   
Cable: UNISANTE GENEVE


IARC Headquarters:                                                 
150, cours Albert Thomas,                                        
F-69372 Lyon Cedex 08, France                                          
Tel.: +33-7 273 84 85                                                
Fax: +33-7 273 85 75                                                
Telex: 380023


UNEP Headquarters:                                                
P.O. Box 30552,                                                       
Nairobi, Kenya                                                                      
Tel.: 2-23 08 00                                                                     
Fax:2-22 68 31                                                                      
Telex: 22068 KNEPKE                                                        
Cable: UNITERRA NAIROBI


IAEA Headquarters                                                  
Vienna International Centre,                                    
Wagramerstrasse 5,                                                   
P.O. Box 100,                                                           
A-1400 Vienna, Austria                                                        
Tel.: +43-1-23 60                                                            
Fax: +43-1-23 45 64                                                 
Telex: 112645 ATOM A                                                       
Cable: INATOM VIENNA


UNDP Headquarters:
1 United Nations Plaza,
New York,
NY 10017,
United States
Tel.: +1-212-906 5000     
Fax: +1-212-906 5778


FAO Headquarters:
Viale delle Terme de Caracalla,
1-00100 Rome, Italy
Tel.: +39-6-522 51     
Fax: +39-6-522 53 152
Telex: 610181 FAO 1
Cable: FOODAGRI ROME


IMO Headquarters:
4 Albert Embankment,
London SE1 7SR,
United Kingdom
Tel.: +44-171-735 7611     
Fax: +44-171-587 3210
Telex: 23588


UNCTAD Headquarters:
Palais des Nations,
CH 1211
Geneva 10,
Switzerland
Tel.: +41-22-907 12 34     
Fax: +41-22-907 0 57
Cable: UNATIONS GENEVE

 

Back

 

Excerpted from Vogel 1994

Danish industrial relations provide an example of a country with a number of institutions that play a role in relation to health and safety. The main features are:

COLLECTIVE BARGAINING: Negotiation of agreements by which trade unions and employers fix wages, conditions of work, etc. Pertinent highlights are:

Shop stewards who are elected by workers under collective bargaining agreements; enjoy statutory protection against dismissal; serve as channel between workers and management on working conditions.

Collective Agreement on Cooperation and Cooperation Committees provides for information to be given to individuals and groups of workers in advance so they can make their views known before a decision is taken and for the establishment of cooperation committees.

Cooperation committees must be set up in all firms employing more than 35 workers (25 in the public service). Joint committees to promote cooperation in day-to-day operations; they must be consulted on the introduction of new technologies and the organization of production; some co-determination rights on working conditions, training and personal data.

National collective agreement on industrial disputes (of 1910) gives workers a right (rarely exercised) to stop work if considerations of “life, welfare or honour” make this absolutely necessary. Other collective agreements contain provisions on training and trade unions also provide it.

FRAMEWORK LAW: The Working Environment Act creates “the basis on which the undertakings themselves will be able to solve questions relating to safety and health under the guidance of the employers’ and workers’ organizations and under the guidance and supervision of the Labour Inspection Service” (Sec. 1(b)). The Act establishes a complete system from the plant to the national level to permit worker participation:

Safety representatives are elected representatives required in firms employing at least ten workers; they enjoy the same protection against dismissal and retaliation as shop stewards and are entitled to reimbursement of official expenses.

Safety groups: The safety representative and the department supervisor form the safety group. Its functions are to:

  • monitor working conditions
  • inspect equipment, tools, materials
  • report any risk which cannot be avoided immediately
  • halt production where necessary to avert an imminent serious danger
  • ensure that work is performed safely and proper instructions are given
  • investigate industrial accidents and occupational diseases
  • participate in prevention activities
  • cooperate with the occupational health service
  • act as link between workers and the safety committee.

 

Members of the safety group are entitled to training and to necessary information.

Safety Committees are required in firms employing at least 20 workers. In firms with more than two safety groups, the safety committees consist of workers elected from among safety representatives, two supervisor members and an employer’s representative.

The functions are:

  • planning, directing and coordinating health and safety activities
  • being consulted on these matters
  • cooperating with other companies engaged in work at the same workplace
  • cooperating with the company’s occupational health service
  • supervising the activity of safety groups
  • making recommendations on prevention of accidents and diseases.

 

WORKING ENVIRONMENT COUNCIL involves employers’ and workers’ organizations in the definition and application of preventive policy at the national level. Composition: 11 representatives of employee organizations representing manual and non-manual workers, one for supervisors, ten of employers’ organizations, plus an occupational medical practitioner, a technical expert and non-voting governmental representatives. Functions:

  • is consulted on drafting legislation and regulations
  • may on its own initiative take up a health and safety matter
  • submits annual recommendations on working environment policy
  • coordinates the activities of Trade Safety Councils
  • supervises the activity of the Working Environment Fund.

 

WORKING ENVIRONMENT FUND is managed by a tripartite board. The Fund has mainly information and training duties, but also finances research programmes.

TRADE SAFETY COUNCILS: Twelve Trade Safety Councils examine the problems of their trade or industry and advise undertakings. They are also consulted on draft legislation. Equal representation of employers’ and supervisors’ organizations on the one hand and workers’ organizations on the other hand.

GOVERNMENTAL AUTHORITIES: In addition, the Ministry of Labour, the Labour Inspection Service and within it, the Danish Institute of the Working Environment, provide various types of services and advice in the field of occupational safety and health. Collective industrial disputes are heard by the Labour Courts.


The agreement between Bethlehem Steel and the United Steelworkers of America is typical of company-wide agreements in large unionized manufacturing enterprises in the United States. Steel industry labour agreements have contained safety and health articles for more than 50 years. Many provisions negotiated in the past gave workers and the union rights that were later guaranteed by law. Despite this redundancy, the provisions still appear in the contract as a hedge against changes in the law, and to allow the union the option of taking violations to impartial arbitration rather than the courts.

The Bethlehem agreement runs from 1 August 1993 to 1 August 1999. It covers 17,000 workers in six plants. The full agreement is 275 pages long; 17 pages are devoted to safety and health.

Section 1 of the safety and health article pledges the company and the union to cooperate in the objective of eliminating accidents and health hazards. It obligates the company to provide safe and healthful workplaces, obey federal and state law, provide employees with the necessary protective equipment free of charge, provide chemical safety information to the union and inform workers of the hazards and controls for toxic substances. It grants the union’s central safety and health department the right to any information in the company’s possession that is “relevant and material” to an understanding of potential hazards. It requires the company to make air sampling tests and environmental investigations at the request of the union co-chairperson of the plant’s safety and health committee.

Section 2 sets up joint union-management safety and health committees at the plant and national levels, prescribes the rules under which they operate, mandates training for committee members, gives members of the committee access to all parts of the plant to facilitate the committee’s work and specifies the applicable rates of pay for committee members on committee business. The section also specifies how disputes over protective equipment are to be resolved, requires the company to notify the union of all potentially disabling accidents, sets up a system of joint accident investigation, requires the company to gather and supply to the union certain safety and health statistics, and establishes an extensive safety and health training programme for all employees.

Section 3 gives workers the right to remove themselves from work involving hazards beyond those “inherent in the operation” and provides an arbitration mechanism through which disputes over such work refusals can be resolved. Under this provision, a worker cannot be disciplined for acting in good faith and on the basis of objective evidence, even if a subsequent investigation shows that the hazard did not in fact exist.

Section 4 specifies that the committee’s role is advisory, and that committee members and officers of the union acting in their official capacity are not to be held liable for injuries or illnesses.

Section 5 states that alcoholism and drug abuse are treatable conditions, and sets up a programme of rehabilitation.

Section 6 establishes an extensive programme for controlling carbon monoxide, a serious hazard in primary steel production.

Section 7 provides workers with vouchers for the purchase of safety shoes.

Section 8 requires the company to keep individual medical records confidential except in certain limited circumstances. However, workers have access to their own medical records, and may release them to the union or to a personal physician. In addition, physicians for the company are required to notify workers of adverse medical findings.

Section 9 establishes a medical surveillance programme.

Section 10 establishes a programme for investigating and controlling the hazards of video display terminals.

Section 11 establishes full-time safety representatives in each plant, chosen by the union but paid by the company.

In addition, an appendix to the agreement commits the company and the union to review each plant’s safety programme for mobile equipment operating on rails. (Fixed rail equipment is the leading cause of death by traumatic injury in the American steel industry.)

 

Back

Wednesday, 26 October 2011 21:03

Case Study: World Trade Organization

The World Trade Organization (WTO), established in 1995 as the result of the Uruguay Round of multilateral trade negotiations, is the successor to the General Agreement on Tariffs and Trade (GATT), the international trade agreement dating from the late 1940s. The WTO is the legal and institutional foundation of the world’s multilateral trading system. It aims to promote open international trade, not only in goods (as in GATT), but also in services and intellectual property. The WTO also has an explicit goal of advancing development, especially of the least developed countries.

The WTO is designed to promote trade, and related issues such as occupational safety and health are addressed only insofar as they may interfere with free trade. Two Agreements are relevant. The Agreement on the Application of Sanitary and Phytosanitary Measures addresses food safety and animal and plant health regulations. It permits countries to promulgate such regulations, but requires that they be based on science, applied only to the extent necessary to protect human, animal, or plant life or health, and should not arbitrarily discriminate between member countries. While member countries are encouraged to base their regulations on international standards, they are permitted to set more stringent standards if there is scientific justification or if they have based their standards on an appropriate risk assessment. The Agreement on Technical Barriers to Trade reinforces these precepts. Its goal is to prevent technical regulations and standards from posing unnecessary obstacles to trade. To this end, there is a code of good practice for promulgating standards and a requirement that standards be applied equitably to domestic and imported products.

While the foregoing two Agreements pertain principally to environmental, food quality, and pharmaceutical regulations, they could conceivably be applied to occupational health and safety. The summary statement from the 1995 Marrakesh meeting of the WTO provided for the formation of a working party on International Labour Standards. However, the WTO has thus far avoided addressing occupational health and safety, and several member governments, especially those of developing countries, have held that worker health should remain a national prerogative, uncoupled from international trade considerations. Therefore, the WTO has to date played no role in advancing occupational health and safety.

Europe

Economic integration in Europe is distinguished by its early origins, dating to the Treaty of Rome in 1957, and by the prominence that social and political issues have assumed alongside economic considerations. In fact, integration in Europe extends well beyond lowering trade barriers; it also includes the free movement of workers (and soon of people in general), the promulgation of binding transnational laws and regulations, and the creation of a transnational bureaucracy with substantial financial backing. As a result, occupational health has received considerable attention.

The European Economic Community (EEC), or Common Market, was established by the Treaty of Rome in 1957. This Treaty began to lift trade barriers among member nations, and established the EEC’s organizational structure. The Commission of the European Communities became the EEC’s civil service and bureaucracy, with its work carried out by 23 Directorates General (including one, DG V, responsible for employment, industrial relations and social affairs). The Council of Ministers handles major policy-making, while the European Parliament has a co-decision-making role.

The Court of Justice adjudicates disputes that arise under treaties. The Advisory Committee on Safety, Hygiene and Health Protection at Work (ACSH), established by the Council in 1974 to advise the Commission, includes representatives of labour, management, and the governments from each member country, and is supported by staff from the Health and Safety Directorate of the DG V. The ACSH reviews legislative proposals relevant to occupational health, initiates activities on specific hazards, and coordinates joint efforts. The Economic and Social Committee has a consultative role.

In 1978 the Commission introduced the first Action Programme on Health and Safety, with considerable support from the ACSH. It focused on hazardous substances, prevention of machinery hazards, monitoring and inspections and the improvement of attitudes towards health and safety. Since then, successive action programmes have been directed at other occupational health concerns such as ergonomics, occupational health statistics, assistance for small enterprises and training. These have promoted occupational health solutions throughout the member nations, providing training, technical advice and written materials. For example, in 1982 the Commission convened an informal group of senior labour inspectors to encourage personnel and information exchanges among the 12 nations, comparison of member countries’ practices and improved practice. Such initiatives exemplify how the integration of national economies can have positive effects on the practice of occupational health and safety.

The Single European Act (SEA) of 1987 signalled a major step forward in European integration and in the development of the European Free Trade Area. A firm date was set for the establishment of a Single Market, 1992, and activity in a range of social issues, including occupational health, was stimulated. Unanimity among member nations was no longer needed to set policy; instead, a “qualified majority” could do so. Two of the Act’s articles are especially relevant to occupational health. Article 100(a) aims to harmonize product standards in the member countries, a process that has important safety implications. This Article specifies that standards should achieve a “high level of health protection”. Article 118(a) directly addresses occupational health and safety, holding that member countries “shall pay particular attention to encouraging improvements, especially in the working environments, as regards the health and safety of workers, and shall set as their objective the harmonization of conditions in this area while maintaining the improvements made”.

In 1989, two important events further solidified the role of occupational health in the process of European integration. The Social Charter was adopted by 11 of the then 12 Member States, including a clause that emphasized “the need for training, information, consultation and balanced participation of workers as regards the risks incurred and the steps taken to eliminate or reduce them”.

Also in 1989, the Framework Directive was adopted by the Council, the first major policy initiative under the SEA. It defined the EC (now the European Union (EU)) approach to worker health and safety, extending to public and private employees in all member countries. Employers were assigned a general “duty to ensure the safety and heath of workers in every aspect related to work”, and specific duties to:

  • evaluate workplace risks
  • integrate preventive measures into all aspects of production
  • inform workers and their representatives of risks and preventive measures taken
  • consult workers and their representatives in all health and safety matters
  • provide worker health and safety training
  • designate workers with specific health and safety responsibilities
  • provide appropriate health surveillance
  • protect sensitive risk groups
  • maintain injury and illness records.

 

 

The Framework Directive adopted a broad view of what workplace factors were relevant to occupational health, including design issues, monotonous work and piece-work. It called for active worker participation in health and safety programmes, including rights to advance consultation with employers on health and safety initiatives, paid time off to perform health and safety functions, meetings with government inspectors and refusal to work in case of “serious, imminent and unavoidable danger” (subject to national laws). A series of so-called daughter directives issued in the wake of the Framework Directive address the use of personal protective equipment, manual handling of loads, work with video display terminals and other issues.

Will the Framework Directive translate into effective national policy? Underlying this issue is the EU’s explicit commitment to the principle of subsidiarity, which holds that all policy should be implemented by member countries rather than by the EU, unless “by reason of the scale of effects of the proposed action” it is better carried out centrally. This will result in tension between the mandates of the central directives and the sovereign actions of the member countries.

Each member country is required to transpose the Framework Directive (like all directives) into national law, to implement policies accordingly and to enforce them in practice. This process leaves countries room for discretion and may allow some non-compliance. By all accounts the EU is not well equipped to monitor member country compliance with its occupational health and safety directives. Closer monitoring of each country’s practices, and the political will to use available remedies in cases of non-compliance (including appeal to the Court of Justice) will be necessary if the EU’s full potential in promoting occupational health is to be realized.

A related question concerns the fate of national policies that are more protective than those of the EU. Since Article 118(a) requires only a minimum common level of workplace protection, there may be a tendency towards downward harmonization in response to economic pressures.

In 1994 the Council, acting on a three-year-old proposal from the Commission, established the European Agency for Safety and Health at Work, sited in Bilbao, Spain. The Agency’s aim is to “provide the Community bodies, the Member States and those involved in the field with the technical, scientific and economic information of use in the field of safety and health at work”. It will focus on technical and scientific consultation to the Commission, information exchange, training, consistent data collection and promoting research.

In 1995 the Commission published its action programme for the period 1996-2000. One important component was continued attention to legislative initiatives—ensuring that Community directives be accurately transported into national law, and promulgating new directives on physical agents, chemical agents, transport, and work equipment. A longstanding Committee of Senior Labour Inspectors was formalized to harmonize methods of workplace inspection and to monitor the implementation of national labour laws. However, there was also considerable emphasis on non-legislative measures, principally information and persuasion. A new initiative, SAFE (Safety Actions for Europe) was announced, to address health and safety problems in small and medium-sized firms. The approach planned was to identify successful initiatives in model firms and to use these as examples for other firms.

In summary, European economic integration and free trade have evolved as part of a broader programme of social and political integration. This process has included serious discussions of social issues, including occupational health and safety. A complicated bureaucracy has several components that bear on workplace health and safety. The reference point for the EU is community law rather than national law, in contrast to every other free-trade agreement. This arrangement is the world’s most advanced example of promoting occupational health and safety as a component of free trade. It will affect more than the EU countries; occupational health and safety considerations will be part of every association, partnership and cooperation agreement between the EU and the countries of Central and Eastern Europe, extending this progressive tradition. The problems that persist—reconciling national sovereignty with coordinated progress, monitoring compliance with Community directives, reconciling differences between more and less progressive countries and sharing scarce technical expertise and resources—will continue to pose challenges to European integration in coming years.

North America

The three nations of North America have been major trading partners for many decades. The first step towards a regional trading agreement was the US-Canada Free Trade Agreement of 1987, which lowered tariffs and other trading restrictions between those two countries. In the early 1990s, in preparation for a continent-wide trade agreement, US and Mexican labour authorities began several cooperative efforts, such as the training of labour inspectors. In 1993 Mexico, Canada and the US ratified the North American Free Trade Agreement (NAFTA), which took effect in 1994 for full implementation over about a decade. NAFTA was designed to abolish most trade restrictions among the three countries.

The process that led to NAFTA differed from the European experience in several ways. NAFTA had a shorter history and was negotiated rapidly. There was no tradition of incorporating social issues into the process. Environmental and labour concerns were ultimately codified in a pair of side agreements that were adopted alongside the NAFTA proper. Environmental groups had been active in the debate leading to NAFTA and won a number of environmental safeguards in the environmental side agreement, but labour groups took a different approach. Unions and their allies, especially in the US and Canada, vigorously opposed NAFTA and campaigned more to block the treaty altogether than for specific labour-friendly provisions. Moreover, there was reluctance among the three governments to relinquish any sovereignty regarding their respective labour laws. As a result NAFTA’s labour side agreement is relatively narrow compared to the environmental side agreement or to the European experience.

The labour side agreement, in an Annex, defines “guiding principles that the Parties are committed to promote, subject to each Party’s domestic law, but do not establish common minimum standards”. These principles include prevention of occupational injuries and illnesses, compensation in cases of occupational injuries and illnesses, protection of migrant workers and children, more traditional labour rights such as freedom of association, the rights to organize, bargain collectively and strike, and prohibition of forced labour. The stated objectives of the side agreement are to improve working conditions, encourage information exchange, data collection and collaborative studies and promote compliance with each country’s labour laws.

The early Articles of the labour side agreement urge each country to publicize its own labour laws internally and to enforce them fairly, equitably and transparently. Next, a Commission for Labour Cooperation is formed. It consists of a Council of the three labour ministers or their designees, which is responsible for policy-making and promoting cooperative activities, and a Secretariat headed by an Executive Director that will prepare background reports and studies and otherwise support the Council. Moreover, each nation is directed to establish a National Administrative Office which will serve as its liaison to the Commission and assist the Commission in its work. Several general procedures are set forth, such as a direction to seek expertise through cooperation with the ILO. However, the agreement defines few specific procedures in support of its objectives.

Much of the concern that drove the side agreement was that a member nation, usually presumed to be Mexico, might, through lax labour practices, gain an unfair trade advantage; this would expose Mexican workers to low wages and unwholesome working conditions and would transfer jobs away from US and Canadian workers. Hence, a large part of the side agreement is dedicated to procedures for handling complaints and grievances. If such a concern arises, the first step is supposed to be consultation between the governments involved at the ministerial level. Next, the Commission may form an Expert Committee of Evaluation (ECE), usually three qualified people “chosen strictly on the basis of objectivity, reliability and sound judgement”, to consider the matter, provided that the matter is trade related and is “covered by mutually recognized labour laws”. The ECE may rely on information provided by the Commission, each member nation, organizations or individuals with relevant expertise, or the public. The ECE report is provided to each member nation.

If the ECE concludes that one country may have failed to enforce its labour standards then a formal dispute resolution process may be triggered. Significantly, this process is available only if the dispute pertains to occupational health and safety, child labour or minimum wages. First, the involved nations attempt to negotiate a settlement. If they cannot agree, an arbitral panel is convened from a roster of experts established and maintained by the Council. The panel presents its findings of fact, its conclusion regarding whether a nation has failed to enforce its standards, and its recommendations for corrective action. If the involved nation does not comply with its recommendations, the panel may be reconvened and may impose fines. If a nation refuses to pay its fine, the ultimate penalty is a suspension of NAFTA benefits, usually through tariff imposition in the sector where the violation occurred, in order to recover the amount of the fine.

Overall, the labour side agreement, as a framework for occupational health and safety under NAFTA, is less extensive than corresponding European arrangements. The focus in NAFTA is on dispute resolution rather than on joint research, information sharing, training, technology development and related initiatives. The dispute resolution process, in the view of labour advocates, is cumbersome, time-consuming and relatively toothless. More importantly, the side agreement expresses no shared commitment to fundamental labour rights. It is assiduous in respecting each nation’s labour laws, and has no provisions for upgrading or harmonizing those that are deficient. Its scope is narrow, and although there has been little experience to date, it is likely that the broad European approach to occupational health, extending to such concerns as shiftwork and stress, will not be replicated.

Asia and Latin America

Although Asia is the world’s fastest growing economic region, free-trade negotiations in the region have not advanced significantly. Neither the ASEAN nor the APEC has addressed occupational health and safety in its trade negotiations. Similarly, the growing trading pacts of Latin America, such as MERCOSUR and the Andean Pact, have included no occupational health and safety initiatives.

OBJECTIVE

These canons provide standards of ethical conduct for industrial hygienists as they practice their profession and exercise their primary mission, to protect the health and well-being of working people and the public from chemical, microbiological and physical health hazards present at, or emanating from, the workplace.

CANONS OF ETHICAL CONDUCT

Industrial Hygienists shall:

  • Practice their profession following recognized scientific principles with the realization that the lives, health and well-being of people may depend upon their professional judgment and that they are obligated to protect the health and well-being of people.
  • Counsel affected parties factually regarding potential health risks and precautions necessary to avoid adverse health effects.
  • Keep confidential personal and business information obtained during the exercise of industrial hygiene activities, except when required by law or overriding health and safety considerations.
  • Avoid circumstances where a compromise of professional judgment or conflict of interest may arise.
  • Perform services only in the areas of their competence.
  • Act responsibly to uphold the integrity of the profession.

 

CANON 1

Practice their profession following recognized scientific principles with the realization that the lives, health and well-being of people may depend upon their professional judgement and that they are obligated to protect the health and well-being of people.

INTERPRETIVE GUIDELINES

  • Industrial Hygienists should base their professional opinions, judgments, interpretations of findings and recommendations upon recognized scientific principles and practices which preserve and protect the health and well-being of people.
  • Industrial Hygienists shall not distort, alter or hide facts in rendering professional opinions or recommendations.
  • Industrial Hygienists shall not knowingly make statements that misrepresent or omit facts.

 

CANON 2

Counsel affected parties factually regarding potential health risks and precautions necessary to avoid adverse health effects.

INTERPRETIVE GUIDELINES

  • Industrial Hygienists should obtain information regarding potential health risks from reliable sources.
  • Industrial Hygienists should review the pertinent, readily available information to factually inform the affected parties.
  • Industrial Hygienists should initiate appropriate measures to see that the health risks are effectively communicated to the affected parties.
  • Parties may include management, clients, employees, contractor employees, or others dependent on circumstances at the time.

 

CANON 3

Keep confidential personal and business information obtained during the exercise of industrial hygiene activities, except when required by law or overriding health and safety considerations.

INTERPRETIVE GUIDELINES

  • Industrial Hygienists should report and communicate information which is necessary to protect the health and safety of workers and the community.
  • If their professional judgment is overruled under circumstances where the health and lives of people are endangered, industrial hygienists shall notify their employer or client or other such authority, as may be appropriate.
  • Industrial Hygienists should release confidential personal or business information only with the information owner’s express authorization except when there is a duty to disclose information as required by law or regulation.

 

CANON 4

Avoid circumstance where a compromise of professional judgment or conflict of interest may arise.

INTERPRETIVE GUIDELINES

  • Industrial Hygienists should promptly disclose known or potential conflicts of interest to parties that may be affected.
  • Industrial Hygienists shall not solicit or accept financial or other valuable consideration from any party, directly or indirectly, which is intended to influence professional judgment.
  • Industrial Hygienists shall not offer any substantial gift, or other valuable consideration, in order to secure work.
  • Industrial Hygienists should advise their clients or employer when they initially believe a project to improve industrial hygiene conditions will not be successful.
  • Industrial Hygienists should not accept work that negatively impacts the ability to fulfill existing commitments.
  • In the event that this Code of Ethics appears to conflict with another professional code to which industrial hygienists are bound, they will resolve the conflict in the manner that protects the health of affected parties.


CANON 5

Perform services only in the areas of their competence.

INTERPRETIVE GUIDELINES

  • Industrial Hygienists should undertake to perform services only when qualified by education, training or experience in the specific technical fields involved, unless sufficient assistance is provided by qualified associates, consultants or employees.
  • Industrial Hygienists shall obtain appropriate certifications, registrations and/or licenses as required by federal, state and/or local regulatory agencies prior to providing industrial hygiene services, where such credentials are required.
  • Industrial Hygienists shall affix or authorize the use of their seal, stamp or signature only when the document is prepared by the Industrial Hygienist or someone under their direction and control.

 

CANON 6

Act responsibly to uphold the integrity of the profession.

INTERPRETIVE GUIDELINES

  • Industrial Hygienists shall avoid conduct or practice which is likely to discredit the profession or deceive the public.
  • Industrial Hygienists shall not permit the use of their name or firm name by any person or firm which they have reason to believe is engaging in fraudulent or dishonest industrial hygiene practices.
  • Industrial Hygienists shall not use statements in advertising their expertise or services containing a material misrepresentation of fact or omitting a material fact necessary to keep statements from being misleading.
  • Industrial Hygienists shall not knowingly permit their employees, their employers or others to misrepresent the individuals’ professional background, expertise or services which are misrepresentations of fact.
  • Industrial Hygienists shall not misrepresent their professional education, experience or credentials.

 

Provided by the American Board of Industrial Hygiene (1995).


Back

Saturday, 22 October 2011 18:57

Case Study: Best Practices Examples

SABRE Employment (UK)

Mission Statement:

To communicate overall objectives/business goals which not only embrace the provision of quality service to applicants, but clearly reflect the desire to provide an efficient recruitment service to employers and which assist employers to improve their capacity to employ people with disabilities. Emphasis should be placed on the primary aim to achieve customer satisfaction. “All of Sabre’s activities begin with our customers. Our goals are to provide recruitment solutions through effective job matching, reliable training and support and to offer expertise in the recruitment and employment of people with disabilities.”

A job fair was recently held to give people a chance to meet employers and learn about different jobs. McDonald’s Restaurants Ltd. ran a workshop on interview skills and also sponsored the job fair event along with Shell and Pizza Hut. There were employer displays which provided an opportunity for employers and prospective employees with learning difficulties to meet in an informal way.

The Coverdale Bursary Programme (UK)

For five years, Coverdale, a small (70 people) management consultancy has offered bursaries to the value of £10,000 per person to disabled individuals seeking high quality management training. These individuals then go into companies like Barclays Bank, the Post Office and Midland Bank for additional training, in a process which promotes long-term attitude change across participating companies. This programme is now being expanded. It has been adapted by The Canadian Council for Rehabilitation and Work.

Brook Street and FYD (UK)

A commercial recruitment agency, Brook Street, and a charity for young deaf people, Friends for the Young Deaf (FYD), have worked in partnership for some years. Brook Street offers work experience and assessment to the young deaf graduates completing the FYD leadership training programme; Brook Street then places appropriate candidates into jobs, charging the same commercial fee they would charge for any candidate.

Employers’ Forum on Disability (UK)

Companies involved in the Employers’ Forum on Disability, an employer-funded association that promotes the integration of disabled persons in the labour market and provides advisory services for interested enterprises, helped disabled entrepreneur Stephen Duckworth to establish his business, Disability Matters, which now offers high quality consultancy and awareness-raising on disability to companies across the UK. Its philosophy encompasses the following:

  • to understand and define the business case for employing disabled people
  • an authoritative employers’ voice on disability
  • employment- and training-related services which are more market led
  • to develop new ways to attract qualified disabled applicants and to retain disabled employees
  • The key to influencing employers and mobilizing their involvement is to network in a way that:
  • promotes the business case through business-to-business communication
  • promotes personal contact between employers and disabled individuals
  • promotes employer ownership of the issue and an awareness on the part of rehabilitation providers that the employer should be valued as stakeholder, customer and potential partner
  • positions disability as part of the wider debate regarding economic and social regeneration, long-term unemployment, poverty and micro and macroeconomic policies

 

Other examples in the UK: The Employer Forum on Disabilities

Leading UK companies drafted a highly influential policy framework called the “Employers Agenda on Disability, a Ten Point Plan”. This was launched by the Prime Minister and is now publicly supported by more than 100 major firms. It has proven a powerful force for change because it was drafted by the employers themselves in consultation with disability experts. It is now a key tool in helping employers to comply with discrimination legislation.

Supporters of the Agenda are publicly committed to structuring their corporate policy on disability using a 10-point framework addressing the following issues: Equal Opportunities Policy and Procedures Statement; Staff Training and Disability Awareness; The Working Environment; Recruitment; Career Development; Retention, Retraining and Redeployment; Training and Work Experience; People with Disabilities in the Wider Community; Involvement of Disabled People; Monitoring Performance.

The Action File on Disability, a unique manual which provides practical information on how to implement the Agenda, has been produced by the Employers’ Forum on Disability.

Graduate Recruitment:

More than 20 companies are involved in a consortium working with “Workable”, which brokers work-experience opportunities to disabled students in a planned and structured manner.

Twenty-five companies jointly fund an initiative making annual Career Fairs for students accessible for disabled students. The Career Fairs are now wheelchair accessible, and interpreters for the deaf are available, as well as large-print brochures and other support. Employers had experienced such difficulty attracting disabled graduates to apply for jobs using traditional intermediaries that they are now pioneering recruitment methods which speak directly to the disabled students.

HIRED (US)

The project HIRED in San Francisco embodies this new employer orientation. The acronym stands for Helping Industry Recruit Employees with Disabilities. Their literature highlights the services they offer employers:

“Project HIRED is a private, not for profit organization serving the San Francisco Bay area. Our purpose is to assist individuals with disabilities to secure jobs appropriate to their qualifications and career goals. Our services to employers include:

  • free referrals, pre-screened, qualified candidates matched to a company’s job openings
  • quality temporary employment services at competitive rates
  • customized, on site seminars on the technical, legal and interpersonal aspects of disability in the workplace, and
  • consultation on all topics related to disabilities in the workplace.

 

In addition to less formal corporate partnerships, Project HIRED has a corporate membership programme involving approximately 50 Bay Area companies. As corporate members, these companies are entitled to free consulting and a discount on seminars. We are currently exploring additional services, such as library of video resources, to further assist corporate members successfully incorporate people with disabilities in their workforce.”

ASPHI (Italy)

The origins of ASPHI (Associazione per lo Sviluppo di Progetti Informatici per gli Handicappati) go back to the late 1970s when IBM Italy organized courses in computer programming for the visually impaired. A number of companies which had subsequently employed the trainees, together with specialist partner agencies from the non-profit sector, created ASPHI for the physically disabled and the hearing and mentally impaired. The Association involves more than 40 companies which provide financial support, staff and volunteer helpers, advice as well as employment opportunities for ASPHI’s graduates. ASPHI’s objective is to harness information technologies for the social and vocational integration of disadvantaged groups. Its activities include: job training, research and development of new products (mainly software) which facilitate alternative methods of communication, personal autonomy and rehabilitation, and community education, thus breaking down prejudices and discrimination against disabled people. Each year, some 60 young people are qualified by ASPHI. With about 85% of its graduates finding a permanent job, ASPHI’s success has brought it national and international recognition.

Swedish Employers’ Federation Initiative

The Swedish Employers’ Federation Initiative, “Persons with Disabilities in Companies”, positions disability firmly in the labour market debate in the country and conveys the message that disability is an issue of importance to the Swedish Employers Confederation and its members. The Federation states: “The path to employment for persons with disabilities must be made smoother. Requirements for this include:

  • clear signals to employers concerning responsibility and costs
  • financial compensation for extra costs, if any, incurred by employers who appoint persons with disabilities
  • more knowledge of disabilities and the scope of persons with disabilities for changing attitudes and values
  • improved cooperation between companies, authorities and individuals to create a dynamic and flexible labour market.”

 

Back

Chemical Name
CAS-Number

Colour/Form

Boiling Point (°C)

Melting Point (°C)

Molecular Weight

Solubility in Water

Relative Density (water=1)

Relative Vapour Density (air=1)

Vapour Pressure/ (Kpa)

Inflam.
Limits

Flash Point (ºC)

Auto Ignition Point (ºC)

1-AMINO-2-METHYL-­5-NITROBENZENE
99-55-8

yellow monoclinic prisms from alcohol

105.5

152.2

sl sol

1.3x
10- 5 mm Hg

4-AMINO-2-NITRO­PHENOL
119-34-6

dark red plates or needles from water & alcohol

131

154.1

sol

1-CHLORO-2,4-DINI­TROBENZENE
97-00-7

yellow crystals

315

53

202.6

insol

1.7

6.98

2.0 ll
22.0 ul

1-CHLORO-3-NITRO­BENZENE
88-73-3

yellow crystals; monoclinic needles

245-246

32-33

157.56

insol

1.305

261

2-CHLORO-3-NITRO­BENZENE
121-73-3

pale-yellow orthorhombic prisms from alcohol

236

46

157.6

insol

1.534

1-CHLORO-4-NITRO­BENZENE
100-00-5

monoclinic prisms; yellow crystals

242

83.5

157.6

insol

1.3

5.44

@ 30 ºC

127 cc

510

2,4-DICHLORO-1-NI­TROBENZENE
611-06-3

258.5

34

192.00

insol

@ 80 ºC

1,2-DICHLORO-4-NI­TROBENZENE
99-54-7

needles from alcohol & carbon tetrachloride; liquid; solid

255.5

43

192.00

insol

@ 75 ºC/4 ºC

6.63

0.014 mm Hg

3,5-DINITRO-p-TOL­UIDINE
19406-51-0

171

197.14

2,3-DINITROTOLUENE
602-01-7

yellow crystals

250-300

63

182.1

insol

1.3

6.28

2,6-DINITROTOLUENE
606-20-2

rhombic needles from alcohol; yellow to red solid

285

66

182.1

@ 111 ºC

6.28

5.67x
10- 4 mm Hg

207 cc

3,4-DINITROTOLUENE
610-39-9

crystals or needles

250-300

58

182.1

insol

1.26

6.28

>110

DINITROBENZENE
25154-54-5

pale yellow solid; white crystalline solid

300

75-85

168

insol

1.6

5.8

<0.1

150

1,3-DINITROBENZENE
99-65-0

yellowish crystals; rhombohedral plates from alcohol; pale yellow solid

300-303

90

168.1

sl sol

@ 18 ºC/4 ºC

5.8

<0.1

149

o-DINITROBENZENE
528-29-0

colourless or yellow crystals, needles or plates; needles from benzene, plates; white crystals;pale yellow solid

319

118

168.1

insol

1.3119  120

5.79

<0.1

150 cc

p-DINITROBENZENE
100-25-4

white crystals; needles from alc; colourless to yellow monoclinic needles; pale yellow solid; yellow crystals

299

174

168.1

insol

@ 18 ºC/4 ºC

5.8

<0.1

150

3,5-DINITROBENZOYL CHLORIDE
99-33-2

196

74

230.56

1,5-DINITRONAPH­TALENE
605-71-0

219

218.16

insol

2,3-DINITROPHENOL
66-56-8

144.5

184.10

sl sol

1.681

2,4-DINITROPHENOL
51-28-5

yellowish to yellow orthorhombic crystals

112-114

184.1

sl sol

@ 24 ºC

6.35

@ 25 ºC

DINITROTOLUENE
25321-14-6

oily liquid

250-300

54-93

182.14

insol

1.3

6.28

0.13

207 cc

2,4-DINITROTOLUENE
121-14-2

crystals or oily liquid

300

71

182.1

insol

@ 71 ºC

6.27

@ 103 ºC

207 oc

2,5-DINITROTOLU­ENE
619-15-8

52.5

182.13

@ 111

1-FLUORO-2,4-DINI­TROBENZENE
70-34-8

pale yellow crystals from alcohol

296

25.8

186.10

@ 84 ºC

2-METHYL-1-NITRO­ANTHRAQUINONE
129-15-7

pale-yellow needles

270.5

267.2

insol

N-METHYL-N-NITRO­SOANILINE
614-00-6

225

14.7

136.15

insol

1.1240

5-NITROACENAPH­THENE
602-87-9

103.5

199.2

sol

NITROBENZENE
98-95-3

greenish-yellow crystals or yellow, oily liquid

210.8

5.7

123.11

sl sol

1.2037

4.3

20 Pa

1.8 ll
40 ul

88 cc

480

4-NITRODIPHENYL
92-93-3

yellow needles; white needles

340

114

199.2

insol

NITROFEN
1836-75-5

white solid; crystals; crystalline solid; yellow crystalline solid; free-flowing solid, dark brown color

@ 0.25 mm Hg

70-71

284.10

insol

@ 90 ºC

@ 40 ºC

5-NITRO-o-ANISIDINE
99-59-2

orange-red needles from alc, ether, water

118

168.2

sol

@ 156 ºC

@ 25 ºC

1-NITRONAPHTHALENE
86-57-7

yellow crystals

304

61.5

173.2

insol

1.332

@ 25 ºC

164 cc

2-NITRONAPHTHALENE
581-89-5

312.5

79

173.16

insol

o-NITROPHENOL
88-75-5

light yellow needles or prisms; monoclinic

216

44.8

139.1

sl sol

@ 14 ºC

@ 49.3 ºC

m-NITROPHENOL
554-84-7

monoclinic prisms from ether & dilute hydrochloric acid; colourless to yellow monoclinic form

@ 70 mm Hg

97

139.1

sl sol

@ 100 ºC/4 ºC

0.75 torr

p-NITROPHENOL
100-02-7

colourless to slightly yellow crystals;yellow monoclinic prisms from toluene; yellow to brown solid

279

113.8

139.1

sl sol

1.270

4.8

0.0032 Pa

169

4-NITROPHENYLBEN­ZANAMINE
836-30-6

yellow needles or tablets from carbon tetrachloride

@ 30 mm Hg

133.5

214.23

insol

7.4

2-NITRO-p-PHENYL­ENEDIAMINE
5307-14-2

almost black needles with dark-green luster

137

153.1

sol

p-NITROSODIPHEN­YLAMINE
156-10-5

green plates with bluish luster (from benzene) or steel-blue prisms or plates (from ether water); yellow liquid plates; greenish crystals

143

198.2

sl sol

m-NITROTOLUENE
99-08-1

yellow liquid

232

15.5

137.1

insol

1.1581

4.73

@ 25 ºC

106

o-NITROTOLUENE
88-72-2

yellowish liquid

222

-10

137.13

insol

1.1629

4.73

@ 50 ºC

2.2 ll
? ul

106 cc

p-NITROTOLUENE
99-99-0

yellowish crystals; colourless rhombic needles; orthorhombic crystals from alcohol & ether

238.3

53-54

137.1

insol

@ 75 /4 ºC

4.72

@ 65 ºC

106

PICRIC ACID
88-89-1

yellow crystals

300

122.5

229.1

sl sol

1.763

7.90

< 1 torr

150

300

TETRYL
479-45-8

colourless to yellow, solid; monoclinic crystals; yellow prisms from alcohol

187

131.5

287.15

insol

1.57

<0.1 Pa

187

2,4,7-TRINITRO­FLUOREN-9-ONE
129-79-3

pale yellow needles from acetic acid or benzene

176

315.19

sl sol

2,4,6-TRINITROTOLUENE
118-96-7

monoclinic rhombohedra; commercial crystals (needles) are yellow; colourless or light yellow solid in form of crystals, flakes, pellets, cast blocks & cast slabs; crushed flake

240

80.1

227.13

insol

1.654

7.85

<0.1 Pa

 

Back

Chemical Name
CAS-Number

Physical

Chemical

UN Class or Division /  Subsidiary Risks

1-AMINO-2-METHYL-5-NITROBENZENE
99-55-8

6.1

1-CHLORO-2,4-DINITROBENZENE
97-00-7

Heating may cause violent combustion or explosion at about 149 °C • May explode on heating under confinement or by shock • The substance decomposes on heating producing toxic gases (oxides of nitrogen, chlorine, hydrogen chloride, phosgene) • The substance is a strong oxidant and reacts with combustible and reducing materials • The substance is a strong reducing agent and reacts with oxidants • Reacts with strong oxidants and strong bases

6.1

1-CHLORO-2-NITROBENZENE
88-73-3

Dust explosion possible if in powder or granular form, mixed with air

The substance decomposes on heating or on burning producing toxic and corrosive fumes (nitrogen oxides, chlorine, hydrogen chloride, phosgene) • Reacts violently with reducing materials, causing fire and explosion hazard

6.1

1-CHLORO-3-NITROBENZENE
121-73-3

6.1

1-CHLORO-4-NITROBENZENE
100-00-5

The substance decomposes on heating producing toxic gases (nitrogen oxides, hydrochloric acid, phosgene and chlorine) • The substance is a strong oxidant and reacts violently with combustible and reducing materials • Reacts with many substances causing fire and explosion hazard

2,3-DINITROTOLUENE
602-01-7

Dust explosion possible if in powder or granular form, mixed with air

May explode on heating • The substance decomposes on heating producing carbon monoxide and oxides of nitrogen • Reacts with strong bases, oxidants, and reducing agents

6.1

2,6-DINITROTOLUENE
606-20-2

Dust explosion possible if in powder or granular form, mixed with air

May explode on heating • The substance decomposes on heating producing carbon monoxide and oxides of nitrogen • Reacts with strong bases, oxidants, and reducing agents

6.1

3,4-DINITROTOLUENE
610-39-9

Dust explosion possible if in powder or granular form, mixed with air

May explode on heating • The substance decomposes on heating producing carbon monoxide and oxides of nitrogen • Reacts with strong bases, oxidants, and reducing agents

6.1

DINITROBENZENE
25154-54-5

Dust explosion possible if in powder or granular form, mixed with air

May explode on heating under confinement • On combustion, forms toxic gases and fumes • Reacts violently with strong oxidants, strong bases, and reducing agents, causing fire and explosion hazard • Mixtures with nitric acid are highly explosive!

6.1

1,3-DINITROBENZENE
99-65-0

Dust explosion possible if in powder or granular form, mixed with air

May explode on heating under confinement • On combustion, forms toxic gases and fumes • Reacts violently with strong oxidants, strong bases, and reducing metals (tin and zinc), causing fire and explosion hazard • Mixtures with nitric acid are highly explosive!

6.1

o-DINITROBENZENE
528-29-0

Dust explosion possible if in powder or granular form, mixed with air

May explode on heating under confinement • On combustion, forms toxic gases and fumes • Reacts violently with strong oxidants, strong bases, and reducing metals, eg, zinc and tin, fire and explosion hazard • Mixtures with nitric acid are highly explosive!

6.1

p-DINITROBENZENE
100-25-4

Dust explosion possible if in powder or granular form, mixed with air

May explode on heating under confinement • On combustion, forms toxic gases and fumes • Reacts violently with strong oxidants, strong bases, and metals eg, tin and zinc, causing fire and explosion hazard • Mixtures with nitric acid are highly explosive!

6.1

2,4-DINITROPHENOL
51-28-5

Dust explosion possible if in powder or granular form, mixed with air

May explosively decompose on shock, friction, or concussion • May explode on heating

DINITROTOLUENE
25321-14-6

The vapour is heavier than air • Dust explosion possible if in powder or granular form, mixed with air

The substance can form explosive peroxides • May explode on heating or exposure to flames • The substance decomposes on heating producing toxic gases and fumes (carbon monoxide and oxides of nitrogen) • Reacts violently with strong oxidants causing fire and explosion hazard • Reacts with strong bases and metals such as tin and zinc and may cause evolution of heat and increase in pressure • Attacks some forms of plastics, rubber, and coatings

6.1

2,4-DINITROTOLUENE
121-14-2

Dust explosion possible if in powder or granular form, mixed with air

May explode on heating • The substance decomposes on heating producing carbon monoxide and oxides of nitrogen • Reacts with strong bases, oxidants, and reducing agents

6.1

5-NITRO-o-ANISIDINE
99-59-2

6.1

NITROBENZENE
98-95-3

On combustion, forms corrosive fumes including nitrogen oxides • Reacts violently with strong oxidants and reducing agents, causing fire and explosion hazard • Attacks many plastics • Forms explosive (thermally unstable) substances or mixtures with many organic and inorganic compounds like oxidants, aluminium chloride with phenol, potassium hydroxide anhydrous or with small amounts of methanol, aniline with glycerol, phosphoruspentachloride, nitric acid, sulphuric acid, potassium

6.1

4-NITRODIPHENYLAMINE
836-30-6

The substance decomposes on heating or on burning producing toxic fumes (nitrogen oxides) • Reacts with strong oxidantsIncompatibility: strong oxidizing agents and strong bases

1-NITRONAPHTHALENE
86-57-7

4.1

o-NITROPHENOL
88-75-5

6.1

m-NITROPHENOL
554-84-7

6.1

p-NITROPHENOL
100-02-7

Dust explosion possible if in powder or granular form, mixed with air

May explode on heating • The substance decomposes on heating or on burning producing toxic fumes including nitrogen oxides, causing fire and explosion hazard • The substance is a strong oxidant and reacts violently with combustible and reducing materials • Mixtures with potassium hydroxide are explosive

6.1

o-NITROTOLUENE
88-72-2

The substance decomposes on contact with strong oxidants, sulfuric acid, reducing agents, acids or bases producing toxic fumes, causing fire and explosion hazard • Attacks some forms of plastics, rubber, and coatings

6.1

m-NITROTOLUENE
99-08-1

6.1

p-NITROTOLUENE
99-99-0

The substance decomposes on heating producing toxic fumes (nitrogen oxides) • Reacts violently with strong oxidizers or sulfuric acid causing fire and explosion hazard • Attacks some forms of plastics, rubber and coatings

6.1

PICRIC ACID
88-89-1

May explosively decompose on shock, friction, or concussion • May explode on heating • Shock-sensitive compounds are formed with metals, particularly copper, lead, mercury and zinc • On combustion, forms toxic carbon and nitrogen oxides • Reacts vigorously with oxidants and reducing materials

1.1D

TETRYL
479-45-8

Dust explosion possible if in powder or granular form, mixed with air

May explosively decompose on shock, friction, or concussion • The substance decomposes explosively on heating to 187 °C • Contact of tetryl with some oxidizable materials may cause fire and explosions • Detonates spontaneously on contact with trioxygendifluoride • T gases and vapours (such as nitrogen oxides) may be released on burning/exploding

1.1D

2,4,6-TRINITROTOLUENE
118-96-7

May explosively decompose on shock, friction, or concussion • Upon heating, toxic fumes are formed • Reacts violently with reducing agents causing fire and explosion hazard • Reacts with heavy metals • Explodes on heating to 240 °C

1.1D

For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance

 

Back

Thursday, 18 August 2011 04:59

Nitrocompounds, Aromatic: Health Hazards

Chemical Name

CAS-Number

ICSC Short-Term Exposure

ICSC Long-Term Exposure

ICSC Routes of Exposure and Symptoms

US NIOSH Target Organs & Routes of Entry

US NIOSH Symptoms

1-CHLORO-2,4-DINITROBEN­ZENE    97-00-7

eyes; skin; resp tract

skin; eyes

Inhalation: blue lips or finger nails, blue skin, dizziness, headache, laboured breathing, nausea, vomiting, disturbed vision 

Skin: may be absorbed, redness, pain  

Eyes: redness, pain  

Ingestion: abdominal pain, blue skin, dizziness, headache, laboured breathing, nausea, vomiting

1-CHLORO-2-NITROBENZENE 88-73-3

eyes; skin; resp tract; blood

blood; liver; kidneys; spleen

Inhalation: blue lips or finger nails, blue skin, dizziness, headache, nausea, shortness of breath

Skin: may be absorbed, redness

Eyes: redness, pain

1-CHLORO-4-NITROBENZENE 100-00-5

blood

skin; blood

Inhalation: headache, faintness, vertigo, weakness    

Skin: may be absorbed

Blood; liver; kidneys; CVS; spleen; bone marrow; repro sys (in animals: vascular & liver tumors) Inh; abs; ing; con

Anoxia; unpleasant taste; anemia; methemo; in animals: hema, hemog; spleen, kidney, bone marrow changes; repro effects; (carc)

1,2-DICHLORO-3-NITROBEN­ZENE    3209-22-1

blood

skin; liver; kidneys

Inhalation: blue lips or finger nails  

Skin: may be absorbed, redness, blue lips, blue fingernails

Ingestion: blue lips or fingernails, blue skin, confusion, headache, vomiting, weakness

1,2-DICHLORO-4-NITROBEN­ZENE    99-54-7

eyes; skin; resp tract; lungs

skin; kidneys; liver

Inhalation: blue lips or finger nails, burning sensation of the throat, headache, shortness of breath

Skin: may be absorbed, redness, burning sensation, pain, blue lips or fingernails  

Eyes: redness, pain      

Ingestion: blue lips or fingernails

2,4-DICHLORO-1-NITROBEN­ZENE    611-06-3

blood

liver; kidneys

Inhalation: blue lips or finger nails

Skin: may be absorbed, redness, blue lips, blue fingernails    

Eyes: redness

Ingestion: blue lips or fingernails, blue skin, confusion, headache, vomiting, weakness

1,3-DINITROBENZENE     99-65-0

eyes; skin; resp tract

liver; may impair male fertility

Inhalation: blue lips or finger nails, blue skin, dizziness, headache, laboured breathing, weakness, burning sensation in the mouth, dry throat, thirst, disturbed vision  

Skin: may be absorbed, redness, skin burns, yellowing of skin

Eyes: redness, burns      

Ingestion: abdominal pain, blue skin, diarrhoea, dizziness, headache, laboured breathing, nausea, vomiting

Blood; liver; CVS; eyes; CNS; skin Inh; abs; ing; con

Anoxia, cyan; vis dist, central scotomas; bad taste, burning mouth, dry throat, thirst; yellowing hair, skin; anemia; liver damage

DINITROBENZENE     25154-54-5

eyes; skin; resp tract; lungs; blood

liver; may impair male fertility

Inhalation: blue lips or finger nails, blue skin, burning sensation, dizziness, headache, laboured breathing, sore throat, weakness, disturbed vision

Skin: may be absorbed, redness, yellowing of skin

Eyes: redness

Ingestion: abdominal pain, blue skin, diarrhoea, dizziness, headache, laboured breathing, nausea, vomiting

o-DINITROBENZENE     528-29-0

eyes; skin; resp tract; lungs; blood

liver

Inhalation: blue lips or finger nails, blue skin, burning sensation, dizziness, headache, laboured breathing, weakness, disturbed vision

Skin: may be absorbed      

Eyes: redness

Ingestion: Abdominal pain, blue skin, diarrhoea, dizziness, headache, laboured breathing, nausea, vomiting

Blood; liver; CVS; eyes; CNS; skin Inh; abs; ing; con

Anoxia, cyan; vis dist, central scotomas; bad taste, burning mouth, dry throat, thirst; yellowing hair, skin; anemia; liver damage

p-DINITROBENZENE     100-25-4

eyes; skin; resp tract

Inhalation: blue lips or finger nails, blue skin, dizziness, headache, laboured breathing, weakness, burning sensation in the mouth, dry throat, thirst, disturbed vision

Skin: may be absorbed, redness, yellowing of skin

Eyes: redness, burns      

Ingestion: abdominal pain, blue skin, diarrhoea, dizziness, headache, laboured breathing, nausea, vomiting

Blood; liver; CVS; eyes; CNS; skin Inh; abs; ing; con

Anoxia, cyan; vis dist, central scotomas; bad taste, burning mouth, dry throat, thirst; yellowing hair, skin; anemia; liver damage

2,4-DINITROPHENOL       51-28-5

GI tract

skin; CNS; blood; eyes;

Inhalation: sweating, palpitations, nausea, vomiting, collapse and death Skin: may be absorbed

DINITROTOLUENE     25321-14-6

blood

liver; male and female fertility

Inhalation: drowsiness, nausea, vomiting, weakness    

Skin: may be absorbed, blue lips or fingernails, blue skin, methemoglobin skin

Blood; liver; CVS; repro sys (in animals: liver, skin & kidney tumors) Inh; abs; ing; con

Anoxia, cyan; anemia, jaun; repro effects (carc)

2,3-DINITROTOLUENE     602-01-7

CNS; CVS; blood

Skin: may be absorbed

Ingestion: blue lips or fingernails; headache, nausea, sore throat; vomiting

2,4-DINITROTOLUENE     121-14-2

CNS; CVS; blood

Inhalation: blue lips or fingernails, headache, nausea, sore throat, vomiting  

Skin: may be absorbed Ingestion: blue lips or fingernails, headache, nausea, sore throat, vomiting

2,6-DINITROTOLUENE     606-20-2

blood

possibly carcinogenic to humans

Inhalation: blue lips or finger nails, blue skin, diarrhoea, dizziness, drowsiness    

Skin: may be absorbed

3,4-DINITROTOLUENE     610-39-9

CNS; CVS; blood;

Skin: may be absorbed

Ingestion: blue lips or fingernails, headache, nausea, sore throat, vomiting

NITROBENZENE 98-95-3

eyes; blood; CNS

skin; blood; liver; CNS; spleen; may impair male fertility

Inhalation: blue lips or finger nails, blue skin, dizziness, headache, nausea, unconsciousness, weakness  

Skin: may be absorbed

Blood; liver; kidneys; CVS; skin; eyes; repro sys Inh; abs; ing; con

Irrit eyes, skin, anoxia; derm; anemia; methemo; in animals: liver, kidney damage; testicular effects

4-NITRODIPHENYLAMINE     836-30-6

eyes; skin; resp tract; blood; brain

blood

Inhalation: burning sensation, cough, sore throat, see ingestion    

Skin: see ingestion    

Eyes: redness, pain    

Ingestion: blue lips or fingernails, blue skin, dizziness, headache, laboured breathing

NITROFEN         1836-75-5

eyes; skin; resp tract

skin; blood; CNS; human reproduction system

Inhalation: cough, laboured breathing, sore throat        

Skin: redness, pain          

Eyes: redness, pain, blurred vision  

Ingestion: abdominal pain

o-NITROTOLUENE           88-72-2

eyes; skin; resp tract; blood

liver; blood

Inhalation: blue lips or finger nails, blue skin, cough, dizziness, headache, laboured breathing, sore throat        

Skin: may be absorbed, redness, pain

Eyes: redness, pain    

Ingestion: abdominal pain, blue lips or fingernails, blue skin, dizziness, headache, laboured breathing

Blood; CNS; CVS; skin; GI tract Inh; abs; ing; con

Anoxia, cyan; head, weak, dizz; ataxia; dysp; tacar; nau, vomit

p-NITROPHENOL     100-02-7

eyes; skin; resp tract; CNS; blood; kidneys

CNS; liver; kidneys; blood;

Inhalation: blue skin, dizziness, headache, fever, nausea, shortness of breath, weakness, perspiration

Skin: may be absorbed, redness, scabs

Eyes: redness, pain    

Ingestion: burning pain in mouth and throat, abdominal pain, dizziness, unconsciousness

p-NITROTOLUENE           99-99-0

eyes; skin; resp tract

liver; kidneys

Inhalation: blue lips or finger nails, blue skin, cough, dizziness, headache, laboured breathing, sore throat        

Skin: may be absorbed, redness, pain

Eyes: redness, pain    

Ingestion: abdominal pain, blue lips or fingernails, blue skin, dizziness, headache, laboured breathing, sore throat, unconsciousness

Blood; CNS; CVS; skin; GI tract Inh; abs; ing; con

Anoxia, cyan; head, weak, dizz; ataxia; dysp; tacar; nau, vomit

PICRIC ACID      88-89-1

eyes; skin

skin

Inhalation: cough, sore throat, weakness

Skin: may be absorbed, redness    

Eyes: redness, pain    

Ingestion: diarrhoea, dizziness, headache, nausea, vomiting

Kidneys; liver; blood; skin; eyes Inh; abs; ing; con

Irrit eyes, skin; sens derm; yellow-stained hair, skin; weak, myalgia, anuria, polyuria; bitter taste, GI dist; hepatitis, hema, album, neph

TETRYL 479-45-8

eyes; skin; resp tract; kidneys; liver; blood

skin

Inhalation: sleeplessness, cough, headache, sore throat, nosebleeds

Skin: redness, yellow stains of skin and hair

Eyes: redness, pain    

Ingestion: abdominal pain, dizziness, headache, nausea

Resp sys; eyes; CNS; skin; liver; kidneys Inh; abs; ing; con

Sens derm, itch, eryt; edema on nasal folds, cheeks, neck; kera; sneez; anemia; ftg; cough, coryza; irrity; mal, head, lass, insom; nau, vomit; liver, kidney damage

2,4,6-TRINITROTOLUENE     118-96-7

eyes; skin; resp tract; blood

liver; blood; eyes

Eyes: redness, pain

Blood; liver; eyes; CVS; CNS; kidneys; skin; resp sys Inh; abs; ing; con

Irrit skin, muc memb; liver damage, jaun; cyan; sneez; cough, sore throat; peri neur, musc pain; kidney damage; cataract; sens derm; leucyt; anemia; card irreg

 

Back

Chemical Formula

Chemical

Synonyms;
UN code

CAS-Number

99558

1-AMINO-2-METHYL-5-NITROBENZENE

2-Amino-4-nitrotoluene;
2-Methyl-5-nitroaniline;
6-Methyl-3-nitroaniline;
2-Methyl-5-nitro-benzeneamine

99-55-8

119346

4-AMINO-2-NITROPHENOL

4-Hydroxy-3-nitroaniline;
o-Nitro-p-aminophenol;
2-Nitro-4-aminophenol

119-34-6

97007

1-CHLORO-2,4-DINITROBENZENE

4-Chloro-1,3-dinitrobenzene;
6-Chloro-1,3-dinitrobenzene;
1,3-Dinitro-4-Chlorobenzene;
2,4-Dinitrochlorobenzene

97-00-7

88733

1-CHLORO-2-NITROBENZENE

Chloro-o-nitrobenzene;
o-Chloronitrobenzene;
2-Chloronitrobenzene;
o-Nitrochlorobenzene
UN1578

88-73-3

121733

1-CHLORO-3-NITROBENZENE

Chloro-m-nitrobenzene;
m-Nitrochlorobenzene
UN1578

121-73-3

100005

1-CHLORO-4-NITROBENZENE

p-Chloronitrobenzene;
4-Chloronitrobenzene;
4-Chloro-1-Nitrobenzene;
p-Nitrochlorobenzene
UN1578

100-00-5

3209221

1,2-DICHLORO-3-NITROBENZENE

2,3-Dichloronitrobenzene

3209-22-1

99547

1,2-DICHLORO-4-NITROBENZENE

3,4-Dichloronitrobenzene

99-54-7

611063

2,4-DICHLORO-1-NITROBENZENE

2,4-Dichloronitrobenzene

611-06-3

35572782

3,5-DINITRO-o-TOLUIDINE

2-Amino-4,6-dinitrotoluene;
2-Methyl-3,5-dinitrobenzenamine

35572-78-2

19406510

3,5-DINITRO-p-TOLUIDINE

Amino-2,6-dinitrotoluene;
Benzenamine, 3,5-Dinitro-4-methyl-;
4- 4-Methyl-3,5-dinitrobenzenamine

19406-51-0

25154545

DINITROBENZENE

UN1597

25154-54-5

528290

o-DINITROBENZENE

1,2-Dinitrobenzene
UN1597

528-29-0

99650

m-DINITROBENZENE

1,3-Dinitrobenzene;
2,4-Dinitrobenzene
UN1597

99-65-0

100254

p-DINITROBENZENE

UN1597

100-25-4

99332

3,5-DINITROBENZOYL CHLORIDE

3,5-Dinitrobenzoic acid chloride

99-33-2

27478348

DINITRONAPHTHALENE

27478-34-8

605710

1,5-DINITRONAPHTHALENE

605-71-0

75321209

1,3-DINITROPYRENE

75321-20-9

42397648

1,6-DINITROPYRENE

42397-64-8

66568

2,3-DINITROPHENOL

66-56-8

51285

2,4-DINITROPHENOL

2,4-DNP;
1-Hydroxy-2,4-dinitrobenzene

51-28-5

42397659

1,8-DINITROPYRENE

42397-65-9

25321146

DINITROTOLUENE

Dinitrophenylmethane;
Methyldinitrobenzene
UN2038

25321-14-6

602017

2,3-DINITROTOLUENE

1-Methyl-2,3-dinitrobenzene

602-01-7

121142

2,4-DINITROTOLUENE

Dinitrotoluene;
2,4-Dinitrotoluol;
1-Methyl-2,4-dinitrobenzene

121-14-2

619158

2,5-DINITROTOLUENE

2-Methyl-1,4-dinitrobenzene

619-15-8

606202

2,6-DINITROTOLUENE

2-Methyl-1,3-dinitrobenzene

606-20-2

610399

3,4-DINITROTOLUENE

4-Methyl-1,2-dinitrobenzene

610-39-9

70348

1-FLUORO-2,4-DINITROBENZENE

2,4-Dinitrofluorobenzene;
2,4-Dinitro-1-fluorobenzene;
1,2,4-Fluorodinitrobenzene

70-34-8

6393426

4-METHYL-2,6-DINITROANILINE

4-Amino-3,5-Dinitrotoluene;
Benzenamine, 4-Methyl-2,6-dinitro-;
2,6-Dinitro-p-toluidine

6393-42-6

129157

2-METHYL-1-NITROANTHRAQUINONE

2-Methyl-1-nitro-9,10-anthracenedione;
1-Nitro-2-methylanthraquinone

129-15-7

614006

N-METHYL-N-NITROSOANILINE

Methylnitrosoaniline;
N-Methyl-N-nitrosobenzenamine;
Methylphenylnitrosamine;
Nitrosomethylaniline;
N-Nitroso-N-methylaniline

614-00-6

602879

5-NITROACENAPHTHENE

1,2-Dihydro-5-nitro-acenaphthylene;
5-Nitronaphthalene ethylene

602-87-9

98953

NITROBENZENE

Nitrobenzene;
Nitrobenzol
UN1662

98-95-3

92933

4-NITRODIPHENYL

4-Nitrobiphenyl;
p-Nitrodiphenyl;
p-Phenyl-nitrobenzene;
4-Phenyl-nitrobenzene

92-93-3

836306

4-NITRODIPHENYLAMINE

Benzenamine, 4-Nitro-N-phenyl-;
p-Nitrodiphenylamine;
p-Nitrophenylphenylamine

836-30-6

5307142

2-NITRO-p-PHENYLENEDIAMINE

4-Amino-2-nitroaniline;
1,4-Diamino-2-nitrobenzene;
2-Nitro-1,4-benzenediamine;
2-Nitro-1,4-diaminobenzene;
2-Nitro-1,4-phenylenediamine

5307-14-2

1836755

NITROFEN

2',4'-Dichloro-4-nitrobiphenyl ether;
2,4-Dichloro-4'-nitrodiphenyl ether;
2,4-Dichloro-1-(4-nitrophenoxy)benzene;
2,4-Dichlorophenyl-p-nitrophenyl ether

1836-75-5

86577

1-NITRONAPHTHALENE

a-Nitronaphthalene

86-57-7

581895

2-NITRONAPHTHALENE

b-Nitronaphthalene

581-89-5

99592

5-NITRO-o-ANISIDINE

2-Amino-1-methoxy-4-nitrobenzene;
3-Amino-4-methoxynitrobenzene;
2-Amino-4-nitroanisole;
2-Methoxy-5-nitroaniline

99-59-2

88755

o-NITROPHENOL

2-Hydroxynitrobenzene;
2-Nitrophenol
UN1663

88-75-5

554847

m-NITROPHENOL

m-Hydroxynitrobenzene;
3-Hydroxynitrobenzene;
3-Nitrophenol
UN2648

554-84-7

100027

p-NITROPHENOL

4-Hydroxynitrobenzene;
4-Nitrophenol
UN1663

100-02-7

5522430

1-NITROPYRENE

3-Nitropyrene

5522-43-0

156105

p-NITROSODIPHENYLAMINE

4-Nitrosodiphenylamine;
p-Nitroso-N-phenylaniline;
4-Nitroso-N-phenylaniline;
4-Nitroso-N-phenylbenzenamine

156-10-5

88722

o-NITROTOLUENE

o-Methylnitrobenzene;
2-Methylnitrobenzene;
2-Nitrotoluene
UN1664

88-72-2

99081

m-NITROTOLUENE

3-Methylnitrobenzene;
m-Methylnitrobenzene;
3-Nitrotoluene
UN1664

99-08-1

99990

p-NITROTOLUENE

p-Methylnitrobenzene;
4-Methylnitrobenzene;
p-Nitrotoluene;
4-Nitrotoluene
UN1664

99-99-0

88891

PICRIC ACID

2-Hydroxy-1,3,5-trinitrobenzene;
1,3,5-Trinitrophenol;
2,4,6-Trinitrophenol
UN0154
UN1344

88-89-1

479458

TETRYL

N-Methyl-N,2,4,6-tetranitroaniline;
N-Methyl-N,2,4,6-tetranitrobenzenamine;
Trinitrophenylmethylnitramine;
2,4,6-Trinitrophenylmethylnitramine
UN0208

479-45-8

129793

2,4,7-TRINITROFLUOREN-9-ONE

2,4,7-Trinitro-9-fluorenone

129-79-3

75321196

1,3,6-TRINITROPYRENE

75321-19-6

118967

2,4,6-TRINITROTOLUENE

2-Methyl-1,3,5-trinitrobenzene;
Trinitrotoluene
UN0209
UN1356

118-96-7

 

Back

Page 2 of 87

" DISCLAIMER: The ILO does not take responsibility for content presented on this web portal that is presented in any language other than English, which is the language used for the initial production and peer-review of original content. Certain statistics have not been updated since the production of the 4th edition of the Encyclopaedia (1998)."

Contents