WHO Headquarters:
150, cours Albert Thomas,
F-69372 Lyon Cedex 08, France
Tel.: +33-7 273 84 85
Fax: +33-7 273 85 75
Telex: 380023
Headquarters: 20 avenue Appia,
1211 Geneva 27, Switzerland
Tel.: +41-22-791 21 11
Fax: +41-22-791 07 46
Telex: 845 415 416
Cable: UNISANTE GENEVE
IARC Headquarters:
150, cours Albert Thomas,
F-69372 Lyon Cedex 08, France
Tel.: +33-7 273 84 85
Fax: +33-7 273 85 75
Telex: 380023
UNEP Headquarters:
P.O. Box 30552,
Nairobi, Kenya
Tel.: 2-23 08 00
Fax:2-22 68 31
Telex: 22068 KNEPKE
Cable: UNITERRA NAIROBI
IAEA Headquarters
Vienna International Centre,
Wagramerstrasse 5,
P.O. Box 100,
A-1400 Vienna, Austria
Tel.: +43-1-23 60
Fax: +43-1-23 45 64
Telex: 112645 ATOM A
Cable: INATOM VIENNA
UNDP Headquarters:
1 United Nations Plaza,
New York,
NY 10017,
United States
Tel.: +1-212-906 5000
Fax: +1-212-906 5778
FAO Headquarters:
Viale delle Terme de Caracalla,
1-00100 Rome, Italy
Tel.: +39-6-522 51
Fax: +39-6-522 53 152
Telex: 610181 FAO 1
Cable: FOODAGRI ROME
IMO Headquarters:
4 Albert Embankment,
London SE1 7SR,
United Kingdom
Tel.: +44-171-735 7611
Fax: +44-171-587 3210
Telex: 23588
UNCTAD Headquarters:
Palais des Nations,
CH 1211
Geneva 10,
Switzerland
Tel.: +41-22-907 12 34
Fax: +41-22-907 0 57
Cable: UNATIONS GENEVE
Excerpted from Vogel 1994
Danish industrial relations provide an example of a country with a number of institutions that play a role in relation to health and safety. The main features are:
COLLECTIVE BARGAINING: Negotiation of agreements by which trade unions and employers fix wages, conditions of work, etc. Pertinent highlights are:
Shop stewards who are elected by workers under collective bargaining agreements; enjoy statutory protection against dismissal; serve as channel between workers and management on working conditions.
Collective Agreement on Cooperation and Cooperation Committees provides for information to be given to individuals and groups of workers in advance so they can make their views known before a decision is taken and for the establishment of cooperation committees.
Cooperation committees must be set up in all firms employing more than 35 workers (25 in the public service). Joint committees to promote cooperation in day-to-day operations; they must be consulted on the introduction of new technologies and the organization of production; some co-determination rights on working conditions, training and personal data.
National collective agreement on industrial disputes (of 1910) gives workers a right (rarely exercised) to stop work if considerations of “life, welfare or honour” make this absolutely necessary. Other collective agreements contain provisions on training and trade unions also provide it.
FRAMEWORK LAW: The Working Environment Act creates “the basis on which the undertakings themselves will be able to solve questions relating to safety and health under the guidance of the employers’ and workers’ organizations and under the guidance and supervision of the Labour Inspection Service” (Sec. 1(b)). The Act establishes a complete system from the plant to the national level to permit worker participation:
Safety representatives are elected representatives required in firms employing at least ten workers; they enjoy the same protection against dismissal and retaliation as shop stewards and are entitled to reimbursement of official expenses.
Safety groups: The safety representative and the department supervisor form the safety group. Its functions are to:
Members of the safety group are entitled to training and to necessary information.
Safety Committees are required in firms employing at least 20 workers. In firms with more than two safety groups, the safety committees consist of workers elected from among safety representatives, two supervisor members and an employer’s representative.
The functions are:
WORKING ENVIRONMENT COUNCIL involves employers’ and workers’ organizations in the definition and application of preventive policy at the national level. Composition: 11 representatives of employee organizations representing manual and non-manual workers, one for supervisors, ten of employers’ organizations, plus an occupational medical practitioner, a technical expert and non-voting governmental representatives. Functions:
WORKING ENVIRONMENT FUND is managed by a tripartite board. The Fund has mainly information and training duties, but also finances research programmes.
TRADE SAFETY COUNCILS: Twelve Trade Safety Councils examine the problems of their trade or industry and advise undertakings. They are also consulted on draft legislation. Equal representation of employers’ and supervisors’ organizations on the one hand and workers’ organizations on the other hand.
GOVERNMENTAL AUTHORITIES: In addition, the Ministry of Labour, the Labour Inspection Service and within it, the Danish Institute of the Working Environment, provide various types of services and advice in the field of occupational safety and health. Collective industrial disputes are heard by the Labour Courts.
The agreement between Bethlehem Steel and the United Steelworkers of America is typical of company-wide agreements in large unionized manufacturing enterprises in the United States. Steel industry labour agreements have contained safety and health articles for more than 50 years. Many provisions negotiated in the past gave workers and the union rights that were later guaranteed by law. Despite this redundancy, the provisions still appear in the contract as a hedge against changes in the law, and to allow the union the option of taking violations to impartial arbitration rather than the courts.
The Bethlehem agreement runs from 1 August 1993 to 1 August 1999. It covers 17,000 workers in six plants. The full agreement is 275 pages long; 17 pages are devoted to safety and health.
Section 1 of the safety and health article pledges the company and the union to cooperate in the objective of eliminating accidents and health hazards. It obligates the company to provide safe and healthful workplaces, obey federal and state law, provide employees with the necessary protective equipment free of charge, provide chemical safety information to the union and inform workers of the hazards and controls for toxic substances. It grants the union’s central safety and health department the right to any information in the company’s possession that is “relevant and material” to an understanding of potential hazards. It requires the company to make air sampling tests and environmental investigations at the request of the union co-chairperson of the plant’s safety and health committee.
Section 2 sets up joint union-management safety and health committees at the plant and national levels, prescribes the rules under which they operate, mandates training for committee members, gives members of the committee access to all parts of the plant to facilitate the committee’s work and specifies the applicable rates of pay for committee members on committee business. The section also specifies how disputes over protective equipment are to be resolved, requires the company to notify the union of all potentially disabling accidents, sets up a system of joint accident investigation, requires the company to gather and supply to the union certain safety and health statistics, and establishes an extensive safety and health training programme for all employees.
Section 3 gives workers the right to remove themselves from work involving hazards beyond those “inherent in the operation” and provides an arbitration mechanism through which disputes over such work refusals can be resolved. Under this provision, a worker cannot be disciplined for acting in good faith and on the basis of objective evidence, even if a subsequent investigation shows that the hazard did not in fact exist.
Section 4 specifies that the committee’s role is advisory, and that committee members and officers of the union acting in their official capacity are not to be held liable for injuries or illnesses.
Section 5 states that alcoholism and drug abuse are treatable conditions, and sets up a programme of rehabilitation.
Section 6 establishes an extensive programme for controlling carbon monoxide, a serious hazard in primary steel production.
Section 7 provides workers with vouchers for the purchase of safety shoes.
Section 8 requires the company to keep individual medical records confidential except in certain limited circumstances. However, workers have access to their own medical records, and may release them to the union or to a personal physician. In addition, physicians for the company are required to notify workers of adverse medical findings.
Section 9 establishes a medical surveillance programme.
Section 10 establishes a programme for investigating and controlling the hazards of video display terminals.
Section 11 establishes full-time safety representatives in each plant, chosen by the union but paid by the company.
In addition, an appendix to the agreement commits the company and the union to review each plant’s safety programme for mobile equipment operating on rails. (Fixed rail equipment is the leading cause of death by traumatic injury in the American steel industry.)
The World Trade Organization (WTO), established in 1995 as the result of the Uruguay Round of multilateral trade negotiations, is the successor to the General Agreement on Tariffs and Trade (GATT), the international trade agreement dating from the late 1940s. The WTO is the legal and institutional foundation of the world’s multilateral trading system. It aims to promote open international trade, not only in goods (as in GATT), but also in services and intellectual property. The WTO also has an explicit goal of advancing development, especially of the least developed countries.
The WTO is designed to promote trade, and related issues such as occupational safety and health are addressed only insofar as they may interfere with free trade. Two Agreements are relevant. The Agreement on the Application of Sanitary and Phytosanitary Measures addresses food safety and animal and plant health regulations. It permits countries to promulgate such regulations, but requires that they be based on science, applied only to the extent necessary to protect human, animal, or plant life or health, and should not arbitrarily discriminate between member countries. While member countries are encouraged to base their regulations on international standards, they are permitted to set more stringent standards if there is scientific justification or if they have based their standards on an appropriate risk assessment. The Agreement on Technical Barriers to Trade reinforces these precepts. Its goal is to prevent technical regulations and standards from posing unnecessary obstacles to trade. To this end, there is a code of good practice for promulgating standards and a requirement that standards be applied equitably to domestic and imported products.
While the foregoing two Agreements pertain principally to environmental, food quality, and pharmaceutical regulations, they could conceivably be applied to occupational health and safety. The summary statement from the 1995 Marrakesh meeting of the WTO provided for the formation of a working party on International Labour Standards. However, the WTO has thus far avoided addressing occupational health and safety, and several member governments, especially those of developing countries, have held that worker health should remain a national prerogative, uncoupled from international trade considerations. Therefore, the WTO has to date played no role in advancing occupational health and safety.
Europe
Economic integration in Europe is distinguished by its early origins, dating to the Treaty of Rome in 1957, and by the prominence that social and political issues have assumed alongside economic considerations. In fact, integration in Europe extends well beyond lowering trade barriers; it also includes the free movement of workers (and soon of people in general), the promulgation of binding transnational laws and regulations, and the creation of a transnational bureaucracy with substantial financial backing. As a result, occupational health has received considerable attention.
The European Economic Community (EEC), or Common Market, was established by the Treaty of Rome in 1957. This Treaty began to lift trade barriers among member nations, and established the EEC’s organizational structure. The Commission of the European Communities became the EEC’s civil service and bureaucracy, with its work carried out by 23 Directorates General (including one, DG V, responsible for employment, industrial relations and social affairs). The Council of Ministers handles major policy-making, while the European Parliament has a co-decision-making role.
The Court of Justice adjudicates disputes that arise under treaties. The Advisory Committee on Safety, Hygiene and Health Protection at Work (ACSH), established by the Council in 1974 to advise the Commission, includes representatives of labour, management, and the governments from each member country, and is supported by staff from the Health and Safety Directorate of the DG V. The ACSH reviews legislative proposals relevant to occupational health, initiates activities on specific hazards, and coordinates joint efforts. The Economic and Social Committee has a consultative role.
In 1978 the Commission introduced the first Action Programme on Health and Safety, with considerable support from the ACSH. It focused on hazardous substances, prevention of machinery hazards, monitoring and inspections and the improvement of attitudes towards health and safety. Since then, successive action programmes have been directed at other occupational health concerns such as ergonomics, occupational health statistics, assistance for small enterprises and training. These have promoted occupational health solutions throughout the member nations, providing training, technical advice and written materials. For example, in 1982 the Commission convened an informal group of senior labour inspectors to encourage personnel and information exchanges among the 12 nations, comparison of member countries’ practices and improved practice. Such initiatives exemplify how the integration of national economies can have positive effects on the practice of occupational health and safety.
The Single European Act (SEA) of 1987 signalled a major step forward in European integration and in the development of the European Free Trade Area. A firm date was set for the establishment of a Single Market, 1992, and activity in a range of social issues, including occupational health, was stimulated. Unanimity among member nations was no longer needed to set policy; instead, a “qualified majority” could do so. Two of the Act’s articles are especially relevant to occupational health. Article 100(a) aims to harmonize product standards in the member countries, a process that has important safety implications. This Article specifies that standards should achieve a “high level of health protection”. Article 118(a) directly addresses occupational health and safety, holding that member countries “shall pay particular attention to encouraging improvements, especially in the working environments, as regards the health and safety of workers, and shall set as their objective the harmonization of conditions in this area while maintaining the improvements made”.
In 1989, two important events further solidified the role of occupational health in the process of European integration. The Social Charter was adopted by 11 of the then 12 Member States, including a clause that emphasized “the need for training, information, consultation and balanced participation of workers as regards the risks incurred and the steps taken to eliminate or reduce them”.
Also in 1989, the Framework Directive was adopted by the Council, the first major policy initiative under the SEA. It defined the EC (now the European Union (EU)) approach to worker health and safety, extending to public and private employees in all member countries. Employers were assigned a general “duty to ensure the safety and heath of workers in every aspect related to work”, and specific duties to:
The Framework Directive adopted a broad view of what workplace factors were relevant to occupational health, including design issues, monotonous work and piece-work. It called for active worker participation in health and safety programmes, including rights to advance consultation with employers on health and safety initiatives, paid time off to perform health and safety functions, meetings with government inspectors and refusal to work in case of “serious, imminent and unavoidable danger” (subject to national laws). A series of so-called daughter directives issued in the wake of the Framework Directive address the use of personal protective equipment, manual handling of loads, work with video display terminals and other issues.
Will the Framework Directive translate into effective national policy? Underlying this issue is the EU’s explicit commitment to the principle of subsidiarity, which holds that all policy should be implemented by member countries rather than by the EU, unless “by reason of the scale of effects of the proposed action” it is better carried out centrally. This will result in tension between the mandates of the central directives and the sovereign actions of the member countries.
Each member country is required to transpose the Framework Directive (like all directives) into national law, to implement policies accordingly and to enforce them in practice. This process leaves countries room for discretion and may allow some non-compliance. By all accounts the EU is not well equipped to monitor member country compliance with its occupational health and safety directives. Closer monitoring of each country’s practices, and the political will to use available remedies in cases of non-compliance (including appeal to the Court of Justice) will be necessary if the EU’s full potential in promoting occupational health is to be realized.
A related question concerns the fate of national policies that are more protective than those of the EU. Since Article 118(a) requires only a minimum common level of workplace protection, there may be a tendency towards downward harmonization in response to economic pressures.
In 1994 the Council, acting on a three-year-old proposal from the Commission, established the European Agency for Safety and Health at Work, sited in Bilbao, Spain. The Agency’s aim is to “provide the Community bodies, the Member States and those involved in the field with the technical, scientific and economic information of use in the field of safety and health at work”. It will focus on technical and scientific consultation to the Commission, information exchange, training, consistent data collection and promoting research.
In 1995 the Commission published its action programme for the period 1996-2000. One important component was continued attention to legislative initiatives—ensuring that Community directives be accurately transported into national law, and promulgating new directives on physical agents, chemical agents, transport, and work equipment. A longstanding Committee of Senior Labour Inspectors was formalized to harmonize methods of workplace inspection and to monitor the implementation of national labour laws. However, there was also considerable emphasis on non-legislative measures, principally information and persuasion. A new initiative, SAFE (Safety Actions for Europe) was announced, to address health and safety problems in small and medium-sized firms. The approach planned was to identify successful initiatives in model firms and to use these as examples for other firms.
In summary, European economic integration and free trade have evolved as part of a broader programme of social and political integration. This process has included serious discussions of social issues, including occupational health and safety. A complicated bureaucracy has several components that bear on workplace health and safety. The reference point for the EU is community law rather than national law, in contrast to every other free-trade agreement. This arrangement is the world’s most advanced example of promoting occupational health and safety as a component of free trade. It will affect more than the EU countries; occupational health and safety considerations will be part of every association, partnership and cooperation agreement between the EU and the countries of Central and Eastern Europe, extending this progressive tradition. The problems that persist—reconciling national sovereignty with coordinated progress, monitoring compliance with Community directives, reconciling differences between more and less progressive countries and sharing scarce technical expertise and resources—will continue to pose challenges to European integration in coming years.
North America
The three nations of North America have been major trading partners for many decades. The first step towards a regional trading agreement was the US-Canada Free Trade Agreement of 1987, which lowered tariffs and other trading restrictions between those two countries. In the early 1990s, in preparation for a continent-wide trade agreement, US and Mexican labour authorities began several cooperative efforts, such as the training of labour inspectors. In 1993 Mexico, Canada and the US ratified the North American Free Trade Agreement (NAFTA), which took effect in 1994 for full implementation over about a decade. NAFTA was designed to abolish most trade restrictions among the three countries.
The process that led to NAFTA differed from the European experience in several ways. NAFTA had a shorter history and was negotiated rapidly. There was no tradition of incorporating social issues into the process. Environmental and labour concerns were ultimately codified in a pair of side agreements that were adopted alongside the NAFTA proper. Environmental groups had been active in the debate leading to NAFTA and won a number of environmental safeguards in the environmental side agreement, but labour groups took a different approach. Unions and their allies, especially in the US and Canada, vigorously opposed NAFTA and campaigned more to block the treaty altogether than for specific labour-friendly provisions. Moreover, there was reluctance among the three governments to relinquish any sovereignty regarding their respective labour laws. As a result NAFTA’s labour side agreement is relatively narrow compared to the environmental side agreement or to the European experience.
The labour side agreement, in an Annex, defines “guiding principles that the Parties are committed to promote, subject to each Party’s domestic law, but do not establish common minimum standards”. These principles include prevention of occupational injuries and illnesses, compensation in cases of occupational injuries and illnesses, protection of migrant workers and children, more traditional labour rights such as freedom of association, the rights to organize, bargain collectively and strike, and prohibition of forced labour. The stated objectives of the side agreement are to improve working conditions, encourage information exchange, data collection and collaborative studies and promote compliance with each country’s labour laws.
The early Articles of the labour side agreement urge each country to publicize its own labour laws internally and to enforce them fairly, equitably and transparently. Next, a Commission for Labour Cooperation is formed. It consists of a Council of the three labour ministers or their designees, which is responsible for policy-making and promoting cooperative activities, and a Secretariat headed by an Executive Director that will prepare background reports and studies and otherwise support the Council. Moreover, each nation is directed to establish a National Administrative Office which will serve as its liaison to the Commission and assist the Commission in its work. Several general procedures are set forth, such as a direction to seek expertise through cooperation with the ILO. However, the agreement defines few specific procedures in support of its objectives.
Much of the concern that drove the side agreement was that a member nation, usually presumed to be Mexico, might, through lax labour practices, gain an unfair trade advantage; this would expose Mexican workers to low wages and unwholesome working conditions and would transfer jobs away from US and Canadian workers. Hence, a large part of the side agreement is dedicated to procedures for handling complaints and grievances. If such a concern arises, the first step is supposed to be consultation between the governments involved at the ministerial level. Next, the Commission may form an Expert Committee of Evaluation (ECE), usually three qualified people “chosen strictly on the basis of objectivity, reliability and sound judgement”, to consider the matter, provided that the matter is trade related and is “covered by mutually recognized labour laws”. The ECE may rely on information provided by the Commission, each member nation, organizations or individuals with relevant expertise, or the public. The ECE report is provided to each member nation.
If the ECE concludes that one country may have failed to enforce its labour standards then a formal dispute resolution process may be triggered. Significantly, this process is available only if the dispute pertains to occupational health and safety, child labour or minimum wages. First, the involved nations attempt to negotiate a settlement. If they cannot agree, an arbitral panel is convened from a roster of experts established and maintained by the Council. The panel presents its findings of fact, its conclusion regarding whether a nation has failed to enforce its standards, and its recommendations for corrective action. If the involved nation does not comply with its recommendations, the panel may be reconvened and may impose fines. If a nation refuses to pay its fine, the ultimate penalty is a suspension of NAFTA benefits, usually through tariff imposition in the sector where the violation occurred, in order to recover the amount of the fine.
Overall, the labour side agreement, as a framework for occupational health and safety under NAFTA, is less extensive than corresponding European arrangements. The focus in NAFTA is on dispute resolution rather than on joint research, information sharing, training, technology development and related initiatives. The dispute resolution process, in the view of labour advocates, is cumbersome, time-consuming and relatively toothless. More importantly, the side agreement expresses no shared commitment to fundamental labour rights. It is assiduous in respecting each nation’s labour laws, and has no provisions for upgrading or harmonizing those that are deficient. Its scope is narrow, and although there has been little experience to date, it is likely that the broad European approach to occupational health, extending to such concerns as shiftwork and stress, will not be replicated.
Asia and Latin America
Although Asia is the world’s fastest growing economic region, free-trade negotiations in the region have not advanced significantly. Neither the ASEAN nor the APEC has addressed occupational health and safety in its trade negotiations. Similarly, the growing trading pacts of Latin America, such as MERCOSUR and the Andean Pact, have included no occupational health and safety initiatives.
OBJECTIVE
These canons provide standards of ethical conduct for industrial hygienists as they practice their profession and exercise their primary mission, to protect the health and well-being of working people and the public from chemical, microbiological and physical health hazards present at, or emanating from, the workplace.
CANONS OF ETHICAL CONDUCT
Industrial Hygienists shall:
CANON 1
Practice their profession following recognized scientific principles with the realization that the lives, health and well-being of people may depend upon their professional judgement and that they are obligated to protect the health and well-being of people.
INTERPRETIVE GUIDELINES
CANON 2
Counsel affected parties factually regarding potential health risks and precautions necessary to avoid adverse health effects.
INTERPRETIVE GUIDELINES
CANON 3
Keep confidential personal and business information obtained during the exercise of industrial hygiene activities, except when required by law or overriding health and safety considerations.
INTERPRETIVE GUIDELINES
CANON 4
Avoid circumstance where a compromise of professional judgment or conflict of interest may arise.
INTERPRETIVE GUIDELINES
CANON 5
Perform services only in the areas of their competence.
INTERPRETIVE GUIDELINES
CANON 6
Act responsibly to uphold the integrity of the profession.
INTERPRETIVE GUIDELINES
Provided by the American Board of Industrial Hygiene (1995).
SABRE Employment (UK)
Mission Statement:To communicate overall objectives/business goals which not only embrace the provision of quality service to applicants, but clearly reflect the desire to provide an efficient recruitment service to employers and which assist employers to improve their capacity to employ people with disabilities. Emphasis should be placed on the primary aim to achieve customer satisfaction. “All of Sabre’s activities begin with our customers. Our goals are to provide recruitment solutions through effective job matching, reliable training and support and to offer expertise in the recruitment and employment of people with disabilities.”
A job fair was recently held to give people a chance to meet employers and learn about different jobs. McDonald’s Restaurants Ltd. ran a workshop on interview skills and also sponsored the job fair event along with Shell and Pizza Hut. There were employer displays which provided an opportunity for employers and prospective employees with learning difficulties to meet in an informal way.
The Coverdale Bursary Programme (UK)
For five years, Coverdale, a small (70 people) management consultancy has offered bursaries to the value of £10,000 per person to disabled individuals seeking high quality management training. These individuals then go into companies like Barclays Bank, the Post Office and Midland Bank for additional training, in a process which promotes long-term attitude change across participating companies. This programme is now being expanded. It has been adapted by The Canadian Council for Rehabilitation and Work.
Brook Street and FYD (UK)
A commercial recruitment agency, Brook Street, and a charity for young deaf people, Friends for the Young Deaf (FYD), have worked in partnership for some years. Brook Street offers work experience and assessment to the young deaf graduates completing the FYD leadership training programme; Brook Street then places appropriate candidates into jobs, charging the same commercial fee they would charge for any candidate.
Employers’ Forum on Disability (UK)
Companies involved in the Employers’ Forum on Disability, an employer-funded association that promotes the integration of disabled persons in the labour market and provides advisory services for interested enterprises, helped disabled entrepreneur Stephen Duckworth to establish his business, Disability Matters, which now offers high quality consultancy and awareness-raising on disability to companies across the UK. Its philosophy encompasses the following:
Other examples in the UK: The Employer Forum on Disabilities
Leading UK companies drafted a highly influential policy framework called the “Employers Agenda on Disability, a Ten Point Plan”. This was launched by the Prime Minister and is now publicly supported by more than 100 major firms. It has proven a powerful force for change because it was drafted by the employers themselves in consultation with disability experts. It is now a key tool in helping employers to comply with discrimination legislation.
Supporters of the Agenda are publicly committed to structuring their corporate policy on disability using a 10-point framework addressing the following issues: Equal Opportunities Policy and Procedures Statement; Staff Training and Disability Awareness; The Working Environment; Recruitment; Career Development; Retention, Retraining and Redeployment; Training and Work Experience; People with Disabilities in the Wider Community; Involvement of Disabled People; Monitoring Performance.
The Action File on Disability, a unique manual which provides practical information on how to implement the Agenda, has been produced by the Employers’ Forum on Disability.
Graduate Recruitment:
More than 20 companies are involved in a consortium working with “Workable”, which brokers work-experience opportunities to disabled students in a planned and structured manner.
Twenty-five companies jointly fund an initiative making annual Career Fairs for students accessible for disabled students. The Career Fairs are now wheelchair accessible, and interpreters for the deaf are available, as well as large-print brochures and other support. Employers had experienced such difficulty attracting disabled graduates to apply for jobs using traditional intermediaries that they are now pioneering recruitment methods which speak directly to the disabled students.
HIRED (US)
The project HIRED in San Francisco embodies this new employer orientation. The acronym stands for Helping Industry Recruit Employees with Disabilities. Their literature highlights the services they offer employers:
“Project HIRED is a private, not for profit organization serving the San Francisco Bay area. Our purpose is to assist individuals with disabilities to secure jobs appropriate to their qualifications and career goals. Our services to employers include:
In addition to less formal corporate partnerships, Project HIRED has a corporate membership programme involving approximately 50 Bay Area companies. As corporate members, these companies are entitled to free consulting and a discount on seminars. We are currently exploring additional services, such as library of video resources, to further assist corporate members successfully incorporate people with disabilities in their workforce.”
ASPHI (Italy)
The origins of ASPHI (Associazione per lo Sviluppo di Progetti Informatici per gli Handicappati) go back to the late 1970s when IBM Italy organized courses in computer programming for the visually impaired. A number of companies which had subsequently employed the trainees, together with specialist partner agencies from the non-profit sector, created ASPHI for the physically disabled and the hearing and mentally impaired. The Association involves more than 40 companies which provide financial support, staff and volunteer helpers, advice as well as employment opportunities for ASPHI’s graduates. ASPHI’s objective is to harness information technologies for the social and vocational integration of disadvantaged groups. Its activities include: job training, research and development of new products (mainly software) which facilitate alternative methods of communication, personal autonomy and rehabilitation, and community education, thus breaking down prejudices and discrimination against disabled people. Each year, some 60 young people are qualified by ASPHI. With about 85% of its graduates finding a permanent job, ASPHI’s success has brought it national and international recognition.
Swedish Employers’ Federation Initiative
The Swedish Employers’ Federation Initiative, “Persons with Disabilities in Companies”, positions disability firmly in the labour market debate in the country and conveys the message that disability is an issue of importance to the Swedish Employers Confederation and its members. The Federation states: “The path to employment for persons with disabilities must be made smoother. Requirements for this include:
Chemical Name |
Colour/Form |
Boiling Point (°C) |
Melting Point (°C) |
Molecular Weight |
Solubility in Water |
Relative Density (water=1) |
Relative Vapour Density (air=1) |
Vapour Pressure/ (Kpa) |
Inflam. |
Flash Point (ºC) |
Auto Ignition Point (ºC) |
1-AMINO-2-METHYL-5-NITROBENZENE |
yellow monoclinic prisms from alcohol |
105.5 |
152.2 |
sl sol |
1.3x |
||||||
4-AMINO-2-NITROPHENOL |
dark red plates or needles from water & alcohol |
131 |
154.1 |
sol |
|||||||
1-CHLORO-2,4-DINITROBENZENE |
yellow crystals |
315 |
53 |
202.6 |
insol |
1.7 |
6.98 |
2.0 ll |
|||
1-CHLORO-3-NITROBENZENE |
yellow crystals; monoclinic needles |
245-246 |
32-33 |
157.56 |
insol |
1.305 |
261 |
||||
2-CHLORO-3-NITROBENZENE |
pale-yellow orthorhombic prisms from alcohol |
236 |
46 |
157.6 |
insol |
1.534 |
|||||
1-CHLORO-4-NITROBENZENE |
monoclinic prisms; yellow crystals |
242 |
83.5 |
157.6 |
insol |
1.3 |
5.44 |
@ 30 ºC |
127 cc |
510 |
|
2,4-DICHLORO-1-NITROBENZENE |
258.5 |
34 |
192.00 |
insol |
@ 80 ºC |
||||||
1,2-DICHLORO-4-NITROBENZENE |
needles from alcohol & carbon tetrachloride; liquid; solid |
255.5 |
43 |
192.00 |
insol |
@ 75 ºC/4 ºC |
6.63 |
0.014 mm Hg |
|||
3,5-DINITRO-p-TOLUIDINE |
171 |
197.14 |
|||||||||
2,3-DINITROTOLUENE |
yellow crystals |
250-300 |
63 |
182.1 |
insol |
1.3 |
6.28 |
||||
2,6-DINITROTOLUENE |
rhombic needles from alcohol; yellow to red solid |
285 |
66 |
182.1 |
@ 111 ºC |
6.28 |
5.67x |
207 cc |
|||
3,4-DINITROTOLUENE |
crystals or needles |
250-300 |
58 |
182.1 |
insol |
1.26 |
6.28 |
>110 |
|||
DINITROBENZENE |
pale yellow solid; white crystalline solid |
300 |
75-85 |
168 |
insol |
1.6 |
5.8 |
<0.1 |
150 |
||
1,3-DINITROBENZENE |
yellowish crystals; rhombohedral plates from alcohol; pale yellow solid |
300-303 |
90 |
168.1 |
sl sol |
@ 18 ºC/4 ºC |
5.8 |
<0.1 |
149 |
||
o-DINITROBENZENE |
colourless or yellow crystals, needles or plates; needles from benzene, plates; white crystals;pale yellow solid |
319 |
118 |
168.1 |
insol |
1.3119 120 |
5.79 |
<0.1 |
150 cc |
||
p-DINITROBENZENE |
white crystals; needles from alc; colourless to yellow monoclinic needles; pale yellow solid; yellow crystals |
299 |
174 |
168.1 |
insol |
@ 18 ºC/4 ºC |
5.8 |
<0.1 |
150 |
||
3,5-DINITROBENZOYL CHLORIDE |
196 |
74 |
230.56 |
||||||||
1,5-DINITRONAPHTALENE |
219 |
218.16 |
insol |
||||||||
2,3-DINITROPHENOL |
144.5 |
184.10 |
sl sol |
1.681 |
|||||||
2,4-DINITROPHENOL |
yellowish to yellow orthorhombic crystals |
112-114 |
184.1 |
sl sol |
@ 24 ºC |
6.35 |
@ 25 ºC |
||||
DINITROTOLUENE |
oily liquid |
250-300 |
54-93 |
182.14 |
insol |
1.3 |
6.28 |
0.13 |
207 cc |
||
2,4-DINITROTOLUENE |
crystals or oily liquid |
300 |
71 |
182.1 |
insol |
@ 71 ºC |
6.27 |
@ 103 ºC |
207 oc |
||
2,5-DINITROTOLUENE |
52.5 |
182.13 |
@ 111 |
||||||||
1-FLUORO-2,4-DINITROBENZENE |
pale yellow crystals from alcohol |
296 |
25.8 |
186.10 |
@ 84 ºC |
||||||
2-METHYL-1-NITROANTHRAQUINONE |
pale-yellow needles |
270.5 |
267.2 |
insol |
|||||||
N-METHYL-N-NITROSOANILINE |
225 |
14.7 |
136.15 |
insol |
1.1240 |
||||||
5-NITROACENAPHTHENE |
103.5 |
199.2 |
sol |
||||||||
NITROBENZENE |
greenish-yellow crystals or yellow, oily liquid |
210.8 |
5.7 |
123.11 |
sl sol |
1.2037 |
4.3 |
20 Pa |
1.8 ll |
88 cc |
480 |
4-NITRODIPHENYL |
yellow needles; white needles |
340 |
114 |
199.2 |
insol |
||||||
NITROFEN |
white solid; crystals; crystalline solid; yellow crystalline solid; free-flowing solid, dark brown color |
@ 0.25 mm Hg |
70-71 |
284.10 |
insol |
@ 90 ºC |
@ 40 ºC |
||||
5-NITRO-o-ANISIDINE |
orange-red needles from alc, ether, water |
118 |
168.2 |
sol |
@ 156 ºC |
@ 25 ºC |
|||||
1-NITRONAPHTHALENE |
yellow crystals |
304 |
61.5 |
173.2 |
insol |
1.332 |
@ 25 ºC |
164 cc |
|||
2-NITRONAPHTHALENE |
312.5 |
79 |
173.16 |
insol |
|||||||
o-NITROPHENOL |
light yellow needles or prisms; monoclinic |
216 |
44.8 |
139.1 |
sl sol |
@ 14 ºC |
@ 49.3 ºC |
||||
m-NITROPHENOL |
monoclinic prisms from ether & dilute hydrochloric acid; colourless to yellow monoclinic form |
@ 70 mm Hg |
97 |
139.1 |
sl sol |
@ 100 ºC/4 ºC |
0.75 torr |
||||
p-NITROPHENOL |
colourless to slightly yellow crystals;yellow monoclinic prisms from toluene; yellow to brown solid |
279 |
113.8 |
139.1 |
sl sol |
1.270 |
4.8 |
0.0032 Pa |
169 |
||
4-NITROPHENYLBENZANAMINE |
yellow needles or tablets from carbon tetrachloride |
@ 30 mm Hg |
133.5 |
214.23 |
insol |
7.4 |
|||||
2-NITRO-p-PHENYLENEDIAMINE |
almost black needles with dark-green luster |
137 |
153.1 |
sol |
|||||||
p-NITROSODIPHENYLAMINE |
green plates with bluish luster (from benzene) or steel-blue prisms or plates (from ether water); yellow liquid plates; greenish crystals |
143 |
198.2 |
sl sol |
|||||||
m-NITROTOLUENE |
yellow liquid |
232 |
15.5 |
137.1 |
insol |
1.1581 |
4.73 |
@ 25 ºC |
106 |
||
o-NITROTOLUENE |
yellowish liquid |
222 |
-10 |
137.13 |
insol |
1.1629 |
4.73 |
@ 50 ºC |
2.2 ll |
106 cc |
|
p-NITROTOLUENE |
yellowish crystals; colourless rhombic needles; orthorhombic crystals from alcohol & ether |
238.3 |
53-54 |
137.1 |
insol |
@ 75 /4 ºC |
4.72 |
@ 65 ºC |
106 |
||
PICRIC ACID |
yellow crystals |
300 |
122.5 |
229.1 |
sl sol |
1.763 |
7.90 |
< 1 torr |
150 |
300 |
|
TETRYL |
colourless to yellow, solid; monoclinic crystals; yellow prisms from alcohol |
187 |
131.5 |
287.15 |
insol |
1.57 |
<0.1 Pa |
187 |
|||
2,4,7-TRINITROFLUOREN-9-ONE |
pale yellow needles from acetic acid or benzene |
176 |
315.19 |
sl sol |
|||||||
2,4,6-TRINITROTOLUENE |
monoclinic rhombohedra; commercial crystals (needles) are yellow; colourless or light yellow solid in form of crystals, flakes, pellets, cast blocks & cast slabs; crushed flake |
240 |
80.1 |
227.13 |
insol |
1.654 |
7.85 |
<0.1 Pa |
Chemical Name |
Physical |
Chemical |
UN Class or Division / Subsidiary Risks |
1-AMINO-2-METHYL-5-NITROBENZENE |
6.1 |
||
1-CHLORO-2,4-DINITROBENZENE |
Heating may cause violent combustion or explosion at about 149 °C • May explode on heating under confinement or by shock • The substance decomposes on heating producing toxic gases (oxides of nitrogen, chlorine, hydrogen chloride, phosgene) • The substance is a strong oxidant and reacts with combustible and reducing materials • The substance is a strong reducing agent and reacts with oxidants • Reacts with strong oxidants and strong bases |
6.1 |
|
1-CHLORO-2-NITROBENZENE |
Dust explosion possible if in powder or granular form, mixed with air |
The substance decomposes on heating or on burning producing toxic and corrosive fumes (nitrogen oxides, chlorine, hydrogen chloride, phosgene) • Reacts violently with reducing materials, causing fire and explosion hazard |
6.1 |
1-CHLORO-3-NITROBENZENE |
6.1 |
||
1-CHLORO-4-NITROBENZENE |
The substance decomposes on heating producing toxic gases (nitrogen oxides, hydrochloric acid, phosgene and chlorine) • The substance is a strong oxidant and reacts violently with combustible and reducing materials • Reacts with many substances causing fire and explosion hazard |
||
2,3-DINITROTOLUENE |
Dust explosion possible if in powder or granular form, mixed with air |
May explode on heating • The substance decomposes on heating producing carbon monoxide and oxides of nitrogen • Reacts with strong bases, oxidants, and reducing agents |
6.1 |
2,6-DINITROTOLUENE |
Dust explosion possible if in powder or granular form, mixed with air |
May explode on heating • The substance decomposes on heating producing carbon monoxide and oxides of nitrogen • Reacts with strong bases, oxidants, and reducing agents |
6.1 |
3,4-DINITROTOLUENE |
Dust explosion possible if in powder or granular form, mixed with air |
May explode on heating • The substance decomposes on heating producing carbon monoxide and oxides of nitrogen • Reacts with strong bases, oxidants, and reducing agents |
6.1 |
DINITROBENZENE |
Dust explosion possible if in powder or granular form, mixed with air |
May explode on heating under confinement • On combustion, forms toxic gases and fumes • Reacts violently with strong oxidants, strong bases, and reducing agents, causing fire and explosion hazard • Mixtures with nitric acid are highly explosive! |
6.1 |
1,3-DINITROBENZENE |
Dust explosion possible if in powder or granular form, mixed with air |
May explode on heating under confinement • On combustion, forms toxic gases and fumes • Reacts violently with strong oxidants, strong bases, and reducing metals (tin and zinc), causing fire and explosion hazard • Mixtures with nitric acid are highly explosive! |
6.1 |
o-DINITROBENZENE |
Dust explosion possible if in powder or granular form, mixed with air |
May explode on heating under confinement • On combustion, forms toxic gases and fumes • Reacts violently with strong oxidants, strong bases, and reducing metals, eg, zinc and tin, fire and explosion hazard • Mixtures with nitric acid are highly explosive! |
6.1 |
p-DINITROBENZENE |
Dust explosion possible if in powder or granular form, mixed with air |
May explode on heating under confinement • On combustion, forms toxic gases and fumes • Reacts violently with strong oxidants, strong bases, and metals eg, tin and zinc, causing fire and explosion hazard • Mixtures with nitric acid are highly explosive! |
6.1 |
2,4-DINITROPHENOL |
Dust explosion possible if in powder or granular form, mixed with air |
May explosively decompose on shock, friction, or concussion • May explode on heating |
|
DINITROTOLUENE |
The vapour is heavier than air • Dust explosion possible if in powder or granular form, mixed with air |
The substance can form explosive peroxides • May explode on heating or exposure to flames • The substance decomposes on heating producing toxic gases and fumes (carbon monoxide and oxides of nitrogen) • Reacts violently with strong oxidants causing fire and explosion hazard • Reacts with strong bases and metals such as tin and zinc and may cause evolution of heat and increase in pressure • Attacks some forms of plastics, rubber, and coatings |
6.1 |
2,4-DINITROTOLUENE |
Dust explosion possible if in powder or granular form, mixed with air |
May explode on heating • The substance decomposes on heating producing carbon monoxide and oxides of nitrogen • Reacts with strong bases, oxidants, and reducing agents |
6.1 |
5-NITRO-o-ANISIDINE |
6.1 |
||
NITROBENZENE |
On combustion, forms corrosive fumes including nitrogen oxides • Reacts violently with strong oxidants and reducing agents, causing fire and explosion hazard • Attacks many plastics • Forms explosive (thermally unstable) substances or mixtures with many organic and inorganic compounds like oxidants, aluminium chloride with phenol, potassium hydroxide anhydrous or with small amounts of methanol, aniline with glycerol, phosphoruspentachloride, nitric acid, sulphuric acid, potassium |
6.1 |
|
4-NITRODIPHENYLAMINE |
The substance decomposes on heating or on burning producing toxic fumes (nitrogen oxides) • Reacts with strong oxidantsIncompatibility: strong oxidizing agents and strong bases |
||
1-NITRONAPHTHALENE |
4.1 |
||
o-NITROPHENOL |
6.1 |
||
m-NITROPHENOL |
6.1 |
||
p-NITROPHENOL |
Dust explosion possible if in powder or granular form, mixed with air |
May explode on heating • The substance decomposes on heating or on burning producing toxic fumes including nitrogen oxides, causing fire and explosion hazard • The substance is a strong oxidant and reacts violently with combustible and reducing materials • Mixtures with potassium hydroxide are explosive |
6.1 |
o-NITROTOLUENE |
The substance decomposes on contact with strong oxidants, sulfuric acid, reducing agents, acids or bases producing toxic fumes, causing fire and explosion hazard • Attacks some forms of plastics, rubber, and coatings |
6.1 |
|
m-NITROTOLUENE |
6.1 |
||
p-NITROTOLUENE |
The substance decomposes on heating producing toxic fumes (nitrogen oxides) • Reacts violently with strong oxidizers or sulfuric acid causing fire and explosion hazard • Attacks some forms of plastics, rubber and coatings |
6.1 |
|
PICRIC ACID |
May explosively decompose on shock, friction, or concussion • May explode on heating • Shock-sensitive compounds are formed with metals, particularly copper, lead, mercury and zinc • On combustion, forms toxic carbon and nitrogen oxides • Reacts vigorously with oxidants and reducing materials |
1.1D |
|
TETRYL |
Dust explosion possible if in powder or granular form, mixed with air |
May explosively decompose on shock, friction, or concussion • The substance decomposes explosively on heating to 187 °C • Contact of tetryl with some oxidizable materials may cause fire and explosions • Detonates spontaneously on contact with trioxygendifluoride • T gases and vapours (such as nitrogen oxides) may be released on burning/exploding |
1.1D |
2,4,6-TRINITROTOLUENE |
May explosively decompose on shock, friction, or concussion • Upon heating, toxic fumes are formed • Reacts violently with reducing agents causing fire and explosion hazard • Reacts with heavy metals • Explodes on heating to 240 °C |
1.1D |
For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance
Chemical Name CAS-Number |
ICSC Short-Term Exposure |
ICSC Long-Term Exposure |
ICSC Routes of Exposure and Symptoms |
US NIOSH Target Organs & Routes of Entry |
US NIOSH Symptoms |
1-CHLORO-2,4-DINITROBENZENE 97-00-7 |
eyes; skin; resp tract |
skin; eyes |
Inhalation: blue lips or finger nails, blue skin, dizziness, headache, laboured breathing, nausea, vomiting, disturbed vision Skin: may be absorbed, redness, pain Eyes: redness, pain Ingestion: abdominal pain, blue skin, dizziness, headache, laboured breathing, nausea, vomiting |
||
1-CHLORO-2-NITROBENZENE 88-73-3 |
eyes; skin; resp tract; blood |
blood; liver; kidneys; spleen |
Inhalation: blue lips or finger nails, blue skin, dizziness, headache, nausea, shortness of breath Skin: may be absorbed, redness Eyes: redness, pain |
||
1-CHLORO-4-NITROBENZENE 100-00-5 |
blood |
skin; blood |
Inhalation: headache, faintness, vertigo, weakness Skin: may be absorbed |
Blood; liver; kidneys; CVS; spleen; bone marrow; repro sys (in animals: vascular & liver tumors) Inh; abs; ing; con |
Anoxia; unpleasant taste; anemia; methemo; in animals: hema, hemog; spleen, kidney, bone marrow changes; repro effects; (carc) |
1,2-DICHLORO-3-NITROBENZENE 3209-22-1 |
blood |
skin; liver; kidneys |
Inhalation: blue lips or finger nails Skin: may be absorbed, redness, blue lips, blue fingernails Ingestion: blue lips or fingernails, blue skin, confusion, headache, vomiting, weakness |
||
1,2-DICHLORO-4-NITROBENZENE 99-54-7 |
eyes; skin; resp tract; lungs |
skin; kidneys; liver |
Inhalation: blue lips or finger nails, burning sensation of the throat, headache, shortness of breath Skin: may be absorbed, redness, burning sensation, pain, blue lips or fingernails Eyes: redness, pain Ingestion: blue lips or fingernails |
||
2,4-DICHLORO-1-NITROBENZENE 611-06-3 |
blood |
liver; kidneys |
Inhalation: blue lips or finger nails Skin: may be absorbed, redness, blue lips, blue fingernails Eyes: redness Ingestion: blue lips or fingernails, blue skin, confusion, headache, vomiting, weakness |
||
1,3-DINITROBENZENE 99-65-0 |
eyes; skin; resp tract |
liver; may impair male fertility |
Inhalation: blue lips or finger nails, blue skin, dizziness, headache, laboured breathing, weakness, burning sensation in the mouth, dry throat, thirst, disturbed vision Skin: may be absorbed, redness, skin burns, yellowing of skin Eyes: redness, burns Ingestion: abdominal pain, blue skin, diarrhoea, dizziness, headache, laboured breathing, nausea, vomiting |
Blood; liver; CVS; eyes; CNS; skin Inh; abs; ing; con |
Anoxia, cyan; vis dist, central scotomas; bad taste, burning mouth, dry throat, thirst; yellowing hair, skin; anemia; liver damage |
DINITROBENZENE 25154-54-5 |
eyes; skin; resp tract; lungs; blood |
liver; may impair male fertility |
Inhalation: blue lips or finger nails, blue skin, burning sensation, dizziness, headache, laboured breathing, sore throat, weakness, disturbed vision Skin: may be absorbed, redness, yellowing of skin Eyes: redness Ingestion: abdominal pain, blue skin, diarrhoea, dizziness, headache, laboured breathing, nausea, vomiting |
||
o-DINITROBENZENE 528-29-0 |
eyes; skin; resp tract; lungs; blood |
liver |
Inhalation: blue lips or finger nails, blue skin, burning sensation, dizziness, headache, laboured breathing, weakness, disturbed vision Skin: may be absorbed Eyes: redness Ingestion: Abdominal pain, blue skin, diarrhoea, dizziness, headache, laboured breathing, nausea, vomiting |
Blood; liver; CVS; eyes; CNS; skin Inh; abs; ing; con |
Anoxia, cyan; vis dist, central scotomas; bad taste, burning mouth, dry throat, thirst; yellowing hair, skin; anemia; liver damage |
p-DINITROBENZENE 100-25-4 |
eyes; skin; resp tract |
Inhalation: blue lips or finger nails, blue skin, dizziness, headache, laboured breathing, weakness, burning sensation in the mouth, dry throat, thirst, disturbed vision Skin: may be absorbed, redness, yellowing of skin Eyes: redness, burns Ingestion: abdominal pain, blue skin, diarrhoea, dizziness, headache, laboured breathing, nausea, vomiting |
Blood; liver; CVS; eyes; CNS; skin Inh; abs; ing; con |
Anoxia, cyan; vis dist, central scotomas; bad taste, burning mouth, dry throat, thirst; yellowing hair, skin; anemia; liver damage |
|
2,4-DINITROPHENOL 51-28-5 |
GI tract |
skin; CNS; blood; eyes; |
Inhalation: sweating, palpitations, nausea, vomiting, collapse and death Skin: may be absorbed |
||
DINITROTOLUENE 25321-14-6 |
blood |
liver; male and female fertility |
Inhalation: drowsiness, nausea, vomiting, weakness Skin: may be absorbed, blue lips or fingernails, blue skin, methemoglobin skin |
Blood; liver; CVS; repro sys (in animals: liver, skin & kidney tumors) Inh; abs; ing; con |
Anoxia, cyan; anemia, jaun; repro effects (carc) |
2,3-DINITROTOLUENE 602-01-7 |
CNS; CVS; blood |
Skin: may be absorbed Ingestion: blue lips or fingernails; headache, nausea, sore throat; vomiting |
|||
2,4-DINITROTOLUENE 121-14-2 |
CNS; CVS; blood |
Inhalation: blue lips or fingernails, headache, nausea, sore throat, vomiting Skin: may be absorbed Ingestion: blue lips or fingernails, headache, nausea, sore throat, vomiting |
|||
2,6-DINITROTOLUENE 606-20-2 |
blood |
possibly carcinogenic to humans |
Inhalation: blue lips or finger nails, blue skin, diarrhoea, dizziness, drowsiness Skin: may be absorbed |
||
3,4-DINITROTOLUENE 610-39-9 |
CNS; CVS; blood; |
Skin: may be absorbed Ingestion: blue lips or fingernails, headache, nausea, sore throat, vomiting |
|||
NITROBENZENE 98-95-3 |
eyes; blood; CNS |
skin; blood; liver; CNS; spleen; may impair male fertility |
Inhalation: blue lips or finger nails, blue skin, dizziness, headache, nausea, unconsciousness, weakness Skin: may be absorbed |
Blood; liver; kidneys; CVS; skin; eyes; repro sys Inh; abs; ing; con |
Irrit eyes, skin, anoxia; derm; anemia; methemo; in animals: liver, kidney damage; testicular effects |
4-NITRODIPHENYLAMINE 836-30-6 |
eyes; skin; resp tract; blood; brain |
blood |
Inhalation: burning sensation, cough, sore throat, see ingestion Skin: see ingestion Eyes: redness, pain Ingestion: blue lips or fingernails, blue skin, dizziness, headache, laboured breathing |
||
NITROFEN 1836-75-5 |
eyes; skin; resp tract |
skin; blood; CNS; human reproduction system |
Inhalation: cough, laboured breathing, sore throat Skin: redness, pain Eyes: redness, pain, blurred vision Ingestion: abdominal pain |
||
o-NITROTOLUENE 88-72-2 |
eyes; skin; resp tract; blood |
liver; blood |
Inhalation: blue lips or finger nails, blue skin, cough, dizziness, headache, laboured breathing, sore throat Skin: may be absorbed, redness, pain Eyes: redness, pain Ingestion: abdominal pain, blue lips or fingernails, blue skin, dizziness, headache, laboured breathing |
Blood; CNS; CVS; skin; GI tract Inh; abs; ing; con |
Anoxia, cyan; head, weak, dizz; ataxia; dysp; tacar; nau, vomit |
p-NITROPHENOL 100-02-7 |
eyes; skin; resp tract; CNS; blood; kidneys |
CNS; liver; kidneys; blood; |
Inhalation: blue skin, dizziness, headache, fever, nausea, shortness of breath, weakness, perspiration Skin: may be absorbed, redness, scabs Eyes: redness, pain Ingestion: burning pain in mouth and throat, abdominal pain, dizziness, unconsciousness |
||
p-NITROTOLUENE 99-99-0 |
eyes; skin; resp tract |
liver; kidneys |
Inhalation: blue lips or finger nails, blue skin, cough, dizziness, headache, laboured breathing, sore throat Skin: may be absorbed, redness, pain Eyes: redness, pain Ingestion: abdominal pain, blue lips or fingernails, blue skin, dizziness, headache, laboured breathing, sore throat, unconsciousness |
Blood; CNS; CVS; skin; GI tract Inh; abs; ing; con |
Anoxia, cyan; head, weak, dizz; ataxia; dysp; tacar; nau, vomit |
PICRIC ACID 88-89-1 |
eyes; skin |
skin |
Inhalation: cough, sore throat, weakness Skin: may be absorbed, redness Eyes: redness, pain Ingestion: diarrhoea, dizziness, headache, nausea, vomiting |
Kidneys; liver; blood; skin; eyes Inh; abs; ing; con |
Irrit eyes, skin; sens derm; yellow-stained hair, skin; weak, myalgia, anuria, polyuria; bitter taste, GI dist; hepatitis, hema, album, neph |
TETRYL 479-45-8 |
eyes; skin; resp tract; kidneys; liver; blood |
skin |
Inhalation: sleeplessness, cough, headache, sore throat, nosebleeds Skin: redness, yellow stains of skin and hair Eyes: redness, pain Ingestion: abdominal pain, dizziness, headache, nausea |
Resp sys; eyes; CNS; skin; liver; kidneys Inh; abs; ing; con |
Sens derm, itch, eryt; edema on nasal folds, cheeks, neck; kera; sneez; anemia; ftg; cough, coryza; irrity; mal, head, lass, insom; nau, vomit; liver, kidney damage |
2,4,6-TRINITROTOLUENE 118-96-7 |
eyes; skin; resp tract; blood |
liver; blood; eyes |
Eyes: redness, pain |
Blood; liver; eyes; CVS; CNS; kidneys; skin; resp sys Inh; abs; ing; con |
Irrit skin, muc memb; liver damage, jaun; cyan; sneez; cough, sore throat; peri neur, musc pain; kidney damage; cataract; sens derm; leucyt; anemia; card irreg |
Chemical Formula |
Chemical |
Synonyms; |
CAS-Number |
99558 |
1-AMINO-2-METHYL-5-NITROBENZENE |
2-Amino-4-nitrotoluene; |
99-55-8 |
119346 |
4-AMINO-2-NITROPHENOL |
4-Hydroxy-3-nitroaniline; |
119-34-6 |
97007 |
1-CHLORO-2,4-DINITROBENZENE |
4-Chloro-1,3-dinitrobenzene; |
97-00-7 |
88733 |
1-CHLORO-2-NITROBENZENE |
Chloro-o-nitrobenzene; |
88-73-3 |
121733 |
1-CHLORO-3-NITROBENZENE |
Chloro-m-nitrobenzene; |
121-73-3 |
100005 |
1-CHLORO-4-NITROBENZENE |
p-Chloronitrobenzene; |
100-00-5 |
3209221 |
1,2-DICHLORO-3-NITROBENZENE |
2,3-Dichloronitrobenzene |
3209-22-1 |
99547 |
1,2-DICHLORO-4-NITROBENZENE |
3,4-Dichloronitrobenzene |
99-54-7 |
611063 |
2,4-DICHLORO-1-NITROBENZENE |
2,4-Dichloronitrobenzene |
611-06-3 |
35572782 |
3,5-DINITRO-o-TOLUIDINE |
2-Amino-4,6-dinitrotoluene; |
35572-78-2 |
19406510 |
3,5-DINITRO-p-TOLUIDINE |
Amino-2,6-dinitrotoluene; |
19406-51-0 |
25154545 |
DINITROBENZENE |
UN1597 |
25154-54-5 |
528290 |
o-DINITROBENZENE |
1,2-Dinitrobenzene |
528-29-0 |
99650 |
m-DINITROBENZENE |
1,3-Dinitrobenzene; |
99-65-0 |
100254 |
p-DINITROBENZENE |
UN1597 |
100-25-4 |
99332 |
3,5-DINITROBENZOYL CHLORIDE |
3,5-Dinitrobenzoic acid chloride |
99-33-2 |
27478348 |
DINITRONAPHTHALENE |
27478-34-8 |
|
605710 |
1,5-DINITRONAPHTHALENE |
605-71-0 |
|
75321209 |
1,3-DINITROPYRENE |
75321-20-9 |
|
42397648 |
1,6-DINITROPYRENE |
42397-64-8 |
|
66568 |
2,3-DINITROPHENOL |
66-56-8 |
|
51285 |
2,4-DINITROPHENOL |
2,4-DNP; |
51-28-5 |
42397659 |
1,8-DINITROPYRENE |
42397-65-9 |
|
25321146 |
DINITROTOLUENE |
Dinitrophenylmethane; |
25321-14-6 |
602017 |
2,3-DINITROTOLUENE |
1-Methyl-2,3-dinitrobenzene |
602-01-7 |
121142 |
2,4-DINITROTOLUENE |
Dinitrotoluene; |
121-14-2 |
619158 |
2,5-DINITROTOLUENE |
2-Methyl-1,4-dinitrobenzene |
619-15-8 |
606202 |
2,6-DINITROTOLUENE |
2-Methyl-1,3-dinitrobenzene |
606-20-2 |
610399 |
3,4-DINITROTOLUENE |
4-Methyl-1,2-dinitrobenzene |
610-39-9 |
70348 |
1-FLUORO-2,4-DINITROBENZENE |
2,4-Dinitrofluorobenzene; |
70-34-8 |
6393426 |
4-METHYL-2,6-DINITROANILINE |
4-Amino-3,5-Dinitrotoluene; |
6393-42-6 |
129157 |
2-METHYL-1-NITROANTHRAQUINONE |
2-Methyl-1-nitro-9,10-anthracenedione; |
129-15-7 |
614006 |
N-METHYL-N-NITROSOANILINE |
Methylnitrosoaniline; |
614-00-6 |
602879 |
5-NITROACENAPHTHENE |
1,2-Dihydro-5-nitro-acenaphthylene; |
602-87-9 |
98953 |
NITROBENZENE |
Nitrobenzene; |
98-95-3 |
92933 |
4-NITRODIPHENYL |
4-Nitrobiphenyl; |
92-93-3 |
836306 |
4-NITRODIPHENYLAMINE |
Benzenamine, 4-Nitro-N-phenyl-; |
836-30-6 |
5307142 |
2-NITRO-p-PHENYLENEDIAMINE |
4-Amino-2-nitroaniline; |
5307-14-2 |
1836755 |
NITROFEN |
2',4'-Dichloro-4-nitrobiphenyl ether; |
1836-75-5 |
86577 |
1-NITRONAPHTHALENE |
a-Nitronaphthalene |
86-57-7 |
581895 |
2-NITRONAPHTHALENE |
b-Nitronaphthalene |
581-89-5 |
99592 |
5-NITRO-o-ANISIDINE |
2-Amino-1-methoxy-4-nitrobenzene; |
99-59-2 |
88755 |
o-NITROPHENOL |
2-Hydroxynitrobenzene; |
88-75-5 |
554847 |
m-NITROPHENOL |
m-Hydroxynitrobenzene; |
554-84-7 |
100027 |
p-NITROPHENOL |
4-Hydroxynitrobenzene; |
100-02-7 |
5522430 |
1-NITROPYRENE |
3-Nitropyrene |
5522-43-0 |
156105 |
p-NITROSODIPHENYLAMINE |
4-Nitrosodiphenylamine; |
156-10-5 |
88722 |
o-NITROTOLUENE |
o-Methylnitrobenzene; |
88-72-2 |
99081 |
m-NITROTOLUENE |
3-Methylnitrobenzene; |
99-08-1 |
99990 |
p-NITROTOLUENE |
p-Methylnitrobenzene; |
99-99-0 |
88891 |
PICRIC ACID |
2-Hydroxy-1,3,5-trinitrobenzene; |
88-89-1 |
479458 |
TETRYL |
N-Methyl-N,2,4,6-tetranitroaniline; |
479-45-8 |
129793 |
2,4,7-TRINITROFLUOREN-9-ONE |
2,4,7-Trinitro-9-fluorenone |
129-79-3 |
75321196 |
1,3,6-TRINITROPYRENE |
75321-19-6 |
|
118967 |
2,4,6-TRINITROTOLUENE |
2-Methyl-1,3,5-trinitrobenzene; |
118-96-7 |
Chemical Name |
Colour/Form |
Boiling Point (°C) |
Melting Point (°C) |
Molecular Weight |
Solubility in Water |
Relative Density (water=1) |
Relative Vapour Density (air=1) |
Vapour Pressure/ (Kpa) |
Inflam. |
Flash Point (ºC) |
Auto Ignition Point (º C) |
AMYL NITRITE |
yellowish, transparent liquid |
99 |
117.1 |
sl sol |
0.8828 |
4.0 |
|||||
1-CHLORO-1-NITROETHANE |
124.5 |
109.51 |
insol |
1.2837 |
|||||||
2-CHLORO-2-NITROPROPANE |
liquid |
133.6 |
123.55 |
@ 20 ° C |
@ 20 ° C/20 ° C |
4.3 |
@ 25 ° C |
57 ° C oc |
|||
1-CHLORO-1-NITROPROPANE |
liquid |
143 |
123.54 |
0.5ml/100 ml |
1.209 |
0.3 |
@ 25 ºC |
62 oc |
|||
CHLOROPICRIN |
slightly oily liquid; colourless; faint yellow liquid. |
112 |
-69.2 |
164.4 |
sol |
1.6558 |
5.7 |
@ 0 º C |
|||
1,1-DICHLORO-1-NITROETHANE |
colourless liquid |
124 |
143.9 |
0.25 ml/100 ml |
1.4271 |
5.0 |
@ 25 ºC |
76 oc |
|||
DIETHYLENE GLYCOL DINITRATE |
liquid |
161 |
-11.6 |
sl sol |
@ 25 ºC |
||||||
ETHYLENE GLYCOL DINITRATE |
yellowish, oily liquid; colourless |
197-200 |
-22.3 |
152.06 |
insol |
1.4918 |
5.24 |
7 Pa |
215 cc |
114 |
|
ETHYLENE GLYCOL DINITRATE mixed with NITROGLYCERIN (1:1) |
pale yellow, viscous liquid |
197-200 |
-22.3 |
152.06 |
sl sol |
1.4978 |
218 |
||||
ETHYL NITRATE |
colourless liquid |
87.2 ° C at 762 mm Hg |
94.6 ° C |
91.07 |
@ 55 ° C |
1.1084 at 20 ° C/4 ° C |
3.1 |
lower, 4.0% by vol |
10 |
||
ETHYL NITRITE |
colourless or yellowish, clear liquid |
17 |
-50 |
75.07 |
slightly sol |
@ 15 ° C/15 ° C |
2.6 |
4.0% ll 50.0% ul by volume in air |
-35 ° C |
90 (decomposes) |
|
NITRILOTRIACETIC ACID |
prismatic crystals from hot water; white crystalline powder |
242 |
191.1 |
sl sol |
> 1 |
||||||
NITROETHANE |
oily liquid; colourless liquid |
114 |
-50 |
75.07 |
sl sol |
@ 25 ºC/4 ºC |
2.58 |
2.08 |
4.0 ll |
28 |
414 |
NITROGLYCERIN |
pale yellow triclinic or rhombic crystals below melting point; viscous liquid; pale-yellow, oily liquid |
260 |
13 |
227.1 |
sl sol |
1.5931 |
7.8 |
0.0025 mm Hg |
270 |
||
NITROMETHANE |
colourless liquid; oily liquid |
101.1 |
-29 |
61.04 |
sol |
1.14 |
2.11 |
3.5 |
7.3 ll |
35 cc |
417 |
1-NITROPROPANE |
colourless liquid |
131.6 |
-108 |
89.09 |
sl sol |
@ 25 ºC/4 ºC |
3.1 |
7.5 mm Hg |
2.2 |
34 |
|
2-NITROPROPANE |
colourless liquid |
120 |
-93 |
89.09 |
sl sol |
@ 25 ºC/4 ºC |
3.06 |
@ 25 ºC |
2.6 ll |
24 cc |
428 |
PENTAERYTHRITOL TETRANITRATE |
white crystalline; prisms (acetone-alcohol) |
@ 50 mm Hg |
140 |
316.1 |
sl sol |
1.773 |
|||||
PROPYL NITRATE |
110 |
105.09 |
sl sol |
1.0538 |
|||||||
1,2-PROPYLENE GLYCOL DINITRATE |
colourless liquid |
121 |
-27.7 |
166.09 |
sol |
0.9234 |
361 |
||||
TETRANITROMETHANE |
pale yellow liquid; colourless oily fluid |
126 |
13.8 |
196.0 |
insol |
1.6229 |
0.8 |
@ 25 ºC |
Chemical Name |
Physical |
Chemical |
UN Class or Division / Subsidiary Risks |
ETHYLENE GLYCOL DINITRATE |
Heating may cause violent combustion or explosion producing toxic fumes (nitrogen oxides) • May explosively decompose on shock, friction, or concussion • Reacts with acids |
||
NITROETHANE |
Heating may cause violent combustion or explosion • May explode on heating rapidly to high temperature • Shock-sensitive compounds are formed with strong alkalies, acids or combination of amines and heavy metal oxides • On combustion, forms toxic gases (nitrogen dioxide) • The substance decomposes on heating above 300°C producing toxic fumes (nitrogen oxides) • The substance is a strong reducing agent and reacts with oxidants • May attack some forms of plastic |
3 |
|
NITROMETHANE |
The vapour is heavier than air and may travel along the ground; distant ignition possible |
May explosively decompose on shock, friction, or concussion • May explode on heating • The substance decomposes on heating producing nitrogen oxides • Reacts with alkalis causing compound formation which when dry pose explosion hazard • Forms shock sensitive mixture with amines |
3 |
PENTAERYTHRITOL TETRANITRATE |
1.1D |
For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance
Chemical Name CAS-Number |
ICSC Short-Term Exposure |
ICSC Long-Term Exposure |
ICSC Routes of Exposure and Symptoms |
US NIOSH Target Organs & Routes of Entry |
US NIOSH Symptoms |
ETHYLENE GLYCOL DINITRATE 628-96-6 |
CVS |
CVS |
Inhalation: dizziness, headache, nausea, weakness, symptoms may be delayed Skin: may be absorbed |
CVS; blood; skin; liver; kidneys Inh, abs, ing, con |
Throb head; dizz; nau, vomit, abdom pain; hypotension, flush, palp, angina; methemo; delirium, CNS depres; irrit skin; in animals: anemia; liver, kidney damage |
NITROETHANE 79-24-3 |
eyes; skin; resp tract |
Inhalation: cough, headache Skin: redness Eyes: redness Ingestion: abdominal pain, sore throat |
Skin; resp sys; CNS; kidneys; liver Inh, ing, con |
Derm; in animals: lac; dysp, pulm rales, edema; liver, kidney inj; narco |
|
NITROMETHANE 75-52-5 |
CNS |
skin; kidneys; liver |
Inhalation: cough, dizziness, headache, nausea, unconsciousness, vomiting Skin: dry skin Eyes: redness |
Eyes; skin; CNS; liver Inh, ing, con |
Derm; in animals: irrit eyes, resp sys; convuls, narco; liver damage |
Chemical Formula |
Chemical |
Synonyms |
CAS-Number |
110463 |
AMYL NITRITE |
Isoamyl nitrite; |
110-46-3 |
598925 |
1-CHLORO-1-NITROETHANE |
598-92-5 |
|
600259 |
1-CHLORO-1-NITROPROPANE |
Chloronitropropane |
600-25-9 |
594718 |
2-CHLORO-2-NITROPROPANE |
Ethyl nitrite; |
594-71-8 |
76062 |
CHLOROPICRIN |
Nitrochloroform; |
76-06-2 |
594729 |
1,1-DICHLORO-1-NITROETHANE |
Dichloronitroethane |
594-72-9 |
693210 |
DIETHYLENE GLYCOL DINITRATE |
Di(hydroxyethyl) ether dinitrate |
693-21-0 |
625581 |
ETHYL NITRATE |
Nitric acid, propyl ester; |
625-58-1 |
109955 |
ETHYL NITRITE |
Nitric acid, propyl ester; |
109-95-5 |
628966 |
ETHYLENE GLYCOL DINITRATE |
Dinitroglycol; |
628-96-6 |
53569645 |
ETHYLENE GLYCOL DINITRATE mixed with NITROGLYCERIN (1:1) |
53569-64-5 |
|
110463 |
AMYL NITRITE |
Isoamyl nitrite; |
110-46-3 |
139139 |
NITRILOTRIACETIC ACID |
Aminotriacetic acid; |
139-13-9 |
79243 |
NITROETHANE |
UN2842 |
79-24-3 |
55630 |
NITROGLYCERIN |
Glycerol trinitrate; |
55-63-0 |
75525 |
NITROMETHANE |
Nitrocarbol |
75-52-5 |
108032 |
1-NITROPROPANE |
108-03-2 |
|
79469 |
2-NITROPROPANE |
Dimethylnitromethane; |
79-46-9 |
78115 |
PENTAERYTHRITOL TETRANITRATE |
2,2-Bis((nitrooxy)methyl)-1,3-Propanediol dinitrate (ester); |
78-11-5 |
627134 |
PROPYL NITRATE |
Nitric acid, propyl ester; |
627-13-4 |
6423434 |
1,2-PROPYLENE GLYCOL DINITRATE |
Propylene dinitrate; |
6423-43-4 |
509148 |
TETRANITROMETHANE |
UN1510 |
509-14-8 |
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