Wednesday, 16 March 2011 20:28

Smelting and Refining

Adapted from the 3rd edition, Encyclopaedia of Occupational Health and Safety.

In the production and refining of metals, valuable components are separated from worthless material in a series of different physical and chemical reactions. The end-product is metal containing controlled amounts of impurities. Primary smelting and refining produces metals directly from ore concentrates, while secondary smelting and refining produces metals from scrap and process waste. Scrap includes bits and pieces of metal parts, bars, turnings, sheets and wire that are off-specification or worn-out but are capable of being recycled (see the article “Metal reclamation” in this chapter).

Overview of Processes

Two metal recovery technologies are generally used to produce refined metals, pyrometallurgical and hydrometallurgical. Pyrometallurgical processes use heat to separate desired metals from other materials. These processes use differences between oxidation potentials, melting points, vapour pressures, densities and/or miscibility of the ore components when melted. Hydrometallurgical technologies differ from pyrometallurgical processes in that the desired metals are separated from other materials using techniques that capitalize on differences between constituent solubilities and/or electrochemical properties while in aqueous solutions.

Pyrometallurgy

 During pyrometallic processing, an ore, after being beneficiated (concentrated by crushing, grinding, floating and drying), is sintered or roasted (calcined) with other materials such as baghouse dust and flux. The concentrate is then smelted, or melted, in a blast furnace in order to fuse the desired metals into an impure molten bullion. This bullion then undergoes a third pyrometallic process to refine the metal to the desired level of purity. Each time the ore or bullion is heated, waste materials are created. Dust from ventilation and process gases may be captured in a baghouse and are either disposed of or returned to the process, depending upon the residual metal content. Sulphur in the gas is also captured, and when concentrations are above 4% it can be turned into sulphuric acid. Depending upon the origin of the ore and its residual metals content, various metals such as gold and silver may also be produced as by-products.

Roasting is an important pyrometallurgical process. Sulphating roasting is used in the production of cobalt and zinc. Its purpose is to separate the metals so that they can be transformed into a water-soluble form for further hydrometallurgical processing.

The smelting of sulphidic ores produces a partially oxidized metal concentrate (matte). In smelting, the worthless material, usually iron, forms a slag with fluxing material and is converted into the oxide. The valuable metals acquire the metallic form at the converting stage, which takes place in converting furnaces. This method is used in copper and nickel production. Iron, ferrochromium, lead, magnesium and ferrous compounds are produced by reduction of the ore with charcoal and a flux (limestone), the smelting process usually taking place in an electric furnace. (See also the Iron and steel industry chapter.) Fused salt electrolysis, used in aluminium production, is another example of a pyrometallurgical process.

The high temperature required for the pyrometallurgical treatment of metals is obtained by burning fossil fuels or by using the exothermic reaction of the ore itself (e.g., in the flash smelting process). The flash smelting process is an example of an energy-saving pyrometallurgical process in which iron and sulphur of the ore concentrate are oxidized. The exothermic reaction coupled with a heat recovery system saves a lot of energy for smelting. The high sulphur recovery of the process is also beneficial for environmental protection. Most of the recently built copper and nickel smelters use this process.

Hydrometallurgy

Examples of hydrometallurgical processes are leaching, precipitation, electrolytic reduction, ion exchange, membrane separation and solvent extraction. The first stage of hydrometallurgical processes is the leaching of valuable metals from less valuable material, for example, with sulphuric acid. Leaching is often preceded by pre-treatment (e.g., sulphating roasting). The leaching process often requires high pressure, the addition of oxygen or high temperatures. Leaching may also be carried out with electricity. From the leaching solution the desired metal or its compound is recovered by precipitation or reduction using different methods. Reduction is carried out, for example, in cobalt and nickel production with gas.

Electrolysis of metals in aqueous solutions is also considered to be a hydrometallurgical process. In the process of electrolysis the metallic ion is reduced to the metal. The metal is in a weak acid solution from which it precipitates on cathodes under the influence of an electrical current. Most non-ferrous metals can also be refined by electrolysis.

Often metallurgical processes are a combination of pyro- and hydrometallurgical processes, depending on the ore concentrate to be treated and the type of metal to be refined. An example is nickel production.

Hazards and Their Prevention

Prevention of health risks and accidents in the metallurgical industry is primarily an educational and technical question. Medical examinations are secondary and have only a complementary role in the prevention of health risks. A harmonious exchange of information and collaboration between the planning, line, safety and occupational health departments within the company give the most efficient result in the prevention of health risks.

The best and least costly preventive measures are those taken at the planning stage of a new plant or process. In planning of new production facilities, the following aspects should be taken into account as a minimum:

  • The potential sources of air contaminants should be enclosed and isolated.
  • The design and placement of the process equipment should allow easy access for maintenance purposes.
  • Areas in which a sudden and unexpected hazard may occur should be monitored continuously. Adequate warning notices should be included. For example, areas in which arsine or hydrogen cyanide exposure might be possible should be under continuous monitoring.
  • Addition and handling of poisonous process chemicals should be planned so that manual handling can be avoided.
  • Personal occupational hygiene sampling devices should be used in order to evaluate the real exposure of the individual worker, whenever possible. Regular fixed monitoring of gases, dusts and noise gives an overview of exposure but has only a complementary role in the evaluation of exposure dose.
  • In space planning, the requirements of future changes or extensions of the process should be taken into account so that the occupational hygiene standards of the plant will not worsen.
  • There should be a continuous system of training and education for safety and health personnel, as well as for foremen and workers. New workers in particular should be thoroughly informed about potential health risks and how to prevent them in their own working environments. In addition, training should be done whenever a new process is introduced.
  • Work practices are important. For example, poor personal hygiene by eating and smoking in the worksite may considerably increase personal exposure.
  • The management should have a health and safety monitoring system which produces adequate data for technical and economic decision making.

 

The following are some of the specific hazards and precautions that are found in smelting and refining.

Injuries

The smelting and refining industry has a higher rate of injuries than most other industries. Sources of these injuries include: splattering and spills of molten metal and slag resulting in burns; gas explosions and explosions from contact of molten metal with water; collisions with moving locomotives, wagons, travelling cranes and other mobile equipment; falls of heavy objects; falls from a height (e.g., while accessing a crane cab); and slipping and tripping injuries from obstruction of floors and passageways.

Precautions include: adequate training, appropriate personal protective equipment (PPE) (e.g., hard hats, safety shoes, work gloves and protective clothing); good storage, housekeeping and equipment maintenance; traffic rules for moving equipment (including defined routes and an effective signal and warning system); and a fall protection programme.

Heat

Heat stress illnesses such as heat stroke are a common hazard, primarily due to infrared radiation from furnaces and molten metal. This is especially a problem when strenuous work must be done in hot environments.

Prevention of heat illnesses can involve water screens or air curtains in front of furnaces, spot cooling, enclosed air-conditioned booths, heat-protective clothing and air-cooled suits, allowing sufficient time for acclimatization, work breaks in cool areas and an adequate supply of beverages for frequent drinking.

Chemical hazards

Exposure to a wide variety of hazardous dusts, fumes, gases and other chemicals can occur during smelting and refining operations. Crushing and grinding ore in particular can result in high exposures to silica and toxic metal dusts (e.g., containing lead, arsenic and cadmium). There can also be dust exposures during furnace maintenance operations. During smelting operations, metal fumes can be a major problem.

Dust and fume emissions can be controlled by enclosure, automation of processes, local and dilution exhaust ventilation, wetting down of materials, reduced handling of materials and other process changes. Where these are not adequate, respiratory protection would be needed.

Many smelting operations involve the production of large amounts of sulphur dioxide from sulphide ores and carbon monoxide from combustion processes. Dilution and local exhaust ventilation (LEV) are essential.

Sulphuric acid is produced as a by-product of smelting operations and is used in electrolytic refining and leaching of metals. Exposure can occur both to the liquid and to sulphuric acid mists. Skin and eye protection and LEV is needed.

The smelting and refining of some metals can have special hazards. Examples include nickel carbonyl in nickel refining, fluorides in aluminium smelting, arsenic in copper and lead smelting and refining, and mercury and cyanide exposures during gold refining. These processes require their own special precautions.

Other hazards

Glare and infrared radiation from furnaces and molten metal can cause eye damage including cataracts. Proper goggles and face shields should be worn. High levels of infrared radiation may also cause skin burns unless protective clothing is worn.

High noise levels from crushing and grinding ore, gas discharge blowers and high-power electric furnaces can cause hearing loss. If the source of the noise cannot be enclosed or isolated, then hearing protectors should be worn. A hearing conservation program including audiometric testing and training should be instituted.

Electrical hazards can occur during electrolytic processes. Precautions include proper electrical maintenance with lockout/tagout procedures; insulated gloves, clothing and tools; and ground fault circuit interrupters where needed.

Manual lifting and handling of materials can cause back and upper extremity injuries. Mechanical lifting aids and proper training in lifting methods can reduce this problem.

Pollution and Environmental Protection

Emissions of irritant and corrosive gases like sulphur dioxide, hydrogen sulphide and hydrogen chloride may contribute to air pollution and cause corrosion of metals and concrete within the plant and in the surrounding environment. The tolerance of vegetation to sulphur dioxide varies depending on the type of forest and soil. In general, evergreen trees tolerate lower concentrations of sulphur dioxide than deciduous ones. Particulate emissions may contain non-specific particulates, fluorides, lead, arsenic, cadmium and many other toxic metals. Wastewater effluent may contain a variety of toxic metals, sulphuric acid and other impurities. Solid wastes can be contaminated with arsenic, lead, iron sulphides, silica and other pollutants.

Smelter management should include evaluation and control of emissions from the plant. This is specialized work which should be carried out only by personnel thoroughly familiar with the chemical properties and toxicities of the materials discharged from the plant processes. The physical state of the material, the temperature at which it leaves the process, other materials in the gas stream and other factors must all be considered when planning measures to control air pollution. It is also desirable to maintain a weather station, to keep meteorological records and to be prepared to reduce output when weather conditions are unfavourable for dispersal of stack effluents. Field trips are necessary to observe the effect of air pollution on residential and farming areas.

Sulphur dioxide, one of the major contaminants, is recovered as sulphuric acid when present in sufficient quantity. Otherwise, to meet emission standards, sulphur dioxide and other hazardous gaseous wastes are controlled by scrubbing. Particulate emissions are commonly controlled by fabric filters and electrostatic precipitators.

Large amounts of water are used in flotation processes such as copper concentration. Most of this water is recycled back into the process. Tailings from the flotation process are pumped as slurry into sedimentation ponds. Water is recycled in the process. Metal-containing process water and rainwater are cleaned in water-treatment plants before discharging or recycling.

Solid-phase wastes include slags from smelting, blowdown slurries from sulphur dioxide conversion to sulphuric acid and sludges from surface impoundments (e.g., sedimentation ponds). Some slags can be reconcentrated and returned to smelters for reprocessing or recovery of other metals present. Many of these solid-phase wastes are hazardous wastes that must be stored according to environmental regulations.

 

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Wednesday, 16 March 2011 19:37

General Profile

The metal smelting and refining industry processes metal ores and scrap metal to obtain pure metals. The metal working industries process metals in order to manufacture machine components, machinery, instruments and tools which are needed by other industries as well as by the other different sectors of the economy. Various types of metals and alloys are used as starting materials, including rolled stock (bars, strips, light sections, sheets or tubes) and drawn stock (bars, light sections, tubes or wire). Basic metal processing techniques include:

    • smelting and refining of metal ores and scrap
    • casting molten metals into a given shape (foundry)
    • hammering or pressing metals into the shape of a die (hot or cold forging)
    • welding and cutting sheet metal
    • sintering (compressing and heating materials in powder form, including one or more metals)
    • shaping metals on a lathe.

               

              A wide variety of techniques are used to finish metals, including grinding and polishing, abrasive blasting and many surface finishing and coating techniques (electroplating, galvanizing, heat treatment, anodizing, powder coating and so forth).

               

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              Wednesday, 16 March 2011 19:21

              Environmental and Public Health Issues

              The main environmental problems associated with electrical appliance and equipment manufacture involve pollution and treatment of materials discarded during the manufacturing processes, together with the recycling, where possible, of the complete product when it has reached the end of its life.

              Batteries

              The exhaust of air contaminated with acid, alkali, lead, cadmium and other potentially harmful materials into the atmosphere and the pollution of water from the manufacturing of batteries should be prevented as far as possible, and where this is not possible it should be monitored to ensure compliance with relevant legislation.

              The use of batteries can generate public health concerns. Leaking lead-acid or alkaline batteries can result in burns from the electrolyte. Recharging large lead-acid batteries can produce hydrogen gas, a fire and explosion hazard in enclosed areas. Release of thionyl chloride or sulphur dioxide from large lithium batteries can involve exposure to sulphur dioxide, hydrochloric acid mist, burning lithium and so on, and has caused at least one fatality (Ducatman, Ducatman and Barnes 1988). This could also be a hazard during manufacture of these batteries.

              Battery manufacturers have become aware of increasing environmental concern from the disposal of batteries containing toxic heavy metals by putting them in landfills or incinerating them with other garbage. Leakage of toxic metals from waste dumps or alternatively escaping from the chimneys of waste incinerators can result in water and air contamination. The manufacturers therefore recognized the need to reduce the mercury content of batteries, in particular, within the limits allowable by modern technology. The campaign for mercury elimination commenced in advance of the legislation introduced in the European Union, the EC Battery Directive.

              Recycling is another way to deal with environmental pollution. Nickel-cadmium batteries can be recycled relatively easily. The recovery of cadmium is very efficient and it is re-used in the construction of nickel-cadmium batteries. The nickel will subsequently be used in the steel industry. The initial economics suggested that the recycling of nickel-cadmium batteries was not cost effective, but advances in technology are expected to improve the situation. Mercuric oxide cells, which are covered by the EC Battery Directive, have been used primarily in hearing aids, and are being replaced typically with lithium or zinc-air batteries. Silver oxide cells are recycled, especially by the jewellery industry, due to the value of the silver content.

              When recycling harmful materials, care has to be taken similar to that exercised during the manufacturing processes. During the recycling of silver batteries, for example, workers may be exposed to mercury vapour and silver oxide.

              The repair and recycling of lead-acid batteries can result not only in lead poisoning among the workers, and sometimes their families, but also in extensive lead contamination of the environment (Matte et al. 1989). In many countries, particularly in the Caribbean and Latin America, lead car battery plates are burned to produce lead oxide for pottery glazes.

              Electric Cable Manufacture

              Electric cable manufacture has three major sources of pollution: solvent vapours, potential release of toluene di-isocyanate from enamelled wire manufacture and environmental emissions during the manufacture of materials used in cables. All of these require appropriate environmental controls.

              Electric Lamp and Tube Manufacture

              The major environmental concerns here are the waste disposal and/or recycling of mercury-containing lamps and the disposal of PCBs from the ballasts of fluorescent lamps. Glass manufacturing can also be a significant source of emission of nitrogen oxides into the atmosphere.

              Domestic Electric Appliances

              Since the electric appliance industry is to a large extent an assembly industry, environmental issues are minimal, with the major exception being paints and solvents used as surface coatings. Standard pollution control measures should be instituted in accordance with environmental regulations.

              The recycling of electrical appliances involves separation of the recovered equipment into different materials such as copper and mild steel which can be reused, which is discussed elsewhere in this Encyclopaedia.

               

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              Wednesday, 16 March 2011 19:12

              Domestic Electrical Appliance Manufacture

              Adapted from 3rd edition, Encyclopaedia of Occupational Health and Safety.

              The domestic electrical appliance industry is responsible for the manufacture of a wide-ranging variety of equipment including appliances designed for audio-visual, cooking, heating, food preparation and storage (refrigeration) uses. The production and manufacture of such appliances involve many highly-automated processes which can have associated health hazards and disease patterns.

              Manufacturing Processes

              Materials used in the manufacture of domestic electrical appliances can be categorized into:

                1. metals which are used typically for electric conductors in cables and appliance structure and/or framework
                2. dielectrics or insulating materials used for prevention of accidental contact with live electrical equipment
                3. paints and finishes
                4. chemicals.

                       

                      Examples of the materials included in the four categories referred to are shown in table 1.

                      Table 1. Examples of materials used in the manufacture of domestic electrical appliances

                      Metals

                      Dielectrics

                      Paints/finishes

                      Chemicals

                      Steel

                      Inorganic materials (e.g., mica)

                      Paints

                      Acids

                      Aluminium

                      Plastics (e.g., PVC)

                      Lacquers

                      Alkalis

                      Lead

                      Rubber

                      Varnishes

                      Solvents

                      Cadmium

                      Silico-organic materials

                      Corrosion-resistant treatments

                       

                      Mercury

                      Other polymers (e.g., nylon)

                         

                      Note: Lead and mercury are decreasingly common in domestic electrical appliance manufacturing

                      The materials used in the domestic electrical appliance industry must satisfy exacting requirements, including the ability to withstand the handling likely to be encountered in normal operation, the ability to withstand metal fatigue and the ability to be unaffected by any other processes or treatment which could render the appliance dangerous to use either immediately or after a prolonged period of time.

                      The materials used in the industry will often be received at the appliance assembly stage having already undergone several manufacturing processes, each of which is likely to have its own hazards and health problems. Details of these hazards and problems are considered under the appropriate chapters elsewhere in this Encyclopaedia.

                      The manufacturing processes will vary from product to product, but in general will follow the production flow shown in figure 1. This chart also shows the hazards associated with the different processes.

                      Figure 1. Manufacturing process sequence & hazards

                      ELA060F1

                      Health and Safety Issues

                      Fire and explosion

                      Many of the solvents, paints and insulating oils used in the industry are flammable substances. These materials should be stored in suitable cool, dry premises, preferably in a fireproof building separate from the production facility. Containers should be clearly labelled and different substances well separated or stored apart as required by their flashpoints and their class of risk. In the case of insulating materials and plastics, it is important to obtain information on the combustibility or fire characteristics of each new substance used. Powdered zirconium, which is now used in significant quantities in the industry, is also a fire hazard.

                      The quantities of flammable substances issued from storerooms should be kept to the minimum required for production. When flammable liquids are being decanted, charges of static electricity may form, and consequently all containers should be grounded. Fire-extinguishing appliances must be provided and the personnel of the storeplace instructed in their use.

                      Painting of components is usually carried out in specially built paint booths, which must have adequate exhaust and ventilation equipment that, when used with personal protective equipment (PPE), will create a safe working environment.

                      During welding, special fire precautions should be taken.

                      Accidents

                      Reception, storage and dispatch of raw materials, components and finished products can give rise to accidents involving trips and falls, falling objects, fork trucks and so forth. Manual materials handling can also create ergonomic problems which can be alleviated by automation whenever possible.

                      Since numerous different processes are employed in the industry, the accident hazards will vary from shop to shop in the plant. During component production there will be machine hazards in the use of machine tools, power presses, plastics injection-moulding machines and so on, and efficient machinery guarding is essential. During electroplating, precautions must be taken against splashes of corrosive chemicals. During component assembly, the constant movement of components from one process to another means that the danger of accidents due to in-plant transport and mechanical handling equipment is high.

                      Quality testing does not give rise to any special safety problems. However, performance testing requires special precautions since the tests are often carried out on semi-finished or uninsulated appliances. During electrical testing, all live components, conductors, terminals and measuring instruments should be protected to prevent accidental contact. The workplace should be screened off, entrance of unauthorized persons prohibited and warning notices posted. In electrical testing areas, the provision of emergency switches is particularly advisable, and the switches should be in a prominent position so that in an emergency all equipment can be immediately de-energized.

                      For testing appliances that emit x rays or contain radioactive substances, there are radiation protection regulations. A competent supervisor should be made responsible for observance of the regulations.

                      There are special risks in the use of compressed gases, welding equipment, lasers, impregnation plant, spray-painting equipment, annealing and tempering ovens and high-voltage electrical installations.

                      During all repair and maintenance activities, adequate lockout/tagout programmes are essential.

                      Health Hazards

                      Occupational diseases associated with the manufacture of domestic electrical equipment are relatively low in number and not normally considered to be severe. Such problems that do exist are typified by:

                        • the development of skin conditions due to the use of solvents, cutting oils, hardeners used with epoxy resin and polychlorinated biphenyls (PCBs)
                        • the onset of silicosis due to the inhalation of silica in sandblasting (although sand is being increasingly replaced by less toxic blasting agents such as corundum, steel grit or shot)
                        • health problems due to inhalation of solvent vapours in painting and degreasing, and lead poisoning from use of lead pigments, enamels, etc.
                        • varying levels of noise produced during the processes.

                               

                              Wherever possible, highly toxic solvents and chlorinated compounds should be replaced by less dangerous substances; under no circumstances should benzene or carbon tetrachloride be employed as solvents. Lead poisoning may be overcome by substitution of safer materials or techniques and the strict application of safe working procedures, personal hygiene and medical supervision. Where there is a danger of exposure to hazardous concentrations of atmospheric contaminants, the workplace air should be regularly monitored, and appropriate measures such as the installation of an exhaust system taken where necessary. The noise hazard may be reduced by enclosure of noise sources, the use of sound-absorbent materials in workrooms or the use of personal hearing protection.

                              Safety engineers and industrial physicians should be called upon at the design and planning stage of new plants or operations, and the hazards of processes or machines should be eliminated before processes are started up. This should be followed up by regular inspection of machines, tools, plant, transport equipment, firefighting appliances, workshops and test areas and so on.

                              Worker participation in the safety effort is essential, and supervisors should ensure that personal protective equipment is available and worn where necessary. Particular attention should be paid to the safety training of new workers, since these account for a relatively high proportion of accidents.

                              Workers should receive a pre-placement medical examination and, where there is the possibility of hazardous exposure, periodic examination as necessary.

                              Many processes in the production of individual components will involve the rejection of waste material (e.g., “swarf” from sheet or bar metal), and the disposal of such materials must be in accordance with safety requirements. Furthermore, if such process waste cannot be returned to the producer or manufacturer for recycling, then its subsequent disposal must be by approved processes in order to avoid environmental pollution.

                               

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                              Wednesday, 16 March 2011 19:10

                              Electric Lamp and Tube Manufacture

                              Lamps consist of two basic types: filament (or incandescent) lamps and discharge lamps. The basic components of both lamp types include glass, various metal wire pieces, a fill gas and usually a base. Depending on the lamp manufacturer, these materials are either made in-house or may be obtained from an outside supplier. The typical lamp manufacturer will make its own glass bulbs, but may purchase other parts and glasses from speciality manufacturers or other lamp companies.

                              Depending on the lamp type, a variety of glasses may be used. Incandescent and fluorescent lamps typically use a soda-lime glass. Higher temperature lamps will use a borosilicate glass, while high-pressure discharge lamps will use either quartz or ceramic for the arc tube and borosilicate glass for the outer envelope. Leaded glass (containing approximately 20 to 30% lead) is typically used for sealing the ends of the lamp bulbs.

                              The wires used as supports or connectors in lamp construction may be made from a variety of materials including steel, nickel, copper, magnesium and iron, while the filaments are made from tungsten or tungsten-thorium alloy. One critical requirement for the support wire is that it must match the expansion characteristics of the glass where the wire penetrates the glass to conduct the electrical current for the lamp. Frequently, multi-part lead wires are used in this application.

                              Bases (or caps) are typically made from either brass or aluminium, brass being the preferred material when outdoor use is required.

                              Filament or Incandescent Lamps

                              Filament or incandescent lamps are the oldest lamp type still being manufactured. They take their name from the way these lamps produce their light: through the heating of a wire filament to a temperature high enough to cause it to glow. While it is possible to manufacture an incandescent lamp with almost any type of filament (early lamps used carbon), today most such lamps use a filament made of tungsten metal.

                              Tungsten lamps. The common household version of these lamps consists of a glass bulb enclosing a tungsten wire filament. Electricity is conducted to the filament by wires which support the filament and extend through the glass mount which is sealed to the bulb. The wires are then connected to the metal base, with one wire soldered at the centre eyelet of the base, the other connecting to the threaded shell. The supporting wires are of special composition, so that they have the same expansion characteristics as the glass, preventing leaks when the lamps become hot during use. The glass bulb is typically made from lime glass, while the glass mount is leaded glass. Sulphur dioxide is frequently used in preparing the mount. The sulphur dioxide acts as a lubricant during high-speed lamp assembly. Depending on the design of the lamp, the bulb may enclose a vacuum or may use a fill gas of argon or some other non-reactive gas.

                              Lamps of this design are sold using clear glass bulbs, frosted bulbs and bulbs coated with a variety of materials. Frosted bulbs and ones coated with a white material (frequently clay or amorphous silica) are used to reduce the glare from the filament found with clear bulbs. The bulbs are also coated with a variety of other decorative coatings, including coloured ceramics and lacquers on the outside of the bulbs and other colours, such as yellow or pink, on the inside of the bulb.

                              While the typical household shape is the most common, incandescent lamps can be made in many bulb shapes, including tubular, globes and reflector, as well as in many sizes and wattages, from subminiature through to large stage/studio lamps.

                              Tungsten-halogen lamps. One problem in the design of the standard tungsten filament lamp is that the tungsten evaporates during use and condenses on the cooler glass wall, darkening it and reducing the light transmission. Adding a halogen, such as hydrogen bromide or methyl bromide, to the fill gas eliminates this problem. The halogen reacts with the tungsten, preventing it from condensing on the glass wall. When the lamp cools, the tungsten will re-deposit back on the filament. Since this reaction works best at higher lamp pressures, tungsten-halogen lamps typically contain gas at several atmospheres pressure. Typically the halogen is added as a part of the lamp fill gas, usually at concentrations of 2% or less.

                              Tungsten-halogen lamps may also use bulbs made from quartz instead of glass. Quartz bulbs can withstand higher pressures than those made from glass. The quartz bulbs present a potential hazard, however, since the quartz is transparent to ultraviolet light. Although the tungsten filament produces relatively little ultraviolet, prolonged exposure at close range can produce reddening of the skin and cause eye irritation. Filtering the light through a cover glass will greatly reduce the amount of ultraviolet, as well as provide protection from the hot quartz in the event the lamp ruptures during use.

                              Hazards and Precautions

                              Overall, the greatest hazards in lamp production, regardless of product type, are due to the hazards of automated equipment and the handling of glass bulbs and lamps and other material. Cuts from the glass and reaching into the operating equipment are the most common causes of accidents; material-handling issues, such as repetitive motion or back injuries, are of particular concern.

                              Lead solder is frequently used on the lamps. For lamps used in higher temperature applications, solders containing cadmium may be used. In automated lamp assembly operations, exposure to both of these solders is minimal. Where hand soldering is done, as in repair or semi-automated operations, the exposures to lead or cadmium should be monitored.

                              Potential exposures to hazardous materials during lamp manufacturing have consistently decreased since the middle of the 20th century. In incandescent lamp manufacturing, large numbers of the lamps formerly were etched with hydrofluoric acid or bifluoride salt solutions to produce a frosted lamp. This has largely been replaced by the use of a low-toxicity clay coating. While not completely replaced, the use of hydrofluoric acid has been greatly reduced. This change has reduced the risk of burns to the skin and lung irritation due to the acid. The ceramic coloured coatings used on the outside of some lamp products formerly contained heavy metal pigments such as lead, cadmium, cobalt and others, as well as using a lead silicate glass frit as part of the composition. During recent years, many of the heavy metal pigments have been replaced by less toxic colourants. In cases where the heavy metals are still used, a lower toxicity form may be used (e.g., chromium III instead of chromium VI).

                              Coiled tungsten filaments continue to be made by wrapping the tungsten around a molybdenum or a steel mandrel wire. Once the coil has been formed and sintered, the mandrels are dissolved using either hydrochloric acid (for the steel) or a mixture of nitric and sulphuric acid for the molybdenum. Due to the potential acid exposures, this work is routinely done in hood systems or, more recently, in totally enclosed dissolvers (especially where the nitric/sulphuric mix is involved).

                              The fill gasses used in tungsten-halogen lamps are added to the lamps in totally enclosed systems with little loss or exposure. Hydrogen bromide use presents its own problems due to its corrosive nature. LEV must be provided, and corrosion-resistant piping must be used for the gas delivery systems. Thoriated tungsten wire (usually 1 to 2% thorium) is still used in some lamp types. However, there is little risk from the thorium in the wire form.

                              Sulphur dioxide must be carefully controlled. LEV should be used wherever the material is added to the process. Leak detectors may also be useful in storage areas. Use of smaller 75-kg gas cylinders is preferred over larger 1,000-kg containers due to the potential consequences of a catastrophic release.

                              Skin irritation can be a potential hazard from either the soldering fluxes or from the resins used in the basing cement. Some basing cement systems use paraformaldehyde instead of natural resins, resulting in potential formaldehyde exposure during curing of the basing cement.

                              All lamps use a chemical “gettering” system, in which a material is coated on the filament prior to assembly. The purpose of the getter is to react with and scavenge any residual moisture or oxygen in the lamp after the lamp is sealed. Typical getters include phosphorus nitride and mixtures of aluminium and zirconium metal powders. While the phosphorus nitride getter is fairly benign in use, handling aluminium and zirconium metal powders can be a flammability hazard. The getters are applied wet in an organic solvent, but if the material is spilled, the dry metal powders can be ignited by friction. Metal fires must be extinguished with special Class D fire extinguishers and cannot be fought with water, foam or other usual materials. A third type of getter includes use of phosphine or silane. These materials can be included in the gas fill of the lamp at low concentration or can be added at high concentration and “flashed” in the lamp prior to the final gas fill. Both these materials are highly toxic; if used at high concentration, totally enclosed systems with leakage detectors and alarms should be used at the site.

                              Discharge Lamps and Tubes

                              Discharge lamps, both low- and high-pressure models, are more efficient on a light per watt basis than incandescent lamps. Fluorescent lamps have been used for many years in commercial buildings and have been finding increased use in the home. Recently, compact versions of the fluorescent lamp have been developed specifically as replacements for the incandescent lamp.

                              High-pressure discharge lamps have long been used for large area and street lighting. Lower-wattage versions of these products are also being developed.

                              Fluorescent lamps

                              Fluorescent lamps are named for the fluorescent powder used to coat the inside of the glass tube. This powder absorbs ultraviolet light produced by the mercury vapour used in the lamp, and converts and re-emits it as visible light.

                              The glass used in this lamp is similar to that used in incandescent lamps, using lime glass for the tube and leaded glass for the mounts on each end. Two different families of phosphors are in use currently. Halophosphates, based on either calcium or strontium chloro-fluoro-phosphate, are the older phosphors, coming into wide use in the early 1950s when they replaced phosphors based on beryllium silicate. The second phosphor family includes phosphors made from rare earths, typically including yttrium, lanthanum and others. These rare-earth phosphors typically have a narrow emission spectrum, and a mixture of these are used—generally a red, a blue and a green phosphor.

                              The phosphors are mixed with a binder system, suspended in either an organic mix or a water/ammonia mixture and coated on the inside of the glass tube. The organic suspension uses butyl acetate, butyl acetate/naphtha or xylene. Due to environmental regulations, water-based suspensions are replacing those that are organic based. Once the coating is applied, it is dried onto the tube, and the tube is heated to a high temperature to remove the binder.

                              One mount is attached to each end of the lamp. Mercury is now introduced into the lamp. This can be done in a variety of ways. Although in some areas the mercury is added manually, the predominant way is automatically, with the lamp mounted either vertically or horizontally. On vertical machines, the mount stem on one end of the lamp is closed. Then mercury is dropped into the lamp from above, the lamp is filled with argon at low pressure, and the top mount stem is sealed, completely sealing the lamp. On horizontal machines, the mercury is introduced from one side, while the lamp is exhausted from the other side. Argon is again added to the proper pressure, and both ends of the lamp are sealed. Once sealed, the caps or bases are added to the ends, and the wire leads are then either soldered or welded to the electrical contacts.

                              Two other possible ways of introducing mercury vapour can be used. In one system, the mercury is contained on a mercury-impregnated strip, which releases the mercury when the lamp is first started. In the other system, liquid mercury is used, but it is contained within a glass capsule which is attached to the mount. The capsule is ruptured after the lamp has been sealed and exhausted, thereby releasing the mercury.

                              Compact fluorescent lamps are smaller versions of the standard fluorescent lamp, sometimes including the ballast electronics as an integral component of the lamp. Compact fluorescents generally will use a mixture of rare-earth phosphors. Some compact lamps will incorporate a glow starter containing small amounts of radioactive materials to aid in starting the lamp. These glow starters typically use krypton-85, hydrogen-3, promethium-147 or natural thorium to provide what is called a dark current, which helps the lamp start quicker. This is desirable from a consumer standpoint, where the customer wants the lamp to start immediately, without flickering.

                              Hazards and precautions

                              Fluorescent lamp manufacturing has seen a considerable number of changes. Early use of a beryllium-containing phosphor was discontinued in 1949, eliminating a significant respiratory hazard during phosphor production and use. In many operations, water-based phosphor suspensions have replaced organic suspensions in the coating of the fluorescent lamps, reducing exposure to the workers as well as reducing the emission of VOCs to the environment. Water-based suspensions do involve some minimal exposure to ammonia, particularly during mixing of the suspensions.

                              Mercury remains the material of greatest concern during fluorescent lamp making. While the exposures are relatively low except around the exhaust machines, there is potential for significant exposure to workers stationed around the exhaust machine, to mechanics working on these machines and during clean-up operations. Personal protective equipment, such as coveralls and gloves to avoid or limit exposure and, where needed, respiratory protection, should be used, especially during maintenance activities and clean-up. A biological monitoring programme, including mercury urinalysis, should be established for fluorescent lamp manufacturing sites.

                              The two phosphor systems currently in production utilize materials considered to have relatively low toxicity. While some of the additives to the parent phosphors (such as barium, lead and manganese) have exposure limits established by various governmental agencies, these components are usually present in relatively low percentages in the compositions.

                              Phenol-formaldehyde resins are used as electrical insulators in the end caps of the lamps. The cement typically includes natural and synthetic resins, which may include skin irritants such as hexamethylene-tetramine. Automated mixing and handling equipment limits the potential for skin contact to these materials, thereby limiting the potential for skin irritation.

                              High-pressure mercury lamps

                              High-pressure mercury lamps include two similar types: those using just mercury and those using a mixture of mercury and a variety of metal halides. The basic design of the lamps is similar. Both types use a quartz arc tube which will contain the mercury or mercury/halide mixture. This arc tube is then enclosed in a hard, borosilicate glass outer jacket, and a metal base is added to provide for electrical contacts. The outer jacket can be clear or coated with either a diffusing material or a phosphor to modify the colour of the light.

                              Mercury lamps contain only mercury and argon in the quartz arc tube of the lamp. The mercury, under high pressure, generates light with a high blue and ultraviolet content. The quartz arc tube is completely transparent to UV light, and in the event that the outer jacket is broken or removed, is a powerful UV light source that can produce skin and eye burns in those exposed. Though the typical mercury lamp design will continue to operate if the outer jacket is removed, manufacturers also offer some models in a fused design which will stop operating if the jacket is broken. During normal use, the borosilicate glass of the outer jacket absorbs a high percentage of the UV light, so that the intact lamp does not pose a hazard.

                              Because of the high blue content of the mercury lamp spectrum, the inside of the outer jacket is frequently coated with a phosphor such as yttrium vanadate phosphate or similar red-enhancing phosphor.

                              Metal halide lamps also contain mercury and argon in the arc tube, but add metal halides (typically a mixture of sodium and scandium, possibly with others). The addition of the metal halides enhances the red light output of the lamp, producing a lamp which has a more balanced light spectrum.

                              Hazards and precautions

                              Other than mercury, potentially hazardous materials used in high-pressure mercury lamp production include the coating materials used on the outer envelopes and the halide additives used in the metal halide lamps. One coating material is a simple diffuser, the same as that used in incandescent lamps. Another is a colour-correcting phosphor, yttrium vanadate or yttrium vanadate phosphate. While similar to vanadium pentoxide, the vanadate is considered to be less toxic. Exposure to the halide materials is normally not significant, since the halides react in moist air and must be kept dry and under an inert atmosphere during handling and use. Similarly, although the sodium is a highly reactive metal, it too needs to be handled under an inert atmosphere to avoid oxidizing the metal.

                              Sodium Lamps

                              Two types of sodium lamps are currently produced. Low-pressure lamps contain only metallic sodium as the light emitting source and produce a highly yellow light. High-pressure sodium lamps use mercury and sodium to generate a whiter light.

                              Low-pressure sodium lamps have one glass tube, which contains the metallic sodium, enclosed within a second glass tube.

                              High-pressure sodium lamps contain a mixture of mercury and sodium within a high-purity ceramic alumina arc tube. Other than the composition of the arc tube, the construction of the high-pressure sodium lamp is essentially the same as the mercury and metal halide lamps.

                              Hazards and precautions

                              There are few unique hazards during manufacturing of high- or low-pressure sodium lamps. In both lamp types, the sodium must be kept dry. Pure metallic sodium will violently react with water, producing hydrogen gas and enough heat to cause ignition. Metallic sodium left out in air will react with the moisture in the air, producing an oxide coating on the metal. To avoid this, the sodium is usually handled in a glove box, under a dry nitrogen or argon atmosphere. For sites manufacturing high-pressure sodium lamps, additional precautions are needed to handle the mercury, similar to those sites manufacturing high-pressure mercury lamps.

                              Environmental and Public Health Issues

                              Waste disposal and/or recycling of mercury-containing lamps is an issue that has received a high degree of attention in many areas of the world over the last several years. While at best a “break even” operation from a cost viewpoint, technology currently exists to reclaim the mercury from fluorescent and high-pressure discharge lamps. Recycling of lamp materials at the present time is more accurately described as reclamation, since the lamp materials are rarely reprocessed and used in making new lamps. Typically, the metal parts are sent to scrap metal dealers. The recovered glass may be used to make fibreglass or glass blocks or used as aggregate in cement or asphalt paving. Recycling may be the lower-cost alternative, depending on location and availability of recycling and hazardous or special waste disposal options.

                              The ballasts used in fluorescent lamp installations previously contained capacitors which used PCBs as the dielectric. While manufacture of PCB-containing ballasts has been discontinued, many of the older ballasts may still be in use due to their long life expectancy. Disposal of the PCB-containing ballasts may be regulated and may require disposal as a special or hazardous waste.

                              Glass manufacturing, particularly borosilicate glasses, can be a significant source of NOx emission to the atmosphere. Recently, pure oxygen instead of air has been used with gas burners as a means of reducing the NOx emissions.

                               

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                              Wednesday, 16 March 2011 19:06

                              Electric Cable Manufacture

                              Cables come in a variety of sizes for different uses, from supertension power cables which carry electrical power at more than 100 kilovolts, down to telecommunication cables. The latter in the past utilized copper conductors, but these have been superseded by fibre optic cables, which carry more information in a much smaller cable. In between there are the general cables used for house wiring purposes, other flexible cables and power cables at voltages below those of the supertension cables. In addition, there are more specialized cables such as mineral insulated cables (used where their inherent protection from burning in a fire is crucial—for example, in a factory, in a hotel or on board a ship), enamelled wires (used as electrical windings for motors), tinsel wire (used in the curly connection of a telephone handset), cooker cables (which historically used asbestos insulation but now use other materials) and so on.

                              Materials and Processes

                              Conductors

                              The most common material used as the conductor in cables has always been copper, due to its electrical conductivity. Copper has to be refined to high purity before it can be made into a conductor. The refining of copper from ore or scrap is a two-stage process:

                              1. fire refining in a large furnace to remove unwanted impurities and cast a copper anode
                              2. electrolytic refining in an electrical cell containing sulphuric acid, from which very pure copper is deposited on to the cathode.

                               

                              In modern plants, copper cathodes are melted in a shaft furnace and continuously cast and rolled into copper rod. This rod is drawn down to the required size on a wire-drawing machine by pulling the copper through a series of precise dies. Historically, the wire-drawing operation was conducted in one central location, with many machines producing wires of different sizes. More recently, smaller autonomous factories have their own, smaller wire-drawing operation. For some specialist applications the copper conductor is plated with a metal coating, such as tin, silver or zinc.

                              Aluminium conductors are used in overhead power cables where the lighter weight more than compensates for the inferior conductivity compared to copper. Aluminium conductors are made by squeezing a heated billet of aluminium through a die using an extrusion press.

                              More specialized metallic conductors utilize special alloys for a particular application. A cadmium-copper alloy has been used for overhead catenaries (the overhead conductor used on a railway) and for the tinsel wire used in a telephone handset. The cadmium increases the tensile strength compared to pure copper, and is used so that the catenary does not sag between supports. Beryllium-copper alloy is also used in certain applications.

                              Optical fibres, consisting of a continuous filament of high optical quality glass to transmit telecommunications, were developed in the early 1980s. This required a totally new manufacturing technology. Silicon tetrachloride is burnt inside a lathe to deposit silicon dioxide on a blank. The silicon dioxide is converted to glass by heating in a chlorine atmosphere; then it is drawn to size, and a protective coating is applied.

                              Insulation

                              Many insulation materials have been used on different types of cables. The most common types are plastic materials, such as PVC, polyethylene, polytetrafluoroethylene (PTFE) and poly- amides. In each case, the plastic is formulated to meet a technical specification, and is applied to the outside of the conductor using an extrusion machine. In some instances, materials may be added to the plastic compound for a particular application. Some power cables, for example, incorporate a silane compound for cross-linking the plastic. In cases where the cable is going to be buried in the ground, a pesticide is added to prevent termites from eating the insulation.

                              Some flexible cables, particularly those in underground mines, use rubber insulation. Hundreds of different rubber compounds are needed to meet different specifications, and a specialist rubber compounding facility is required. The rubber is extruded on to the conductor. It must also be vulcanized by passing through either a bath of hot nitrite salt or a pressurized liquid. To prevent adjacent rubber-insulated conductors from sticking together, they are drawn through talc powder.

                              The conductor inside a cable may be wrapped with an insulator such as paper (which may have been soaked in a mineral or a synthetic oil) or mica. An outer sheath is then applied, typically by plastic extrusion.

                              Two methods of manufacturing mineral insulated (MI) cables have been developed. In the first, a copper tube has a number of solid copper conductors inserted into it, and the space between is packed with a magnesium oxide powder. The whole assembly is then drawn down through a series of dies to the required size. The other technique involves continuous welding of a copper spiral around conductors separated by powder. In use, the outer copper sheath of an MI cable is the earth connection, and the inner conductors carry the current. Although no outer layer is needed, some customers specify a PVC sheath for aesthetic reasons. This is counter-productive, since the main advantage of MI cable is that it does not burn, and a PVC sheath negates this advantage somewhat.

                              In recent years the behaviour of cables in fires has received increasing attention for two reasons:

                              1. Most rubbers and plastics, the traditional insulation materials, emit copious quantities of smoke and toxic gases in a fire, and in a number of high-profile fire incidents this has been the main cause of death.
                              2. Once a cable has burnt through, the conductors touch and fuse the circuit, and so electrical power is lost. This has led to the development of low smoke and fire (LSF) compounds, both for plastic and rubber materials. It should be realized, however, that the best performance in a fire will always be obtained from an MI cable.

                               

                              A number of specialized materials are used for certain cables. Supertension cables are oil-filled both for insulation and cooling properties. Other cables use a hydrocarbon grease known as MIND, petroleum jelly or a lead sheath. Enamelled wires are typically made by coating them with a polyurethane enamel dissolved in cresol.

                              Cablemaking

                              In many cables the individual, insulated conductors are twisted together to form a particular configuration. A number of reels containing the individual conductors revolve around a central axis as the cable is drawn through the machine, in operations known as stranding and lay-up.

                              Some cables need to be protected from mechanical damage. This is often done by braiding, where a material is interwoven around the outer insulation of a flexible cable such that each strand crosses each other one over and over again in a spiral. An example of such a braided cable (at least in the UK) is that used on electric irons, where textile thread is used as the braiding material. In other cases steel wire is used for the braiding, where the operation is referred to as armouring.

                              Ancillary operations

                              Larger cables are supplied on drums of up to a few metres in diameter. Traditionally, drums are wooden, but steel ones have been used. A wooden drum is made by nailing together sawn timber using either a machine or a pneumatic nailing gun. A copper-chrome-arsenic preservative is used to prevent the wood from rotting. Smaller cables are usually supplied on a cardboard reel.

                              The operation of connecting the two ends of cables together, known as jointing, may well have to be carried out in a remote location. The joint not only has to have a good electrical connection, but must also be able to withstand future environmental conditions. The jointing compounds used are commonly acrylic resins and incorporate both isocyanate compounds and silica powder.

                              Cable connectors are commonly made out of brass on automatic lathes which manufacture them from bar stock. The machines are cooled and lubricated using a water-oil emulsion. Cable clips are made by plastic injection machines.

                              Hazards and their Prevention

                              The most widespread health hazard throughout the cable industry is noise. The noisiest operations are:

                              • wire-drawing
                              • braiding
                              • the copper fire refinery
                              • continuous casting of copper rods
                              • cable drum manufacture.

                               

                              Noise levels in excess of 90 dBA are common in these areas. For wire-drawing and braiding the overall noise level depends upon the number and location of machines and the acoustic environment. The machine layout should be planned to minimize noise exposures. Carefully designed acoustic enclosures are the most effective means of controlling the noise, but are expensive. For the copper fire refinery and continuous casting of copper rods the main sources of noise are the burners, which should be designed for low noise emission. In the case of cable drum manufacture the pneumatically operated nail guns are the principal source of noise, which can be reduced by lowering the air-line pressure and installing exhaust silencers. The industry’s norm in most of the above cases, however, is to issue hearing protection to workers in the areas affected, but such protection will be more uncomfortable than usual due to the hot environments in the copper fire refinery and continuous casting of copper rods. Regular audiometry should also be conducted to monitor each individual’s hearing.

                              Many of the safety hazards and their prevention are the same as those in many other manufacturing industries. However, special hazards are presented by some cablemaking machines, in that they have numerous reels of conductors rotating around two axes at the same time. It is essential to ensure that machine guards are interlocked to prevent the machine from operating unless the guards are in position to prevent access to running nips and other rotating parts, such as large cable drums. During the initial threading of the machine, when it may well be necessary to permit the operator access inside the machine guard, the machine should be capable of moving only a few centimetres at a time. Interlock arrangements can be achieved by having a unique key which either opens the guard or has to be inserted into the control console to allow it to operate.

                              An assessment of the risk from flying particles—for example, if a wire breaks and whips out—should be made.

                              Guards should preferably be designed to physically prevent such particles from reaching the operator. Where this is not possible, suitable eye protection must be issued and worn. Wire-drawing operations are often designated as areas where eye protection must be used.

                              Conductors

                              In any hot metal process, such as a copper fire refinery or casting copper rods, water must be prevented from coming into contact with molten metal to prevent an explosion. Loading the furnace can result in the escape of metal oxide fumes into the workplace. This should be controlled using effective local exhaust ventilation over the charging door. Similarly the launders down which the molten metal passes from the furnace to the casting machine and the casting machine itself need to be adequately controlled.

                              The principal hazard in the electrolytic refinery is the sulphuric acid mist evolved from each cell. Airborne concentrations must be kept below 1 mg/m3 by suitable ventilation to prevent irritation.

                              When casting copper rods, an additional hazard can be presented by the use of insulation boards or blankets to conserve heat around the casting wheel. Ceramic materials may have replaced asbestos in such applications, but ceramic fibres themselves must be handled with great care to prevent exposures. Such materials become more friable (i.e., easily broken up) after use when they have been affected by heat, and exposures to airborne respirable fibres have resulted from handling them.

                              An unusual hazard is presented in the manufacture of aluminium power cables. A suspension of graphite in a heavy oil is applied to the ram of the extrusion press to prevent the aluminium billet from sticking to the ram. As the ram is hot, some of this material is burnt off and rises into the roof space. Provided that there is no overhead crane operator in the vicinity and that roof fans are fitted and working, there should be no risk to the health of workers.

                              Making either cadmium-copper alloy or beryllium-copper alloy can present high risks to the employees involved. Since cadmium boils well below the melting point of copper, freshly generated cadmium oxide fumes will be generated in great quantities whenever cadmium is added to molten copper (which it must be to make the alloy). The process can be carried out safely only with very careful design of the local exhaust ventilation. Similarly the manufacture of beryllium-copper alloy requires great attention to detail, since beryllium is the most toxic of all the toxic metals and has the most stringent of exposure limits.

                              The manufacture of optical fibres is a highly specialized, high-technology operation. The chemicals used have their own special hazards, and control of the working environment requires the design, installation and maintenance of complex LEV and process ventilation systems. These systems must be controlled by computer-monitored control dampers. The main chemical hazards are from chlorine, hydrogen chloride and ozone. In addition, the solvents used to clean the dies must be handled in extracted fume cabinets, and skin contact with the acrylate-based resins used to coat the fibres must be avoided.

                              Insulation

                              Both plastic compounding and rubber compounding operations present particular hazards which must be adequately controlled (see the chapter Rubber Industry). Although the cable industry may use different compounds than other industries, the control techniques are the same.

                              When they are heated, plastic compounds will give off a complex mixture of thermal degradation products, the composition of which will depend upon the original plastic compound and the temperature to which it is subjected. At the normal processing temperature of plastic extruders, airborne contaminants are usually a relatively small problem, but it is prudent to install ventilation over the gap between the extruder head and the water trough used to cool the product down, mainly to control exposure to the phthalate plasticizers commonly used in PVC. The phase of the operation which may well warrant further investigation is during a changeover. The operator has to stand over the extruder head to remove the still-hot plastic compound, and then run the new compound through (and on to the floor) until only the new colour is coming through and the cable is centralized in the extruder head. It can be difficult to design effective LEV during this phase when the operator is so close to the extruder head.

                              Polytetrafluoroethylene (PTFE) has its own special hazard. It can cause polymer fume fever, which has symptoms resembling those of influenza. The condition is a temporary one, but should be prevented by adequately controlling exposures to the heated compound.

                              The use of rubber in making cables has presented a lower level of risk than other uses of rubber, such as in the tyre industry. In both industries the use of an antioxidant (Nonox S) containing β-naphthylamine, up to its withdrawal in 1949, resulted in cases of bladder cancer up to 30 years later in those who had been exposed prior to the withdrawal date, but none in those employed after 1949 only. The cable industry, however, has not experienced the increased incidence of other cancers, particularly of lung and stomach, seen in the tyre industry. The reason is almost certainly that in cable manufacture the extrusion and vulcanizing machines are enclosed, and employee exposures to rubber fumes and rubber dust were generally much lower than in the tyre industry. One exposure of potential concern in rubber cable factories is the use of talc. It is important to ensure that only the non-fibrous form of talc (i.e., one which does not contain any fibrous tremolite) is used and that the talc is applied in an enclosed box with local exhaust ventilation.

                              Many cables are printed with identification markings. Where modern video jet printers are used the risk to health is almost certainly negligible due to the very small quantities of solvent utilized. Other printing techniques, however, can result in significant solvent exposures, either during normal production, or more usually during cleaning operations. Suitable exhaust systems should therefore be used to control such exposures.

                              The main hazards from making MI cables are dust exposure, noise and vibration. The first two of these are controlled by standard techniques described elsewhere. Vibration exposure occurred in the past during swaging, when a point was formed at the end of the assembled tube by manual insertion into a machine with rotating hammers, so that the point could be inserted into the drawing machine. More recently this type of swaging machine has been replaced with pneumatic ones, and this has eliminated both the vibration and the noise generated by the older method.

                              Lead exposure during lead sheathing should be controlled by using adequate LEV and by prohibiting eating, drinking and cigarette smoking in areas liable to be contaminated with lead. Regular biological monitoring should be undertaken by analysing blood samples for lead content at a qualified laboratory.

                              The cresol used in the manufacture of enamelled wires is corrosive and has a distinctive odour at very low concentrations. Some of the polyurethane is thermally degraded in the enamelling ovens to release toluene di-isocyanate (TDI), a potent respiratory sensitizer. Good LEV is needed around the ovens with catalytic afterburners to ensure that the TDI does not pollute the surrounding area.

                              Ancillary operations

                              Jointing operations present hazards to two distinct groups of workers—those that make them and those that use them. Manufacture involves the handling of a fibrogenic dust (silica), a respiratory sensitizer (isocyanate) and a skin sensitizer (acrylic resin). Effective LEV must be used to adequately control employee exposures, and suitable gloves must be worn to prevent skin contact with the resin. The main hazard to users of the compounds is from skin sensitization to the resin. This can be difficult to control since the jointer may not be able to avoid skin contact altogether, and will often be in a remote location away from a source of water for cleaning purposes. A waterless hand cleanser is therefore essential.

                              Environmental hazards and their prevention

                              In the main, cable manufacture does not result in significant emissions outside the factory. There are three exceptions to this rule. The first is that exposure to the vapours of solvents used for printing and other purposes are controlled by the use of LEV systems which discharge the vapours to the atmosphere. Such emissions of volatile organic compounds (VOCs) are one of the components necessary to form photochemical smog, and so are coming under increasing pressure from regulatory authorities in a number of countries. The second exception is the potential release of TDI from enamelled wire manufacture. The third exception is that in a number of instances the manufacture of the raw materials used in cables can result in environmental emissions if control measures are not taken. Metal particulate emissions from a copper fire refinery, and from the manufacture of either cadmium-copper or beryllium-copper alloys, should each be ducted to suitable bag filter systems. Similarly any particulate emissions from rubber compounding should be ducted to a bag filter unit. Emissions of particulates, hydrogen chloride and chlorine from the manufacture of optical fibres should be ducted to a bag filter system followed by a caustic soda scrubber.

                               

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                              Wednesday, 16 March 2011 18:57

                              Batteries

                              The term battery refers to a collection of individual cells, which can generate electricity though chemical reactions. Cells are categorized as either primary or secondary. In primary cells, the chemical reactions that produce the electron flow are not reversible, and therefore the cells are not easily recharged. Conversely, secondary cells must be charged prior to their use, which is achieved by passing an electrical current through the cell. Secondary cells have the advantage that they can often be repeatedly recharged and discharged through use.

                              The classic primary battery in everyday use is the Leclanché dry cell, so called because the electrolyte is a paste, not a liquid. The Leclanché cell is typified by the cylindrical batteries used in flashlights, portable radios, calculators, electric toys and the like. In recent years, alkaline batteries, such as the zinc-manganese dioxide cell, have become more prevalent for this type of use. Miniature or “button” batteries have found use in hearing aids, computers, watches, cameras and other electronic equipment. The silver oxide-zinc cell, mercury cell, the zinc-air cell, and the lithium-manganese dioxide cell are some examples. See figure 1 for a cutaway view of a typical alkaline miniature battery.

                              Figure 1. Cutaway view of alkaline miniature battery

                              ELA030F1

                              The classic secondary or storage battery is the lead-acid battery, widely used in the transportation industry. Secondary batteries are also used in power plants and industry. Rechargeable, battery-operated tools, toothbrushes, flashlights and the like are a new market for secondary cells. Nickel-cadmium secondary cells are becoming more popular, especially in pocket cells for emergency lighting, diesel starting and stationary and traction applications, where the reliability, long life, frequent rechargeability and low-temperature performance outweigh their extra cost.

                              Rechargeable batteries under development for use in electric vehicles utilize lithium-ferrous sulphide, zinc-chlorine and sodium-sulphur.

                              Table 1 gives the composition of some common batteries.

                              Table 1. Composition of common batteries

                              Type of battery

                              Negative electrode

                              Positive electrode

                              Electrolyte

                              Primary cells

                              Leclanché dry cell

                              Zinc

                              Manganese dioxide

                              Water, zinc chloride, ammonium chloride

                              Alkaline

                              Zinc

                              Manganese dioxide

                              Potassium hydroxide

                              Mercury (Ruben’s cell)

                              Zinc

                              Mercuric oxide

                              Potassium hydroxide, zinc oxide, water

                              Silver

                              Zinc

                              Silver oxide

                              Potassium hydroxide, zinc oxide, water

                              Lithium

                              Lithium

                              Manganese dioxide

                              Lithium chlorate, LiCF3SO3

                              Lithium

                              Lithium

                              Sulphur dioxide

                              Sulphur dioxide, acetonitrile, lithium bromide

                                 

                              Thionyl chloride

                              Lithium aluminium chloride

                              Zinc in air

                              Zinc

                              Oxygen

                              Zinc oxide, potassium hydroxide

                              Secondary cells

                              Lead-acid

                              Lead

                              Lead dioxide

                              Dilute sulphuric acid

                              Nickel-iron (Edison battery)

                              Iron

                              Nickel oxide

                              Potassium hydroxide

                              Nickel-cadmium

                              Cadmium hydroxide

                              Nickel hydroxide

                              Potassium hydroxide, possibly lithium hydroxide

                              Silver-zinc

                              Zinc powder

                              Silver oxide

                              Potassium hydroxide

                               

                              Manufacturing Processes

                              While there are clear differences in the manufacture of the different types of batteries, there are several processes which are common: weighing, grinding, mixing, compressing and drying of constituent ingredients. In modern battery plants many of these processes are enclosed and highly automated, using sealed equipment. Therefore, exposure to the various ingredients can occur during weighing and loading and during cleaning of the equipment.

                              In older battery plants, many of the grinding, mixing and other operations are done manually, or the transfer of ingredients from one step of the process to another is done manually. In these instances, the risk of inhalation of dusts or skin contact with corrosive substances is high. Precautions for dust-producing operations include total enclosure and mechanized handling and weighing of powders, local exhaust ventilation, daily wet mopping and/or vacuuming and wearing of respirators and other personal protective equipment during maintenance operations.

                              Noise is also a hazard, since compressing machines and wrapping machines are noisy. Noise control methods and hearing conservation programmes are essential.

                              The electrolytes in many batteries contain corrosive potassium hydroxide. Enclosure and skin and eye protection are indicated precautions. Exposures can also occur to the particulates of toxic metals such as cadmium oxide, mercury, mercuric oxide, nickel and nickel compounds, and lithium and lithium compounds, which are used as anodes or cathodes in particular types of batteries. The lead-acid storage battery, sometimes referred to as the accumulator, can involve considerable lead exposure hazards and is discussed separately in the article “Lead-acid battery manufacture”.

                              Lithium metal is highly reactive, thus lithium batteries must be assembled in a dry atmosphere in order to avoid the lithium reacting with water vapour. Sulphur dioxide and thionyl chloride, used in some lithium batteries, are respiratory hazards. Hydrogen gas, used in nickel-hydrogen batteries, is a fire and explosion hazard. These, as well as materials in newly developed batteries, will require special precautions.

                              Leclanché Cells

                              Leclanché dry-cell batteries are produced as shown in figure 2. The positive electrode or cathode mixture comprises 60 to 70% manganese dioxide, the remainder being made up of graphite, acetylene black, ammonium salts, zinc chloride and water. Dry, finely ground manganese dioxide, graphite and acetylene black are weighed and fed into a grinder-mixer; electrolyte containing water, zinc chloride and ammonium chloride is added, and the prepared mixture is pressed on a hand-fed tableting or agglomerating press. In certain cases, the mixture is dried in an oven, sifted and remoistened before tableting. The tablets are inspected and wrapped on hand-fed machines after being allowed to harden for a few days. The agglomerates are then placed in trays and soaked in electrolyte, and are now ready for assembly.

                              Figure 2. Leclanché cell battery production

                              ELA030F2

                              The anode is the zinc case, which is prepared from zinc blanks on a hot press (or zinc sheets are folded and welded to the case). An organic gelatinous paste consisting of maize and flour starches soaked in electrolyte is mixed in large vats. The ingredients are usually poured in from sacks without weighing. The mixture is then purified with zinc chips and manganese dioxide. Mercuric chloride is added to the electrolyte to form an amalgam with the interior of the zinc container. This paste will form the conducting medium or electrolyte.

                              Cells are assembled by automatic pouring of the required amount of gelatinous paste into the zinc cases to form an inner sleeve lining on the zinc container. In some cases, the cases receive a chromate finish by the pouring in and emptying of a mixture of chromic and hydrochloric acid before adding the gelatinous paste. The cathode agglomerate is then placed in position in the centre of the case. A carbon rod is placed centrally in the cathode to act as the current collector.

                              The zinc cell is then sealed with molten wax or paraffin and heated with a flame to give a better seal. The cells are then welded together to form the battery. The reaction of the battery is:

                              2 MnO2 + 2 NH4Cl + Zn → ZnCl2 + H2O2 + Mn2O3

                              Workers may be exposed to manganese dioxide during weighing, mixer loading, grinding, cleaning the oven, sifting, hand pressing and wrapping, depending on the degree of automation, sealed enclosure and local exhaust ventilation. In manual pressing and wet wrapping, there may be exposure to the wet mixture, which can dry to produce inhalable dust; dermatitis may occur from exposure to the slightly corrosive electrolyte. Personal hygiene measures, gloves and respiratory protection for cleaning and maintenance operations, showering facilities and separate lockers for work and street clothes can reduce these risks. As mentioned above, noise hazards can result from the wrapping and tableting press.

                              Mixing is automatic during manufacture of the gelatinous paste, and the only exposure is during addition of the materials. During addition of mercuric chloride to the gelatinous paste, there is the risk of inhalation and skin absorption and possible mercury poisoning. LEV or personal protective equipment is necessary.

                              Exposure to spills of chromic acid and hydrochloric acid during chromating and exposure to welding fumes and fumes from heating the sealing compound are also possible. Mechanization of the chromating process, use of gloves and LEV for heat sealing and welding are suitable precautions.

                              Nickel-Cadmium Batteries

                              The most common method today of making nickel-cadmium electrodes is by depositing the active electrode material directly into a porous sintered nickel substrate, or plate. (See figure 3.) The plate is prepared by pressing a paste of sintered grade nickel powder (often made by decomposition of nickel carbonyl) into the open grid of nickel-plated perforated sheet steel (or nickel gauze or nickel-plated steel gauze) and then sintering or drying in an oven. These plates may then be cut, weighed and coined (compressed) for particular purposes or rolled into a spiral for household-type cells.

                              Figure 3. Nickel-cadmium battery production

                              ELA030F3

                              The sintered plaque is then impregnated with nickel nitrate solution for the positive electrode or cadmium nitrate for the negative electrode. These plaques are rinsed and dried, immersed in sodium hydroxide to form nickel hydroxide or cadmium hydroxide and washed and dried again. Usually the next step is to immerse the positive and negative electrodes in a large temporary cell containing 20 to 30% sodium hydroxide. Charge-discharge cycles are run to remove impurities and the electrodes are removed, washed and dried.

                              An alternative way of making cadmium electrodes is to prepare a paste of cadmium oxide mixed with graphite, iron oxide and paraffin, which is milled and finally compacted between rollers to form the active material. This is then pressed into a moving perforated steel strip that is dried, sometimes compressed, and cut into plates. Lugs may be attached at this stage.

                              The next steps involve cell and battery assembly. For large batteries, the individual electrodes are then assembled into electrode groups with plates of opposite polarity interleaved with plastic separators. These electrode groups may be bolted or welded together and placed in a nickel-plated steel casing. More recently, plastic battery casings have been introduced. The cells are filled with an electrolyte solution of potassium hydroxide, which may also contain lithium hydroxide. The cells are then assembled into batteries and bolted together. Plastic cells may be cemented or taped together. Each cell is connected with a lead connector to the adjacent cell, leaving a positive and negative terminal at the ends of the battery.

                              For cylindrical batteries, the impregnated plates are assembled into electrode groups by winding the positive and negative electrodes, separated by an inert material, into a tight cylinder. The electrode cylinder is then placed in a nickel-plated metal case, potassium hydroxide electrolyte is added and the cell is sealed by welding.

                              The chemical reaction involved in the charging and discharging of nickel-cadmium batteries is:

                              The major potential exposure to cadmium occurs from handling of cadmium nitrate and its solution while making paste from cadmium oxide powder and handling the dried active powders. Exposure can also occur during reclamation of cadmium from scrap plates. Enclosure and automated weighing and mixing can reduce these hazards during the early steps.

                              Similar measures can control exposures to nickel compounds. The production of sintered nickel from nickel carbonyl, although done in sealed machinery, involves potential exposure to extremely toxic nickel carbonyl and carbon monoxide. The process requires continuous monitoring for gas leaks.

                              The handling of caustic potassium or lithium hydroxide requires suitable ventilation and personal protection. Welding generates fumes and requires LEV.

                              Health Effects and Disease Patterns

                              The most serious health hazards in traditional battery making are lead, cadmium, mercury and manganese dioxide exposures. Lead hazards are discussed elsewhere in this chapter and Encyclopaedia. Cadmium can cause kidney disease and is carcinogenic. Cadmium exposure was found to be widespread in US nickel-cadmium battery plants, and many workers have had to be medically removed under the Occupational Safety and Health Administration’s Cadmium Standard provisions due to high cadmium levels in blood and urine (McDiarmid et al. 1996). Mercury affects the kidneys and nervous system. Excessive exposure to mercury vapour has been shown in studies of several mercury battery plants (Telesca 1983). Manganese dioxide exposures have been shown to be high in powder mixing and handling in alkaline dry cell manufacturing (Wallis, Menke and Chelton 1993). This can result in neurofunctional deficits in battery workers (Roels et al. 1992). Manganese dusts can, if absorbed in excessive quantities, lead to disorders of the central nervous system similar to Parkinson’s syndrome. Other metals of concern include nickel, lithium, silver and cobalt.

                              Skin burns can result from exposure to zinc chloride, potassium hydroxide, sodium hydroxide and lithium hydroxide solutions used in the electrolytes of batteries.

                               

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                              Wednesday, 16 March 2011 18:52

                              Lead-Acid Battery Manufacture

                              The first practical design of a lead-acid battery was developed by Gaston Planté in 1860, and production has continued to grow steadily since. Automotive batteries represent the major use of lead-acid technology, followed by industrial batteries (stand-by power and traction). More than half the worldwide production of lead goes into batteries.

                              The low cost and ease of manufacture of lead-acid batteries in relation to other electrochemical couples should ensure a continuing demand for this system in the future.

                              The lead-acid battery has a positive electrode of lead peroxide (PbO2) and a negative electrode of high surface area spongy lead (Pb). The electrolyte is a sulphuric acid solution with specific gravity in the range 1.21 to 1.30 (28 to 39% by weight). On discharge, both electrodes convert to lead sulphate, as shown below:

                              Manufacturing Process

                              The manufacturing process, which is shown in the process flow chart (figure 1), is described below:

                              Figure 1. Lead-acid battery manufacturing process

                              ELA020F1

                              Oxide manufacture: Lead oxide is manufactured from pigs of lead (masses of lead from smelting furnaces) by one of two methods—a Barton Pot or a milling process. In the Barton Pot process, air is blown over molten lead to produce a fine stream of lead droplets. The droplets react with oxygen in the air to form the oxide, which consists of a core of lead with a lead oxide (PbO) coating.

                              In the milling process, solid lead (which may range in size from small balls to complete pigs) is fed into a rotating mill. The tumbling action of the lead generates heat and the surface of the lead oxidizes. As the particles roll around in the drum, the surface layers of oxide are removed to expose more clean lead for oxidation. The airstream carries the powder to a bag filter, where it is collected.

                              Grid production: Grids are produced mainly by casting (both automatic and manual) or, particularly for automotive batteries, expansion from wrought or cast lead alloy.

                              Pasting: Battery paste is made by mixing the oxide with water, sulphuric acid and a range of proprietary additives. The paste is pressed by machine or hand into the grid lattice, and the plates are usually flash-dried in a high-temperature oven.

                              Pasted plates are cured by storing them in ovens under carefully controlled conditions of temperature, humidity and time. Free lead in the paste converts to lead oxide.

                              Formation, plate cutting and assembly: Battery plates undergo an electrical formation process in one of two ways. In tank formation, plates are loaded into large baths of dilute sulphuric acid and a direct current is passed to form the positive and negative plates. After drying, the plates are cut and assembled, with separators between them, into battery boxes. Plates of like polarity are connected by welding together the plate lugs.

                              In jar formation, the plates are electrically formed after being assembled into battery boxes.

                              Occupational Health Hazards and Controls

                              Lead

                              Lead is the major health hazard associated with battery manufacture. The principal exposure route is through inhalation, but ingestion can also pose a problem if insufficient attention is paid to personal hygiene. Exposure can occur at all stages of production.

                              Lead oxide manufacture is potentially very hazardous. Exposures are controlled by automating the process, thus removing the workers from the hazard. In many factories the process is operated by one person.

                              In grid casting, exposures to lead fumes are minimized by the use of local exhaust ventilation (LEV) together with thermostatic control of lead pots (lead fume emissions increase markedly above 500 C). Lead-bearing dross, which forms on top of the molten lead, can also cause problems. The dross contains a large amount of very fine dust, and great care has to be exercised when disposing of it.

                              Pasting areas have traditionally resulted in high lead exposures. The manufacturing method often results in splashes of lead slurry getting onto machinery, the floor, aprons and boots. These splashes dry out and produce airborne lead dust. Control is achieved by keeping the floor permanently wetted and frequently sponging down aprons.

                              Lead exposures in other departments (forming, plate cutting and assembly) occur through handling dry, dusty plates. Exposures are minimized by LEV together with appropriate use of personal protective equipment.

                              Many countries have legislation in place to limit the degree of occupational exposure, and numerical standards exist for lead-in-air and blood lead levels.

                              An occupational health professional is normally employed to take blood samples from exposed workers. The frequency of blood testing can range from annual for low-risk workers to quarterly for those in high-risk departments (e.g., pasting). If a worker’s blood lead level exceeds the statutory limit, then the worker should be removed from any work exposure to lead until the blood lead falls to a level deemed acceptable by the medical adviser.

                              Air sampling for lead is complementary to blood lead testing. Personal, rather than static, sampling is the preferred method. A large number of lead-in-air samples is usually required because of the inherent variability in results. Use of the correct statistical procedures in analysing the data can give information on sources of lead and can provide a basis for making improvements to engineering design. Regular air sampling can be used to assess the continuing effectiveness of control systems.

                              The allowable lead-in-air concentrations and blood lead concentrations vary from country to country, and presently range from 0.05 to 0.20 mg/m3 and 50 to 80 mg/dl respectively. There is a continuing downward trend in these limits.

                              In addition to the normal engineering controls, other measures are necessary to minimize lead exposures. There should be no eating, smoking, drinking or gum chewing in any production area.

                              Suitable washing and changing facilities should be provided to enable work clothing to be kept in a separate area from personal clothing and footwear. Washing/shower facilities should be located between the clean and dirty areas.

                              Sulphuric acid

                              During the formation process the active material on the plates is converted to PbO2 at the positive and Pb at the negative electrode. As the plates become fully charged, the formation current begins to dissociate the water in the electrolyte into hydrogen and oxygen:

                              Positive:        

                              Negative:      

                              Gassing generates sulphuric acid mist. Tooth erosion was, at one time, a common feature among workers in formation areas. Battery companies have traditionally employed the services of a dentist, and many continue to do so.

                              Recent studies (IARC 1992) have suggested a possible link between exposures to inorganic acid mists (including sulphuric acid) and cancer of the larynx. Research continues in this area.

                              The occupational exposure standard in the UK for sulphuric acid mist is 1 mg/m3. Exposures can be kept below this level with LEV in place over the formation circuits.

                              Skin exposure to the corrosive sulphuric acid liquid is also of concern. Precautions include personal protection equipment, eyewash fountains and emergency showers.

                              Talc

                              Talc is used in certain hand-casting operations as a mould release agent. Long-term exposure to talc dust can cause pneumoconiosis, and it is important that the dust be controlled by suitable ventilation and process control measures.

                              Man-made mineral fibres (MMFs)

                              Separators are used in lead-acid batteries to electrically insulate the positive from the negative plates. Various types of material have been used over the years (e.g., rubber, cellulose, polyvinyl chloride (PVC), polyethylene), but, increasingly, glass fibre separators are being used. These separators are manufactured from MMFs.

                              An increased risk of lung cancer amongst workers was demonstrated in the early days of the mineral wool industry (HSE 1990). However, this may have been caused by other carcinogenic materials in use at the time. It is prudent nevertheless to ensure that any exposure to MMFs is kept to a minimum by either total enclosure or LEV.

                              Stibine and arsine

                              Antimony and arsenic are commonly used in lead alloys, and stibine (SbH3) or arsine (AsH3) can be produced under certain circumstances:

                                • when a cell is given excessive overcharge
                                • when dross from a lead calcium alloy is mixed with dross from a lead antimony or lead arsenic alloy. The two drosses can react chemically to form calcium stibide or calcium arsenide which, on subsequent wetting, can generate SbH3 or AsH3.

                                   

                                  Stibine and arsine are both highly toxic gases which act by destroying red blood cells. Strict process controls during battery manufacture should prevent any risk of exposure to these gases.

                                  Physical hazards

                                  A variety of physical hazards also exists in battery manufacturing (e.g., noise, molten metal and acid splashes, electrical hazards and manual handling), but the risks from these can be reduced by appropriate engineering and process controls.

                                  Environmental Issues

                                  The effect of lead on the health of children has been extensively studied. It is therefore very important that environmental releases of lead be kept to a minimum. For battery factories, the most polluting air emissions should be filtered. All process waste (usually an acidic lead-bearing slurry) should be processed at an effluent treatment plant to neutralize the acid and settle out the lead from the suspension.

                                  Future Developments

                                  It is likely that there will be increasing restrictions on the use of lead in the future. In an occupational sense this will result in increasing automation of processes so that the worker is removed from the hazard.

                                   

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                                  Wednesday, 16 March 2011 18:51

                                  General Profile

                                  Overview of the Sector

                                  Electrical equipment includes a wide-ranging field of devices. It would be impossible to include information on all items of equipment, and this chapter will therefore be limited to coverage of products of some of the major industries. Numerous processes are involved in the manufacture of such equipment. This chapter discusses the hazards likely to be encountered by persons working in the manufacture of batteries, electric cables, electric lamps and general domestic electrical equipment. It concentrates upon electrical equipment; electronic equipment is discussed in detail in the chapter Microelectronics and semiconductors.

                                  Evolution of the Industry

                                  The pioneering discovery of electromagnetic induction was instrumental in the development of today’s vast electrical industry. The discovery of the electrochemical effect led to the development of batteries as a means of supplying electrical equipment from portable power sources using direct current systems. As devices which relied upon power from mains were invented, a system of transmission and distribution of electricity was required, which led to the introduction of flexible electrical conductors (cables).

                                  The early forms of artificial lighting (i.e., carbon arc and gas lighting) were superseded by the filament lamp (originally with a carbon filament, exhibited by Joseph Swan in England in January 1879). The filament lamp was to enjoy an unprecedented monopoly in domestic, commercial and industrial applications prior to the outbreak of the Second World War, at which stage the fluorescent lamp was introduced. Other forms of discharge lighting, all of which depend upon the passage of an electric current through a gas or vapour, have subsequently been developed and have a variety of applications in commerce and industry.

                                  Other electrical appliances in many fields (e.g., audio-visual, heating, cooking and refrigeration) are constantly being developed, and the range of such devices is increasing. This is typified by the introduction of satellite television and the microwave cooker.

                                  While the availability and accessibility of raw materials had a significant effect upon the development of the industries, the locations of the industries were not necessarily determined by the locations of the raw material sources. The raw materials are often processed by a third party before being used in the assembly of electrical appliances and equipment.

                                  Characteristics of the Workforce

                                  The skills and expertise possessed by those who work in the industry now are different from those possessed by the workforce in earlier years. Equipment used in the production and manufacture of batteries, cables, lamps and domestic electrical appliances is highly automated.

                                  In many instances those who are currently involved in the industry require specialized training in order to carry out their work. Teamwork is a significant factor in the industry, since many processes involve production line systems, where the work of individuals depends upon the work of others.

                                  An ever-increasing number of manufacturing processes involved in the production of electrical appliances rely on some form of computerization. It is necessary, therefore, for the workforce to be familiar with computer techniques. This may not present any problems to the younger workforce, but older workers may not have had any previous computer experience, and it is likely that they will need to be re-trained.

                                  Economic Importance of the Industry

                                  Some countries benefit more than others from the electrical appliances and equipment industry. The industry has economic importance for those countries from which raw materials are obtained and those in which the end products are assembled and/or constructed. Assembly and construction take place in many different countries.

                                  Raw materials do not have infinite availability. Discarded equipment should be re-used wherever possible. However, the costs involved in recovering those parts of discarded equipment which may be re-used may ultimately be prohibitive.

                                   

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                                  Tuesday, 15 March 2011 15:39

                                  Static Electric and Magnetic Fields

                                  Both our natural and our artificial environments generate electric and magnetic forces of various magnitudes—in the outdoors, in offices, in households and in industrial workplaces. This raises two important questions: (1) do these exposures pose any adverse human health effects, and (2) what limits can be set in an attempt to define “safe” limits of such exposures?

                                  This discussion focuses on static electric and magnetic fields. Studies are described on workers in various industries, and also on animals, which fail to demonstrate any clear-cut adverse biological effects at the levels of exposure to electric and magnetic fields usually encountered. Nevertheless, attempts are made to discuss the efforts of a number of international organizations to set guidelines to protect workers and others from any possible dangerous level of exposure.

                                  Definition of Terms

                                  When a voltage or electric current is applied to an object such as an electrical conductor, the conductor becomes charged and forces start to act on other charges in the vicinity. Two types of forces may be distinguished: those arising from stationary electric charges, known as the electrostatic force, and those appearing only when charges are moving (as in an electric current in a conductor), known as the magnetic force. To describe the existence and spatial distribution of these forces, physicists and mathematicians have created the concept of field. One thus speaks of a field of force, or simply, electric and magnetic fields.

                                  The term static describes a situation where all charges are fixed in space, or move as a steady flow. As a result, both charges and current densities are constant in time. In the case of fixed charges, we have an electric field whose strength at any point in space depends on the value and geometry of all the charges. In the case of steady current in a circuit, we have both an electric and a magnetic field constant in time (static fields), since the charge density at any point of the circuit does not vary.

                                  Electricity and magnetism are distinct phenomena as long as charges and current are static; any interconnection between electric and magnetic fields disappears in this static situation and thus they can be treated separately (unlike the situation in time-varying fields). Static electric and magnetic fields are clearly characterized by steady, time-independent strengths and correspond to the zero-frequency limit of the extremely low frequency (ELF) band.

                                  Static Electric Fields

                                  Natural and occupational exposure

                                  Static electric fields are produced by electrically charged bodies where an electric charge is induced on the surface of an object within a static electric field. As a consequence, the electric field at the surface of an object, particularly where the radius is small, such as at a point, can be larger than the unperturbed electric field (that is, the field without the object present). The field inside the object may be very small or zero. Electric fields are experienced as a force by electrically charged objects; for example, a force will be exerted on body hair, which may be perceived by the individual.

                                  On the average, the surface charge of the earth is negative while the upper atmosphere carries a positive charge. The resulting static electric field near the earth’s surface has a strength of about 130 V/m. This field decreases with height, and its value is about 100 V/m at 100 m elevation, 45 V/m at 1 km, and less than 1 V/m at 20 km. Actual values vary widely, depending upon the local temperature and humidity profile and the presence of ionized contaminants. Beneath thunderclouds, for example, and even as thunderclouds are approaching, large field variations occur at ground level, because normally the lower part of a cloud is negatively charged while the upper part contains a positive charge. In addition, there is a space charge between the cloud and ground. As the cloud approaches, the field at ground level may first increase and then reverse, with the ground becoming positively charged. During this process, fields of 100 V/m to 3 kV/m may be observed even in the absence of local lightning; field reversals may take place very rapidly, within 1 min, and high field strengths may persist for the duration of the storm. Ordinary clouds, as well as thunderclouds, contain electric charges and therefore deeply affect the electric field at ground level. Large deviations from the fair-weather field, up to 200%, are also to be expected in the presence of fog, rain and naturally occurring small and large ions. Electric field changes during the daily cycle can even be expected in completely fair weather: fairly regular changes in local ionization, temperature or humidity and the resulting changes in the atmospheric electrical conductivity near the ground, as well as mechanical charge transfer by local air movements, are probably responsible for these diurnal variations.

                                  Typical levels of man-made electrostatic fields are in the 1 to 20 kV/m range in offices and households; these fields are frequently generated around high-voltage equipment, such as TV sets and video display units (VDUs), or by friction. Direct current (DC) transmission lines generate both static electric and magnetic fields and are an economical means of power distribution where long distances are involved.

                                  Static electric fields are widely used in industries such as chemicals, textile, aviation, paper and rubber, and in transportation.

                                  Biological effects

                                  Experimental studies provide little biological evidence to suggest any adverse effect of static electric fields on human health. The few animal studies that have been carried out also appear to have yielded no data supporting adverse effects on genetics, tumour growth, or on the endocrine or cardiovascular systems. (Table 1 summarizes these animal studies.)

                                  Table 1. Studies on animals exposed to static electric fields

                                  Biological end-points

                                  Reported effects

                                  Exposure conditions

                                  Haematology and immunology

                                  Changes in the albumin and globulin fractions of serum proteins in rats.
                                  Responses not consistent

                                  No significant differences in blood cell counts, blood proteins or blood
                                  chemistry in mice

                                  Continuous exposure to fields between 2.8 and 19.7 kV/m
                                  from 22 to 52 days of age

                                  Exposure to 340 kV/m for 22 h/day for a total of 5,000 h

                                  Nervous system

                                  Induction of significant changes observed in the EEGs of rats. However, no clear indication of a consistent response

                                  No significant changes in the concentrations and utilization rates of
                                  various neurotransmitters in brains of male rats

                                  Exposure to electric field strengths up to 10 kV/m

                                  Exposure to a 3 kV/m field for up to 66 h

                                  Behaviour

                                  Recent, well-conducted studies suggesting no effect on rodent
                                  behaviour

                                  Production of dose-dependent avoidance behaviour in male rats, with  no influence of air ions

                                  Exposure to field strengths up to 12 kV/m

                                  Exposure to HVD electric fields ranging from 55 to 80 kV/m

                                  Reproduction and development

                                  No significant differences in the total number of offspring nor in the
                                  percentage surviving in mice

                                  Exposure to 340 kV/m for 22 h/day before, during and after
                                  gestation

                                   

                                  No in vitro studies have been conducted to evaluate the effect of exposing cells to static electric fields.

                                  Theoretical calculations suggest that a static electric field will induce a charge on the surface of exposed people, which may be perceived if discharged to a grounded object. At a sufficiently high voltage, the air will ionize and become capable of conducting an electric current between, for example, a charged object and a grounded person. The breakdown voltage depends on a number of factors, including the shape of the charged object and atmospheric conditions. Typical values of corresponding electric field strengths range between 500 and 1,200 kV/m.

                                  Reports from some countries indicate that a number of VDU operators have experienced skin disorders, but the exact relationship of these to VDU work is unclear. Static electric fields at VDU workplaces have been suggested as a possible cause of these skin disorders, and it is possible that the electrostatic charge of the operator may be a relevant factor. However, any relationship between electrostatic fields and skin disorders must still be regarded as hypothetical based on available research evidence.

                                  Measurements, prevention, exposure standards

                                  Static electric field strength measurements may be reduced to measurements of voltages or electric charges. Several electrostatic voltmeters are commercially available which permit accurate measurements of electrostatic or other high-impedance sources without physical contact. Some utilize an electrostatic chopper for low drift, and negative feedback for accuracy and probe-to-surface spacing insensitivity. In some cases the electrostatic electrode “looks” at the surface under measurement through a small hole at the base of the probe assembly. The chopped AC signal induced on this electrode is proportional to the differential voltage between the surface under measurement and the probe assembly. Gradient adapters are also used as accessories to electrostatic voltmeters, and permit their use as electrostatic field strength meters; direct readout in volts per metre of separation between the surface under test and the grounded plate of the adapter is possible.

                                  There are no good data which can serve as guidelines to set base limits of human exposure to static electric fields. In principle, an exposure limit could be derived from the minimum breakdown voltage for air; however, the field strength experienced by a person within a static electric field will vary according to body orientation and shape, and this must be taken into account in attempting to arrive at an appropriate limit.

                                  Threshold limit values (TLVs) have been recommended by the American Conference of Governmental Industrial Hygienists (ACGIH 1995). These TLVs refer to the maximum unprotected workplace static electric field strength, representing conditions under which nearly all workers may be exposed repeatedly without adverse health effects. According to ACGIH, occupational exposures should not exceed a static electric field strength of 25 kV/m. This value should be used as a guide in the control of exposure and, due to individual susceptibility, should not be regarded as a clear line between safe and dangerous levels. (This limit refers to the field strength present in air, away from the surfaces of conductors, where spark discharges and contact currents may pose significant hazards, and is intended for both partial-body and whole-body exposures.) Care should be taken to eliminate ungrounded objects, to ground such objects, or to use insulated gloves when ungrounded objects must be handled. Prudence dictates the use of protective devices (e.g., suits, gloves and insulation) in all fields exceeding 15 kV/m.

                                  According to ACGIH, present information on human responses and possible health effects of static electric fields is insufficient to establish a reliable TLV for time-weighted average exposures. It is recommended that, lacking specific information from the manufacturer on electromagnetic interference, the exposure of wearers of pacemakers and other medical electronic devices should be maintained at or below 1 kV/m.

                                  In Germany, according to a DIN Standard, occupational exposures should not exceed a static electric field strength of 40 kV/m. For short exposures (up to two hours per day) a higher limit of 60 kV/m is permitted.

                                  In 1993, the National Radiological Protection Board (NRPB 1993) provided advice concerning appropriate restrictions on the exposure of people to electromagnetic fields and radiation. This includes both static electric and magnetic fields. In the NRPB document, investigation levels are provided for the purpose of comparing values of measured field quantities in order to determine whether or not compliance with basic restrictions has been achieved. If the field to which a person is exposed exceeds the relevant investigation level, compliance with the basic restrictions must be checked. Factors that might be considered in such an assessment include, for example, the efficiency of the coupling of the person to the field, the spatial distribution of the field across the volume occupied by the person, and the duration of exposure.

                                  According to NRPB it is not possible to recommend basic restrictions for avoiding direct effects of human exposure to static electric fields; guidance is given to avoid annoying effects of direct perception of the surface electric charge and indirect effects such as electric shock. For most people, the annoying perception of surface electric charge, acting directly on the body, will not occur during exposure to static electric field strengths less than about 25 kV/m, that is, the same field strength recommended by ACGIH. To avoid spark discharges (indirect effects) causing stress, NRPB recommends that DC contact currents be restricted to less than 2 mA. Electric shock from low impedance sources can be prevented by following established electrical safety procedures relevant to such equipment.

                                  Static Magnetic Fields

                                  Natural and occupational exposure

                                  The body is relatively transparent to static magnetic fields; such fields will interact directly with magnetically anisotropic materials (exhibiting properties with different values when measured along axes in different directions) and moving charges.

                                  The natural magnetic field is the sum of an internal field due to the earth acting as a permanent magnet and an external field generated in the environment from such factors as solar activity or atmospherics. The internal magnetic field of the earth originates from the electric current flowing in the upper layer of the earth’s core. There are significant local differences in the strength of this field, whose average magnitude varies from about 28 A/m at the equator (corresponding to a magnetic flux density of about 35 mT in a non-magnetic material such as air) to about 56 A/m over the geomagnetic poles (corresponding to about 70 mT in air).

                                  Artificial fields are stronger than those of natural origin by many orders of magnitude. Artificial sources of static magnetic fields include all devices containing wires carrying direct current, including many appliances and equipment in industry.

                                  In direct-current power transmission lines, static magnetic fields are produced by moving charges (an electric current) in a two-wire line. For an overhead line, the magnetic flux density at ground level is about 20 mT for a  500 kV line. For an underground transmission line buried at 1.4 m and carrying a maximum current of about 1 kA, the maximum magnetic flux density is less than 10 mT at ground level.

                                  Major technologies that involve the use of large static magnetic fields are listed in table 2 along with their corresponding exposure levels.

                                  Table 2. Major technologies involving the use of large static magnetic fields, and corresponding exposure levels

                                  Procedures

                                  Exposure levels

                                  Energy technologies

                                  Thermonuclear fusion reactors

                                  Fringe fields up to 50 mT in areas accessible to personnel.
                                  Below 0.1 mT outside the reactor site

                                  Magnetohydrodynamic systems

                                  Approximately 10 mT at about 50 m; 100 mT only at distances greater than 250 m

                                  Superconducting magnet energy storage systems

                                  Fringe fields up to 50 mT at operator-accessible locations

                                  Superconducting generators and transmission lines

                                  Fringe fields projected to be less than 100 mT

                                  Research facilities

                                  Bubble chambers

                                  During changes of film cassettes, the field is about 0.4–0.5 T at foot level and about 50 mT at the level of the head

                                  Superconducting spectrometers

                                  About 1 T at operator-accessible locations

                                  Particle accelerators

                                  Personnel are seldom exposed because of exclusion from the high radiation zone. Exceptions arise only during maintenance

                                  Isotope separation units

                                  Brief exposures to fields up to 50 mT
                                  Usually field levels are less than 1 mT

                                  Industry

                                  Aluminium production

                                  Levels up to 100 mT in operator-accessible locations

                                  Electrolytic processes

                                  Mean and maximum field levels of about 10 and 50 mT, respectively

                                  Production of magnets

                                  2–5 mT at worker’s hands; in the range of 300 to 500 mT at the level of the chest and head

                                  Medicine

                                  Nuclear magnetic resonance imaging and spectroscopy

                                  An unshielded 1-T magnet produces about 0.5 mT at 10 m, and an unshielded 2-T magnet produces the same exposure at about 13 m

                                   

                                  Biological effects

                                  Evidence from experiments with laboratory animals indicates that there are no significant effects on the many developmental, behavioural, and physiological factors evaluated at static magnetic flux densities up to 2 T. Nor have studies on mice demonstrated any harm to the foetus from exposure to magnetic fields up to 1 T.

                                  Theoretically, magnetic effects could retard blood flowing in a strong magnetic field and produce a rise in blood pressure. A flow reduction of at most a few per cent could be expected at 5 T, but none was observed in human subjects at 1.5 T, when investigated.

                                  Some studies on workers involved in the manufacture of permanent magnets have reported various subjective symptoms and functional disturbances: irritability, fatigue, headache, loss of appetite, bradycardia (slow heart beat), tachycardia (rapid heart beat), decreased blood pressure, altered EEG, itching, burning and numbness. However, lack of any statistical analysis or assessment of the impact of physical or chemical hazards in the working environment significantly reduces the validity of these reports and makes them difficult to evaluate. Although the studies are inconclusive, they do suggest that, if long-term effects do in fact occur, they are very subtle; no cumulative gross effects have been reported.

                                  Individuals exposed to a 4T magnetic flux density have been reported as experiencing sensory effects associated with motion in the field, such as vertigo (dizziness), feeling of nausea, a metallic taste, and magnetic sensations when moving the eyes or head. However, two epidemiological surveys of general health data in workers chronically exposed to static magnetic fields failed to reveal any significant health effects. Health data of 320 workers were obtained in plants using large electrolytic cells for chemical separation processes where the average static field level in the work environment was 7.6 mT and the maximum field was 14.6 mT. Slight changes in the white blood cell count, but still within the normal range, were detected in the exposed group compared to the 186 controls. None of the observed transient changes in blood pressure or other blood measurements was considered indicative of a significant adverse effect associated with magnetic field exposure. In another study, the prevalence of disease was evaluated among 792 workers who were occupationally exposed to static magnetic fields. The control group consisted of 792 unexposed workers matched for age, race and socio-economic status. The range of magnetic field exposures varied from 0.5 mT for long durations to 2 T for periods of several hours. No statistically significant change in the prevalence of 19 categories of disease was observed in the exposed group compared with the controls. No difference in the prevalence of disease was found between a subgroup of 198 who had experienced exposures of 0.3 T or higher for periods of one hour or longer when compared with the remainder of the exposed population or the matched controls.

                                  A report on workers in the aluminium industry indicated an elevated leukaemia mortality rate. Although this epidemiological study reported an increased cancer risk for persons directly involved in aluminium production where workers are exposed to large static magnetic fields, there is at present no clear evidence to indicate exactly which carcinogenic factors within the work environment are responsible. The process used for aluminium reduction creates coal tar, pitch volatiles, fluoride fumes, sulphur oxides and carbon dioxide, and some of these might be more likely candidates for cancer-causing effects than magnetic field exposure.

                                  In a study on French aluminium workers, cancer mortality and mortality from all causes were found not to differ significantly from that observed for the general male population of France (Mur et al. 1987).

                                  Another negative finding linking magnetic field exposures to possible cancer outcomes comes from a study of a group of workers at a chloroalkali plant where the 100 kA DC currents used for the electrolytic production of chlorine gave rise to static magnetic flux densities, at worker’s locations, ranging from 4 to 29 mT. The observed versus expected incidence of cancer among these workers over a 25-year period showed no significant differences.

                                  Measurements, prevention and exposure standards

                                  During the last thirty years, the measurement of magnetic fields has undergone considerable development. Progress in techniques has made it possible to develop new methods of measurement as well as to improve old ones.

                                  The two most popular types of magnetic field probes are a shielded coil and a Hall probe. Most of the commercially available magnetic field meters use one of them. Recently, other semiconductor devices, namely bipolar transistors and FET transistors, have been proposed as magnetic field sensors. They offer some advantages over Hall probes, such as higher sensitivity, greater spatial resolution and broader frequency response.

                                  The principle of the nuclear magnetic resonance (NMR) measurement technique is to determine the resonant frequency of the test specimen in the magnetic field to be measured. It is an absolute measurement that can be made with very great accuracy. The measuring range of this method is from about 10 mT to 10 T, with no definite limits. In field measurements using the proton magnetic resonance method, an accuracy of 10–4 is easily obtained with simple apparatus and an accuracy of 10–6 can be reached with extensive precautions and refined equipment. The inherent shortcoming of the NMR method is its limitation to a field with a low gradient and the lack of information about the field direction.

                                  Recently, several personal dosimeters suitable for monitoring exposures to static magnetic fields have also been developed.

                                  Protective measures for the industrial and scientific use of magnetic fields can be categorized as engineering design measures, the use of separation distance, and administrative controls. Another general category of hazard-control measures, which include personal protective equipment (e.g., special garments and face masks), does not exist for magnetic fields. However, protective measures against potential hazards from magnetic interference with emergency or medical electronic equipment and for surgical and dental implants are a special area of concern. The mechanical forces imparted to ferromagnetic (iron) implants and loose objects in high-field facilities require that precautions be taken to guard against health and safety hazards.

                                  Techniques to minimize undue exposure to high-intensity magnetic fields around large research and industrial facilities generally fall into four types:

                                    1. distance and time
                                    2. magnetic shielding
                                    3. electromagnetic interference (EMI) and compatibility
                                    4. administrative measures.

                                           

                                          The use of warning signs and special-access areas to limit exposure of personnel near large magnet facilities has been of greatest use for controlling exposure. Administrative controls such as these are generally preferable to magnetic shielding, which can be extremely expensive. Loose ferromagnetic and paramagnetic (any magnetizing substances) objects can be converted into dangerous missiles when subjected to intense magnetic field gradients. Avoidance of this hazard can be achieved only by removing loose metallic objects from the area and from personnel. Such items as scissors, nail files, screwdrivers and scalpels should be banned from the immediate vicinity.

                                          The earliest static magnetic field guidelines were developed as an unofficial recommendation in the former Soviet Union. Clinical investigations formed the basis for this standard, which suggested that the static magnetic field strength at the workplace should not exceed 8 kA/m (10 mT).

                                          The American Conference of Governmental Industrial Hygienists issued TLVs of static magnetic flux densities that most workers could be exposed to repeatedly, day after day, without adverse health effects. As for electric fields, these values should be used as guides in the control of exposure to static magnetic fields, but they should not be regarded as a sharp line between safe and dangerous levels. According to ACGIH, routine occupational exposures should not exceed 60 mT averaged over the whole body or 600 mT to the extremities on a daily, time-weighted basis. A flux density of 2 T is recommended as a ceiling value. Safety hazards may exist from the mechanical forces exerted by the magnetic field upon ferromagnetic tools and medical implants.

                                          In 1994, the International Commission on Non-Ionizing Radiation Protection (ICNIRP 1994) finalized and published guidelines on limits of exposure to static magnetic fields. In these guidelines, a distinction is made between exposure limits for workers and the general public. The limits recommended by the ICNIRP for occupational and general public exposures to static magnetic fields are summarized in table 3. When magnetic flux densities exceed 3 mT, precautions should be taken to prevent hazards from flying metallic objects. Analogue watches, credit cards, magnetic tapes and computer disks may be adversely affected by exposure to 1 mT, but this is not seen as a safety concern for people.

                                          Table 3. Limits of exposure to static magnetic fields recommended by the International Commission on Non-Ionizing Radiation Protection (ICNIRP)

                                          Exposure characteristics

                                          Magnetic flux density

                                          Occupational

                                          Whole working day (time-weighted average)

                                          200 mT

                                          Ceiling value

                                          2 T

                                          Limbs

                                          5 T

                                          General Public

                                          Continuous exposure

                                          40 mT

                                           

                                          Occasional access of the public to special facilities where magnetic flux densities exceed 40 mT can be allowed under appropriately controlled conditions, provided that the appropriate occupational exposure limit is not exceeded.

                                          ICNIRP exposure limits have been set for a homogeneous field. For inhomogeneous fields (variations within the field), the average magnetic flux density must be measured over an area of 100 cm2.

                                          According to a recent NRPB document, the restriction on acute exposure to less than 2 T will avoid acute responses such as vertigo or nausea and adverse health effects resulting from cardiac arrhythmia (irregular heart beat) or impaired mental function. In spite of the relative lack of evidence from studies of exposed populations regarding possible long-term effects of high fields, the Board considers it advisable to restrict long-term, time-weighted exposure over 24 hours to less than 200 mT (one-tenth of that intended to prevent acute responses). These levels are quite similar to those recommended by ICNIRP; ACGIH TLVs are slightly lower.

                                          People with cardiac pacemakers and other electrically activated implanted devices, or with ferromagnetic implants, may not be adequately protected by the limits given here. The majority of cardiac pacemakers are unlikely to be affected from exposure to fields below 0.5 mT. People with some ferromagnetic implants or electrically activated devices (other than cardiac pacemakers) may be affected by fields above a few mT.

                                          Other sets of guidelines recommending limits of occupational exposure exist: three of these are enforced in high-energy physics laboratories (Stanford Linear Accelerator Center and Lawrence Livermore National Laboratory in California, CERN accelerator laboratory in Geneva), and an interim guideline at the US Department of Energy (DOE).

                                          In Germany, according to a DIN Standard, occupational exposures should not exceed a static magnetic field strength of 60 kA/m (about 75 mT). When only the extremities are exposed, this limit is set at 600 kA/m; field strength limits up to 150 kA/m are permitted for short, whole-body exposures (up to 5 min per hour).

                                           

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