Table 4. List of technical products classified in Class III: "Slightly hazardous"
Name |
Status |
Main use |
Chemical type |
Physical state |
Route |
LD50 (mg/kg) |
Remarks |
Acephate |
ISO |
I |
OP |
S |
O |
945 |
|
Acetochlor |
ISO |
H |
L |
O |
2,950 |
||
Acifluorfen |
ISO |
H |
S |
O |
1,370 |
Strong irritant to eyes |
|
Allethrin |
ISO |
I |
PY |
oil |
O |
c685 |
EHC 87; HSG 24 |
Ametryn |
ISO |
H |
T |
S |
O |
1,110 |
|
Amitraz |
ISO |
AC |
S |
O |
800 |
||
Azamethiphos |
ISO |
I |
OP |
S |
O |
1,010 |
|
Azidithion |
N(F) |
See menazon |
|||||
Barban |
ISO |
H |
S |
O |
1,300 |
||
Bensultap |
ISO |
I |
S |
O |
1,100 |
||
Bentazone |
ISO |
H |
S |
O |
1,100 |
||
Benzoylprop-ethyl |
(ISO) |
H |
S |
O |
1,555 |
||
Benzthiazuron |
ISO |
H |
S |
O |
1,280 |
||
Bromofenoxim |
ISO |
H |
S |
O |
1,217 |
||
Bromophos |
ISO |
I |
OP |
S |
O |
c1,600 |
DS 76 |
Buthidazole |
ISO |
H |
S |
O |
1,480 |
||
Cacodylic acid |
See dimethylarsinic acid |
||||||
Carbofos |
N(U) |
See malathion |
|||||
Chlorfenac |
ISO |
H |
OC |
S |
O |
575 |
|
Chlorfenethol |
ISO |
AC |
OC |
S |
O |
930 |
|
Chlorfenson |
ISO |
AC |
OC |
S |
O |
c2,000 |
Irritant to skin |
Chlorinat |
N(U) |
See barban |
|||||
Chlormequat (chloride) |
ISO |
PGR |
S |
O |
670 |
||
Chloroacetic acid |
C |
H |
S |
O |
650 |
Irritant to skin and eyes; data refer to sodium salt |
|
Chlorobenzilate |
ISO |
AC |
OC |
S |
O |
700 |
|
Chlorocholine chloride |
C |
See chlormequat |
|||||
Chlorthiamid |
ISO |
H |
S |
O |
757 |
||
Cismethrin |
ISO |
Resmethrin is a mixture of isomers, the trans isomer (70-80%) being also known as bioresmethrin and the cis isomer (20-30%) as cismethrin. Bioresmethrin (see table 62.5) alone is of much lower toxicity (oral LD50 9,000 mg/kg) (DS 34) |
|||||
Citrex |
N(U) |
See dodine |
|||||
Clofop |
ISO |
H |
L |
O |
1,208 |
||
Copper hydroxide |
C |
F |
S |
O |
1,000 |
||
Copper oxychloride |
C |
F |
S |
O |
1,440 |
||
4-CPA |
ISO |
PGR |
S |
O |
850 |
||
Crufomate |
ISO |
I |
OP |
S |
O |
770 |
|
Cycloate |
ISO |
H |
TC |
L |
O |
+2,000 |
|
Cyhexatin |
ISO |
AC |
OT |
S |
O |
540 |
|
Cymoxanil |
ISO |
F |
S |
O |
1,196 |
||
Cyproconazole |
N(B) |
F |
S |
O |
1,020 |
||
Dazomet |
ISO |
F-S |
S |
O |
640 |
Irritant to skin and eyes |
|
2,4-DB |
N(B) |
H |
S |
O |
700 |
||
DCBN |
N(J) |
See chlorthiamid |
|||||
Deet |
See diethyltoluamide |
||||||
Dehydroacetic acid |
C |
F |
S |
O |
1,000 |
||
2,4-DES |
N(B,U) |
See disul |
|||||
Desmetryn |
ISO |
H |
T |
S |
O |
1,390 |
|
Diallyl dichloroacetamide |
See dichlormid |
||||||
Dicamba |
ISO |
H |
S |
O |
1,707 |
||
Dichlone |
ISO |
FST |
S |
O |
1,300 |
||
Dichlormid |
N(A) |
H |
L |
O |
2,080 |
||
Dichlorobenzene |
C |
FM |
S |
O |
500-5,000 |
Mixture of isomers |
|
Dichlorophen |
ISO |
F |
OC |
S |
O |
1,250 |
|
Dichlorprop |
ISO |
H |
S |
O |
800 |
||
Diclofop |
ISO |
H |
S |
O |
565 |
||
Dicofol |
ISO |
AC |
S |
O |
c690 |
DS 81 |
|
Dienochlor |
ISO |
AC |
S |
O |
3,160 |
Acutely toxic by inhalation; skin sensitizer |
|
Diethyltoluamide |
ISO |
RP (insect) |
L |
O |
c2,000 |
DS 80 |
|
Difenoconazole |
ISO |
F |
T |
S |
O |
1,453 |
|
Dimepiperate |
ISO |
H |
TC |
S |
O |
946 |
|
Dimethachlor |
ISO |
H |
S |
O |
1,600 |
||
Dimethametryn |
ISO |
H |
T |
L |
O |
3,000 |
|
Dimethipin |
ISO |
H |
S |
O |
1,180 |
||
Dimethylarsinic acid |
C |
H |
S |
O |
1,350 |
||
Diniconazole |
ISO |
F |
S |
O |
639 |
||
Dinocap |
ISO |
AC,F |
CNP |
S |
O |
980 |
|
Diphenamid |
ISO |
H |
S |
O |
970 |
||
Disul |
ISO |
H |
S |
O |
730 |
||
Dithianon |
ISO |
F |
S |
O |
640 |
||
2,4-DP |
N(U) |
See dichlorprop |
|||||
Dodine |
ISO |
F |
S |
O |
1,000 |
||
Doguadine |
N(F) |
See dodine |
|||||
DSMA |
See methylarsonic acid |
||||||
Empenthrin ((1R) isomers) |
ISO |
I |
PY |
oil |
O |
+2,280 |
|
Ephirsulphonate |
N(U) |
See chlorfenson |
|||||
Esprocarb |
ISO |
H |
TC |
L |
O |
+2,000 |
Skin and eye irritant |
Etacelasil |
ISO |
PGR |
L |
O |
2,065 |
||
Etaconazole |
ISO |
F |
S |
O |
1,340 |
||
Ethohexadiol |
N(A) |
RP (insect) |
L |
O |
2,400 |
||
Etridiazole |
ISO |
F |
L |
O |
2,000 |
||
Fenoprop |
ISO |
H |
S |
O |
650 |
||
Fenson |
ISO |
AC |
S |
O |
1,550 |
||
Fenothiocarb |
ISO |
L |
C |
S |
O |
1,150 |
|
Fenpropidin |
ISO |
F |
S |
O |
1,440 |
||
Fenthiaprop |
N(B) |
H |
S |
O |
915 |
||
Ferimzone |
ISO |
F |
S |
O |
725 |
||
Flamprop |
ISO |
H |
S |
O |
1,210 |
||
Fluchloralin |
ISO |
H |
S |
O |
1,550 |
||
Fluoroglycofen |
N(B) |
H |
S |
O |
1,500 |
||
Flurprimidol |
ISO |
PGR |
S |
O |
709 |
||
Flusilazole |
N(B) |
F |
S |
O |
1,110 |
||
Flutriafol |
ISO |
F,FST |
T |
S |
O |
1,140 |
|
Fomesafen |
ISO |
H |
OC |
S |
O |
1,250 |
|
Fuberidazole |
ISO |
F |
S |
O |
1,100 |
||
Furalaxyl |
ISO |
F |
S |
O |
940 |
||
Glufosinate |
ISO |
H |
S |
O |
1,625 |
||
Heptopargil |
ISO |
PGR |
L |
O |
2,100 |
||
Hexazinone |
ISO |
H |
S |
O |
1,690 |
||
Hydramethylnon |
N(A,B) |
I |
S |
O |
1,200 |
||
IBP |
See iprobenphos |
||||||
Iprobenphos |
N(B) |
F |
S |
O |
600 |
||
Isoprothiolane |
ISO |
F |
S |
O |
1,190 |
||
Isoproturon |
ISO |
H |
S |
O |
1,800 |
||
Isouron |
ISO |
H |
S |
O |
630 |
||
Isoxapyrifop |
ISO |
H |
S |
O |
500 |
||
Kelthane |
N(J) |
See dicofol |
|||||
Malathion |
ISO |
I |
OP |
L |
O |
c2,100 |
LD50 value can vary according to impurities. This value has been adopted for classification purposes and is that of a technical product conforming to WHO specifications; DS 29 |
Maldison |
N(Aus,NZ) |
See malathion |
|||||
MCPA |
ISO |
H |
S |
O |
700 |
||
MCPA-thioethyl |
ISO |
H |
S |
O |
790 |
||
MCPB |
ISO |
H |
S |
O |
680 |
||
Mecoprop |
ISO |
H |
S |
O |
930 |
||
Mecoprop-P |
ISO |
H |
S |
O |
1,050 |
||
Mefluidide |
ISO |
H |
S |
O |
1,920 |
||
Menazon |
ISO |
AP |
OP |
S |
O |
1,950 |
|
Mepiquat |
ISO |
PGR |
S |
O |
1,490 |
||
Metalaxyl |
ISO |
F |
S |
O |
670 |
||
Metaxon |
N(U) |
See MCPA |
|||||
Metconazole |
ISO |
F |
S |
O |
660 |
||
Methazole |
N(A,B) |
H |
S |
O |
4,543 |
Slightly irritant to eyes |
|
2-Methoxyethlymercury silicate |
C |
FST |
OM |
S |
O |
1,140 |
|
Methylarsonic acid |
ISO |
H |
S |
O |
1,800 |
||
Metolachlor |
ISO |
H |
L |
O |
2,780 |
||
MSMA |
See methylarsonic acid |
||||||
Myclobutanil |
N(B) |
F |
S |
O |
1,600 |
||
2-Napthyloxy acetic acid |
ISO |
PGR |
S |
O |
600 |
||
Nitrapyrin |
ISO |
B-S |
S |
O |
1,072 |
||
Nuarimol |
ISO |
F |
S |
O |
1,250 |
||
Octhilinone |
ISO |
F |
S |
O |
1,470 |
||
N-octyl bicycloheptene dicarboximide |
C |
SY |
L |
O |
2,800 |
||
Oxadixyl |
N(B) |
F |
S |
O |
1,860 |
||
Paclobutrazol |
ISO |
PGR |
S |
O |
1,300 |
||
Pallethrine |
N(F) |
See allethrin |
|||||
Para-dichlorobenzene |
See dichlorobenzene |
||||||
Pendimethalin |
ISO |
H |
S |
O |
1,050 |
||
Perfluidone |
ISO |
H |
S |
O |
920 |
||
Pimaricin |
N(B) |
F |
S |
O |
2,730 |
Antibiotic, identical with tennecetin and natamycin |
|
Piproctanyl |
ISO |
PGR |
S |
O |
820 |
||
Pirimiphos-methyl |
ISO |
I |
OP |
L |
O |
2,018 |
DS 49 |
Prochloraz |
ISO |
F |
S |
O |
1,600 |
||
Propachlor |
ISO |
H |
S |
O |
1,500 |
DS 78 |
|
Propanil |
ISO |
H |
S |
O |
c1,400 |
||
Propargite |
ISO |
AC |
L |
O |
2,200 |
||
Pyrazoxyfen |
ISO |
H |
S |
O |
1,644 |
||
Pyridaben |
ISO |
AC |
S |
O |
820 |
||
Pyridaphenthion |
N(J) |
I |
OP |
S |
O |
769 |
|
Pyridate |
ISO |
H |
S |
O |
c2,000 |
||
Pyrifenox |
ISO |
F |
L |
O |
2,900 |
||
Quinoclamine |
ISO |
H |
S |
O |
1,360 |
||
Quizalofop |
N(B) |
H |
S |
O |
1,670 |
||
Resmethrin |
ISO |
I |
PY |
S |
O |
2,000 |
See cismethrin; EHC 92, DS 83, HSG 25 |
Ryania |
C |
I |
S |
O |
c750 |
LD50 varies: vegetable product |
|
Sesamex |
N(A) |
SY |
L |
O |
2,000 |
||
Sethoxydim |
ISO |
H |
L |
O |
3,200 |
||
Silvex |
N(A) |
See fenoprop |
|||||
Simetryn |
ISO |
H |
T |
S |
O |
1,830 |
|
Sodium chlorate |
ISO |
H |
S |
O |
1,200 |
||
Sulfluramid |
ISO |
I |
S |
O |
543 |
||
Sulfoxide |
N(A) |
SY |
L |
O |
2,000 |
||
2,3,6-TBA |
ISO |
H |
S |
O |
1,500 |
||
Tebuthiuron |
ISO |
H |
S |
O |
644 |
||
Thiram |
ISO |
F |
S |
O |
560 |
DS 71 |
|
TMTD |
N(U) |
See thiram |
|||||
2,4,5-TP |
N(F,J,U) |
See fenoprop |
|||||
Tralkoxydim |
ISO |
H |
S |
O |
934 |
||
Triadimefon |
ISO |
F |
S |
O |
602 |
||
Triadimenol |
ISO |
FST |
S |
O |
900 |
||
Tri-allate |
ISO |
H |
TC |
L |
O |
2,165 |
HSG 89 |
Trichlorfon |
ISO |
H |
OP |
S |
O |
560 |
DS 27; EHC 132; HSG 66 |
Triclopyr |
ISO |
H |
S |
O |
710 |
||
Tridiphane |
N(B) |
H |
S |
O |
1,740 |
||
Trifenmorph |
ISO |
M |
S |
O |
1,400 |
DS 64 |
|
Triflumizole |
N(B) |
F |
S |
O |
695 |
||
Undecan-2-one |
C |
RP (dogs,cats) |
oil |
O |
2,500 |
||
Uniconazole |
ISO |
PGR |
S |
O |
1,790 |
||
XMC |
N(J) |
I |
C |
S |
O |
542 |
|
Ziram |
ISO |
F |
S |
O |
1,400 |
Irritant to skin; DS 73 |
Source: WHO 1996.